Κατάλογος περιορισμών
Κατάλογος περιορισμών
Κατάλογος περιορισμών
The table below is the Annex XVII to REACH and includes all the restrictions adopted in the framework of REACH and the previous legislation, Directive 76/769/EEC. Each entry shows a substance or a group of substances or a substance in a mixture, and the consequent restriction conditions. The latest consolidated version of REACH presents the restrictions adopted until the date of publication. Subsequent changes are included in the amending Commission regulations.
The restricted substances (on their own, in a mixture or in an article) are substances for which manufacture, placing on the market or use is limited or banned in the European Union.
The table has been prepared by the European Chemicals Agency (ECHA) to facilitate the searching of restricted substances in the Annex XVII of the REACH Regulation, and the table provides additional information related to the specific restriction entry.
The table contains:
- Name: the name as given in column 1 of Annex XVII of each entry. In certain cases a group name is not available and the entry number is used instead;
- EC and CAS numbers; please note that not all the entries in Annex XVII of the REACH Regulation have these numbers. Note also that if it is a group entry, the EC and CAS numbers are under the group member information;
- Conditions: a document prepared by ECHA that includes the conditions of the restriction according to the latest updated consolidated version of Annex XVII to REACH Regulation. The document also contains the subsequent amendment(s) after the publishing of the consolidated version of REACH;
- Appendices: links to appendices that concern only certain entries. Please note that searching with CAS or EC numbers is not yet possible for substances restricted under Appendices 1-6 (CMR substances);
- Standards: links providing information on standards, where available (links to the CEN search engine for the European standards, or to the international standards' pages);
- History: links to the original restriction and subsequent amendments;
- Q&A: the relevant question(s) and answers related to the restriction entry. Please note that the list of Questions and Answers on Restrictions contains also general Q&As, which are not entry specific.
Group members: if there is an entry which concerns several substances (i.e. group entry); the substances within the group entry are described as ‘Group members' and listed in the table. These members are either explicitly mentioned in the specific restriction entry, or they are identified by ECHA in case the entry is of general nature (like cadmium and its compounds). Note that this identification is not yet ready for all entries.
Note that some entries have been deleted from the table:
- Regulation (EU) No 552/2009: entries 33 and 39 have been deleted (substances severely restricted under Regulation (EC) No 2037/2000 – substances that deplete the ozone layer).
- Regulation (EU) No 207/2011: entries 44 and 53 have been deleted (substances severely restricted under Regulation (EU) No 850/2004 – substances as persistent organic pollutants). Note: Regulation (EC) No 850/2004 is repealed with Regulation (EU) No 2020/2096.
- Regulation (EU) No 126/2013: entry 42 has been deleted (substances severely restricted under Regulation (EU) No 519/2012 amending Regulation (EC) No 850/2004 – substances as persistent organic pollutants). Note: Regulation (EC) No 519/2012 is repealed with Regulation (EU) No 2020/2096.
- Regulation (EU) No 2020/2096: entries 22, 67 and 68 have been deleted (substances severely restricted under Regulation (EU) No 2019/1021 on persistent organic pollutants). See Regulation (EU) No 2020/2096.
Last updated 01 Αυγούστου 2024. Database contains 73 unique substances/entries.
Substance name | EC No. | CAS No. | Entry no. | Conditions | Appendices | |
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Arsonic acid, [4-[[4-(dimethylamino)phenyl]azo]phenyl]-, monohydrochloride
EC No.:
620-678-7
| CAS No.:
73688-85-4
3-[(dimethylcarbamothioyl)thio]-N,N,6-trimethyl-1,5-bis(thioxo)-2,4-dithia-6-aza-3-arsaheptan-1-amine; asomate
EC No.:
803-606-0
| CAS No.:
3586-60-5
Slimes and Sludges, copper electrolytic refining, decopperized, arsenic-rich
Product obtained by centrifuging the slime discharged at the bases of cells for decopperization of electrolytic copper solutions. Composed primarily of a copper powder rich in arsenic.
