legislation-obligation

Substance Regulatory Obligations

OBL

4-methyl-m-phenylenediamine

EC number: 202-453-1

CAS number: 95-80-7

Last updated: 11/03/2020
ECHA Legislation Regulatory Obligations

Regulatory obligations may exist for this substance under the legislations under ECHA’s remit or for which ECHA has delegated tasks (i.e. REACH, CLP, BPR, PIC, CAD / CMD, WFD, and POPs). Please check the substance Infocard.

CAD - Chemical Agents Directive

EU. Worker Protection-Hazardous (98/24)

This list represents a calculated inventory of substances based on the list of harmonized substances contained in Table 3 of Annex VI to the CLP Regulation (1272/2008/EC). Note that this list is not exhaustive. While the harmonized list covers many hazardous substances, other ones not listed may also meet the classification criteria in accordance with the CLP.

Name CAS
4-methyl-m-phenylenediamine; 2,4-toluenediamine
diaminotoluene, technical product - reaction mass of 4-methyl-m-phenylene diamine and 2-methyl-m-phenylene diamine; methyl-phenylenediamine
CMD - Carcinogens and Mutagens Directive

EU. Carcinogens/Mutagens Directive (2004/37)

This is a non-exhaustive list of substances based on the Article 2 carcinogen and mutagen (CM) definitions and Annex I of Directive 2004/37/EC. 1A & 1B CMs are derived from the CLP Regulation's Table 3 of Annex VI (1272/2008/EC). Employers are obligated to minimize worker exposure to these agents as far as possible, and must arrange for medical surveillance of workers exposed to these substances.

Name CAS Restriction(s) Physical form Substance Description Notes  
4-methyl-m-phenylenediamine; 2,4-toluenediamine
Details
diaminotoluene, technical product - reaction mass of 4-methyl-m-phenylene diamine and 2-methyl-m-phenylene diamine with methyl-phenylenediamine
Details
Cosmetic Products Regulation

EU. Cosmetics Regulation, Annex II, Prohibited Substances

This list contains substances which are banned from use in any cosmetic products marketed for sale or use in the European Union.

Ref No. Substance Identification Expressed As Product type, body parts Maximum Threshold Restriction(s) Notes  
Name EC Number CAS Molecular formula
364
4-Methyl-m-phenylenediamine
202-453-1
95-80-7
All cosmetic products
0 %
Details
EU Ecolabel Regulation

EU. Dangerous Substances - Eco-Labels

This database contains: (1) the list of hazardous substances harmonized for classification and labeling in EU (i.e. Table 3 of Annex VI to CLP Regulation); and (2) the Candidate List of substances of very high concern (SVHC). The EU Ecolabel may not be awarded to substances or mixtures classified as such. Note that this list is not exhaustive. While the harmonized list covers many hazardous substances, other ones not listed may also meet the classification criteria in accordance with the CLP.

Name CAS Restriction(s) Expressed As Table 3 of Annex VI to CLP EU REACH: List of SVHC Physical form Substance Description  
4-Methyl-m-phenylenediamine
toluene-2,4-diamine
95-80-7
yes
Details
4-methyl-m-phenylenediamine
2,4-toluenediamine
yes
Details
diaminotoluene, technical product - reaction mass of 4-methyl-m-phenylene diamine and 2-methyl-m-phenylene diamine with methyl-phenylenediamine
yes
Details
Inland Transport of Dangerous Goods Directive

EU. ADN Dangerous Goods Lists, Directive 2008/68/EC

This database contains the ADN's Dangerous Goods List, as implemented by the EU's Directive 2008/68/EC. This Directive establishes rules for the safe transport of dangerous goods between EU countries by road, rail, and waterway. It applies the European Agreements on the international transport of dangerous goods by road (ADR) and inland waterways (ADN), and the Regulations concerning the international carriage of dangerous goods by rail (RID).

Name CAS Class Labels Packing Group UN No. or ID no. Carriage permitted Classification code Equipment required Limited and excepted quantities Number of blue cones/lights Provisions concerning loading, unloading and carriage Ventilation Remarks Special provisions Notes  
Excepted quantities Limited quantities Units Column (11c) Column (11b) Column (11a)
2,4-TOLUYLENEDIAMINE, SOLID
95-80-7
6.1
6.1
III
1709
T2
PP
EP
E1
5 kg
0
802
Details
2,4-TOLUYLENEDIAMINE SOLUTION
95-80-7
6.1
6.1
III
3418
T1
PP
EP
TOX
A
E1
5 L
0
VE02
802
Details

EU. ADR Dangerous Goods Lists, Directive 2008/68/EC

This database contains the ADR's Dangerous Goods List, as implemented by the EU's Directive 2008/68/EC. This Directive establishes rules for the safe transport of dangerous goods between EU countries by road, rail, and waterway. It applies the European Agreements on the international transport of dangerous goods by road (ADR) and inland waterways (ADN), and the Regulations concerning the international carriage of dangerous goods by rail (RID).