EC No.:
309-772-6
| CAS No.:
100995-81-1
Slimes and Sludges, copper-lead ore roasting off gas scrubbing, arsenic-contg.
The product obtained by the purification of copper-lead ore concentrate roasting offgas. Composed primarily of arsenic oxide (As2O3).
EC No.:
310-063-9
| CAS No.:
102110-62-3
Flue dust, arsenic-contg.
Formed when arsenic and metal oxide particles are driven off during the roasting and converting of copper concentrates and matte in the production of anode copper.
EC No.:
232-434-3
| CAS No.:
8028-73-7
3-methyl-4-(pyrrolidin-1-yl)benzenediazonium hexafluoroarsenate
EC No.:
248-532-4
| CAS No.:
27569-09-1
Slimes and Sludges, copper refining
A complex combination resulting from copper processing-other than electrolytic.
EC No.:
266-977-2
| CAS No.:
67712-00-9
Silicic acid (H4SiO4), zinc salt (1:2), arsenic and manganese-doped
EC No.:
271-895-5
| CAS No.:
68611-46-1
Bis(pentane-2,4-dionato-O,O')boron(1+) hexafluoroarsenate(1-)
EC No.:
272-591-5
| CAS No.:
68892-01-3
Lead alloy, base, dross
A scum formed on the surface of molten lead-base alloys. Includes those cases in which aluminum is used to remove arsenic, nickel and antimony.
EC No.:
273-700-9
| CAS No.:
69011-59-2
Lead, antimonial, dross
A scum formed on the surface of antimonial lead. Consists primarily of sodium arsenate and sodium antimonate with some lead oxide and free caustic soda.
EC No.:
273-795-7
| CAS No.:
69029-51-2
Flue dust, lead-refining
By-product of refining lead ores obtained from baghouse and electro-static precipitator and as slurry from scrubbers.
EC No.:
273-809-1
| CAS No.:
69029-67-0
Disodium 3,6-bis[(o-arsonophenyl)azo]-4,5-dihydroxynaphthalene-2,7-disulphonate
EC No.:
263-516-7
| CAS No.:
62337-00-2
4-(diethylamino)-2-ethoxybenzenediazonium hexafluoroarsenate
EC No.:
264-027-1
| CAS No.:
63217-33-4
Disodium 3-[(o-arsonophenyl)azo]-4,5-dihydroxynaphthalene-2,7-disulphonate
EC No.:
222-600-3
| CAS No.:
3547-38-4
Disodium 4-[(o-arsonophenyl)azo]-3-hydroxynaphthalene-2,7-disulphonate
EC No.:
222-993-1
| CAS No.:
3688-92-4
2,7-(bis(2-arsonophenylazo))-1,8-dihydroxynaphthalene-3,6-disulphonic acid
EC No.:
216-788-6
| CAS No.:
1668-00-4
4-[(2-arsonophenyl)azo]-3-hydroxynaphthalene-2,7-disulphonic acid
EC No.:
205-058-2
| CAS No.:
132-33-2
Disodium hydrogen 2-[[7-[(2-arsonophenyl)azo]-1,8-dihydroxy-3,6-disulphonato-2-naphthyl]azo]benzoate
EC No.:
238-715-7
| CAS No.:
14674-83-0
Trisodium 4-[(o-arsonophenyl)azo]-3-oxidonaphthalene-2,7-disulphonate
EC No.:
258-693-2
| CAS No.:
53669-45-7
Disodium 3,6-bis[[2-[(dihydroxyarsino)oxy]phenyl]azo]-4,5-dihydroxynaphthalene-2,7-disulphonate
EC No.:
282-453-6
| CAS No.:
84215-47-4
Disodium 3-[[2-[(dihydroxyarsino)oxy]phenyl]azo]-4,5-dihydroxynaphthalene-2,7-disulphonate
EC No.:
282-454-1
| CAS No.:
84215-48-5
Tetraphenylarsonium chloride, compound with hydrochloric acid (1:1)
EC No.:
277-208-5
| CAS No.:
73003-83-5
Methyl 17α-hydroxyyohimban-16α-carboxylate, methylarsonate (1:1)
EC No.:
279-628-4
| CAS No.:
80925-03-7
[4-[(4,6-diamino-1,3,5-triazin-2-yl)amino]phenyl]arsonic acid
EC No.:
227-365-0
| CAS No.:
5806-89-3
Methyl 1,2,5,6-tetrahydro-1-methylnicotinate, mono[(3-acetamido-4-hydroxyphenyl)arsonate]
EC No.:
212-983-5
| CAS No.:
900-77-6
Disodium [4-[(4,6-diamino-1,3,5-triazin-2-yl)amino]phenyl]arsonate
EC No.:
222-749-4
| CAS No.:
3599-28-8
2-[[7-[(2-arsonophenyl)azo]-1,8-dihydroxy-3,6-disulpho-2-naphthyl]azo]benzoic acid
EC No.:
223-216-9
| CAS No.:
3772-44-9
Sodium p-[[4-[3-(2-arsono-4-nitrophenyl)triazen-1-yl]phenyl]azo]benzenesulphonate
EC No.:
217-197-6
| CAS No.:
1772-02-7
Trisodium 2-(-hydrogen arsonatophenylazo)-1,8-dihydroxynaphthalene-3,6-disulphonate
EC No.:
208-285-5
| CAS No.:
520-10-5
Silicic acid (H4SiO4), tetraethyl ester, polymer with arsenic oxide (As2O3)
EC No.:
-
| CAS No.:
68957-75-5
Silicic acid (H4SiO4), magnesium manganese(2+) zinc salt, arsenic and lead-doped
EC No.:
-
| CAS No.:
68784-76-9
Trisodium 3-[(o-arsonatophenyl)azo]-4,5-dihydroxynaphthalene-2,7-disulphonate
EC No.:
266-069-6
| CAS No.:
66019-20-3
Leucomycin V, 9-O-[5-(dimethylamino)tetrahydro-6-methyl-2H-pyran-2-yl]-, [9(5S,6R)]-, [1,2-ethanediylbis(imino-4,1-phenylene)]bis[arsonate] (1:1) (salt)
EC No.:
299-051-1
| CAS No.:
93841-79-3
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Disodium [[N,N'-ethylenebis[N-(carboxymethyl)glycinato]](4-)-N,N',O,O',ON,ON']cadmate(2-)
EC No.:
252-736-9
| CAS No.:
35803-35-1
Potassium [N,N-bis(carboxymethyl)glycinato(3-)-N,O,O',O'']cadmate(1-)
EC No.:
256-488-2
| CAS No.:
49784-42-1
Cadmium sulfoselenide red
This substance is identified in the Colour Index by Colour Index Constitution Number, C.I. 77202.
EC No.:
261-218-1
| CAS No.:
58339-34-7
(S)-dichloro[2-[[(2,3-dihydroxypropoxy)hydroxyphosphinyl]oxy]triethylmethylammoniumato]cadmium
EC No.:
265-010-1
| CAS No.:
64681-08-9
Bis(propane-1,2-diyldiamine-N,N')cadmium(2+) bis[bis(cyano-C)aurate(1-)]
EC No.:
267-692-6
| CAS No.:
67906-19-8
Tetrapotassium [[[nitrilotris(methylene)]tris[phosphonato]](6-)-N,O,O'',O'''']cadmate(6-)
EC No.:
268-020-4
| CAS No.:
67989-93-9
Pentapotassium hydrogen [[[ethylenebis[nitrilobis(methylene)]]tetrakis[phosphonato]](8-)]cadmate(6-)
EC No.:
269-685-3
| CAS No.:
68309-98-8
Cadmium sulfide (CdS), solid soln. with zinc sulfide, copper and lead-doped
EC No.:
269-773-1
| CAS No.:
68332-81-0
Pyrochlore, bismuth cadmium ruthenium
An inorganic pigment that is the reaction product of high temperature calcination in which bismuth oxide, cadmium oxide, and ruthenium oxide in varying amounts are homogeneously and ionically interdiffused to form a crystalline matrix of pyrochlore.