Name CAS Class Labels Packing Group Packaging UN No. ADR tank Classification code Hazard identification no. Limited and excepted quantities Vehicle for tank carriage Portable tank and bulk containers Special provisions Special provisions for carriage Transport category (Tunnel restriction code) Notes  
Mixed packing provisions Special packing provisions Packing instructions Tank code Special provisions Excepted quantities Limited quantities Unit Instructions Special provisions bulk Loading, unloading & handling Operation Packages Tunnel restriction code Transport category
2,4-TOLUYLENEDIAMINE, SOLID
95-80-7
6.1
6.1
III
MP10
B3
P002
IBC08
LP02
R001
1709
SGAH
L4BH
TU15
TE19
T2
60
E1
5 kg
AT
T1
TP33
VC1
VC2
AP7
CV13
CV28
S9
B3
(E)
2
Details
2,4-TOLUYLENEDIAMINE SOLUTION
95-80-7
6.1
6.1
III
MP19
P001
IBC03
LP01
R001
3418
L4BH
TU15
TE19
T1
60
E1
5 L
AT
T4
TP1
CV13
CV28
S9
(E)
2
Details

EU. RID Dangerous Goods Lists, Directive 2008/68/EC

This database contains the RID's Dangerous Goods List, as implemented by the EU's Directive 2008/68/EC. This Directive establishes rules for the safe transport of dangerous goods between EU countries by road, rail, and waterway. It applies the European Agreements on the international transport of dangerous goods by road (ADR) and inland waterways (ADN), and the Regulations concerning the international carriage of dangerous goods by rail (RID).

Name CAS Class Labels Packing Group UN No. Classification code Express parcels Hazard identification number RID Tanks Limited and excepted quantities Packaging Portable tanks and bulk containers Transport category Special provisions for carriage Special provisions Notes  
Tank code Special provisions Excepted quantities Units Limited quantities Special packaging provisions Packaging instructions Mixed packing provisions Special provisions Instructions Loading, unloading & handling bulk Packages
2,4-TOLUYLENEDIAMINE, SOLID
95-80-7
6.1
6.1
III
1709
T2
CE11
60
SGAH
L4BH
TU15
E1
5 kg
B3
P002
IBC08
LP02
R001
MP10
TP33
T1
2
CW13
CW28
CW31
VC1
VC2
AP7
Details
2,4-TOLUYLENE-DIAMINE SOLUTION
95-80-7
6.1
6.1
III
3418
T1
CE8
60
L4BH
TU15
E1
5 L
P001
IBC03
LP01
R001
MP19
TP1
T4
2
CW13
CW28
CW31
W12
Details
Protection of Pregnant and Breastfeeding Workers Directive

EU. Pregnant Women Protection (92/85)

This list contains substances to which pregnant workers and workers who have recently given birth or are breastfeeding may not be exposed. This is only a partial list; employers are obliged to prevent the exposure of these workers to any agents that may cause adverse health effect for either mother or child. This list is generated from hazardous substances listed in Directive 92/85/EEC and from table 3.2 of Annex VI of the CLP.

Name CAS CLP (1272/2008) CMRs ECCAR Directive 2004/37/EC EU_BA PREGW Notes  
4-methyl-m-phenylenediamine; 2,4-toluenediamine
Carc. 1B; Muta. 2; Repr. 2
yes
Details
diaminotoluene, technical product - reaction mass of 4-methyl-m-phenylene diamine and 2-methyl-m-phenylene diamine; methyl-phenylenediamine
Carc. 1B; Muta. 2; Repr. 2
yes
Details
Protection of Young People Directive

EU. Young People at Work (94/33)

This list contains biological and chemical agents, in accordance with Art. 7 and points 2 and 3 of the Annex to Directive 94/33/EC, to which young persons (under 18 years of age) may not be exposed at the workplace. The database represents a non-exhaustive list of such substances based on: 1) agents of risk groups 3 and 4 under Directive 2000/54/EC; 2) Table 3 of Annex VI to the CLP Regulation; 3) and Annex I of Directive 2004/37/EC.

Name CAS EC_YOUNG ECCAR Directive 2004/37/EC EU CLP (1272/2008) EU_BA Directive 2000/54/EC Notes  
4-methyl-m-phenylenediamine; 2,4-toluenediamine
Carc. 1B; Muta. 2; Acute Tox. 3; STOT RE 2; Skin Sens. 1
Details
diaminotoluene, technical product - reaction mass of 4-methyl-m-phenylene diamine and 2-methyl-m-phenylene diamine; methyl-phenylenediamine
Carc. 1B; Muta. 2; Acute Tox. 3; STOT RE 2; Skin Sens. 1
Details
Safety and/or Health Signs at Work Directive

EU. Workplace Signs

This directive requires employers to ensure proper signage is posted in areas where hazards cannot be avoided or reduced. The annexes to this directive provide detailed information about the minimum requirements for all safety and health signs. According to the annexes to the directive, storage areas and containers containing chemical substances or mixtures that are classified as hazardous according to the CLP Regulation (1272/2008/EC) must be marked and/or labeled.

Name EC Number CAS Index Sustance Description Danger Symbols Restriction Physical form  
diaminotoluene, technical product - reaction mass of 4-methyl-m-phenylene diamine and 2-methyl-m-phenylene diamine with methyl-phenylenediamine
202-453-1
612-151-00-5
Skull and crossbones
Health hazard
Details
4-methyl-m-phenylenediamine; 2,4-toluenediamine
202-453-1
612-099-00-3
Skull and crossbones
Health hazard
Details
WFD - Waste Framework Directive

EU. Hazardous Waste Properties: Annex III (2008/98/EC)

This database contains substances that have been assigned hazard property (HP) waste codes 1-15, as defined in terms of the hazard class & category, hazard (H) statement, and/or concentration limits provided in Annex III of the Waste Framework Directive (2008/98/EC). The classifications of the substances listed in the database are based on their harmonized classifications per Table 3 of Annex VI to the CLP Regulation (1272/2008/EC).

Name EC Number CAS EU CLP (1272/2008) HP Code Index
4-methyl-m-phenylenediamine; 2,4-toluenediamine
202-453-1
Carc. 1B
Muta. 2
Repr. 2
Acute Tox. 3
Acute Tox. 4
STOT RE 2
Skin Sens. 1
Aquatic Chronic 2
HP7 Carcinogenic: waste which induces cancer or increases its incidence.
HP11 Mutagenic: waste which may cause a mutation, that is a permanent change in the amount or structure of the genetic material in a cell.
HP10 Toxic for reproduction: waste which has adverse effects on sexual function and fertility in adult males and females, as well as developmental toxicity in the offspring.
HP6 Acute Toxicity: waste which can cause acute toxic effects following oral or dermal administration, or inhalation exposure.
HP5 Specific Target Organ Toxicity (STOT)/Aspiration Toxicity: waste which can cause specific target organ toxicity either from a single or repeated exposure, or which cause acute toxic effects following aspiration.
HP13 Sensitising: waste which contains one or more substances known to cause sensitising effects to the skin or the respiratory organs.
HP14 Ecotoxic: waste which presents or may present immediate or delayed risks for one or more sectors of the environment.
612-099-00-3
diaminotoluene, technical product - reaction mass of 4-methyl-m-phenylene diamine and 2-methyl-m-phenylene diamine; methyl-phenylenediamine
202-453-1
Carc. 1B
Muta. 2
Repr. 2
Acute Tox. 3
Acute Tox. 4
STOT RE 2
Skin Sens. 1
Aquatic Chronic 2
HP7 Carcinogenic: waste which induces cancer or increases its incidence.
HP11 Mutagenic: waste which may cause a mutation, that is a permanent change in the amount or structure of the genetic material in a cell.
HP10 Toxic for reproduction: waste which has adverse effects on sexual function and fertility in adult males and females, as well as developmental toxicity in the offspring.
HP6 Acute Toxicity: waste which can cause acute toxic effects following oral or dermal administration, or inhalation exposure.
HP5 Specific Target Organ Toxicity (STOT)/Aspiration Toxicity: waste which can cause specific target organ toxicity either from a single or repeated exposure, or which cause acute toxic effects following aspiration.
HP13 Sensitising: waste which contains one or more substances known to cause sensitising effects to the skin or the respiratory organs.
HP14 Ecotoxic: waste which presents or may present immediate or delayed risks for one or more sectors of the environment.
612-151-00-5

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