EC No.:
270-855-4
| CAS No.:
68479-13-0
Cadmium sulfide (CdS), solid soln. with zinc sulfide, aluminum and cobalt and copper and silver-doped
EC No.:
272-220-7
| CAS No.:
68784-10-1
Barium cadmium calcium chloride fluoride phosphate, antimony and manganese-doped
EC No.:
272-257-9
| CAS No.:
68784-55-4
Hydrogen [4-[(5-chloro-4-methyl-2-sulphophenyl)azo]-3-hydroxynaphthalene-2-carboxylato(3-)]cadmate(1-)
EC No.:
273-461-0
| CAS No.:
68966-97-2
Cadmium, dross
A scum formed on the surface of molten cadmium.
EC No.:
273-707-7
| CAS No.:
69011-69-4
Wastewater, cadmium sulfate electrolytic, acid
Electrolytic solution from electrolysis of cadmium sulfate consisting primarily of cadmium sulfate and sulfuric acid.
EC No.:
273-721-3
| CAS No.:
69012-21-1
Flue dust, cadmium-refining
By-product of refining of cadmium consisting primarily of oxides and chlorides of cadmium, lead, arsenic and zinc.
EC No.:
273-754-3
| CAS No.:
69012-57-3
Calcines, cadmium residue
Product of the roasting of cadmium-enriched lead smelting dusts to remove cadmium. Consists primarily of oxides and sulfates of lead and zinc.
EC No.:
273-806-5
| CAS No.:
69029-63-6
Leach residues, cadmium-refining
Product of leaching calcine and sump tank mud from lead ore refining with sulfuric acid. Consists primarily of lead sulfate and cadmium arsenate.
EC No.:
273-811-2
| CAS No.:
69029-70-5
Residues, cadmium-refining
Product from the washing of sweeps and cleanings from a cadmium plant. Consists primarily of metallic cadmium and iron.
EC No.:
273-819-6
| CAS No.:
69029-77-2
Slimes and Sludges, cadmium-refining, oxidized
Product of adding oxidizer to solution in the cadmium plant. Consists primarily of hydroxides of cadmium, thallium and indium and cadmium arsenate.
EC No.:
273-831-1
| CAS No.:
69029-90-9
Slimes and Sludges, cadmium sump tank
Product of adding sodium carbonate to solutions in the cadmium plant. Consists primarily of cadmium carbonate with lesser amounts of carbonates and hydroxides of other nonferrous metals.
EC No.:
273-832-7
| CAS No.:
69029-91-0
Cadmium potassium 1-(hydroxyethylidene)bisphosphonate(1:2:1)
EC No.:
273-906-9
| CAS No.:
69190-99-4
Tetra-μ-chlorodichlorobis[2-[[(2,3-dihydroxypropoxy)hydroxyphosphinyl]oxy]triethylmethylammoniumato]tricadmium, stereoisomer
EC No.:
276-100-5
| CAS No.:
71861-27-3
Cadmium zinc lithopone yellow
This substance is identified in the Colour Index by Colour Index Constitution Number, C.I. 77205:1.
EC No.:
292-385-9
| CAS No.:
90604-89-0
Cadmium lithopone yellow
This substance is identified in the Colour Index by Colour Index Constitution Number, C.I. 77199:1.
EC No.:
292-386-4
| CAS No.:
90604-90-3
Leach residues, cadmium cake
Residues obtained by cementation of cadmium by iron dust out of cadmium sulfate solutions. Composed primarily of metallic cadmium and zinc.
EC No.:
293-309-7
| CAS No.:
91053-44-0
Leach residues, zinc ore-calcine, cadmium-copper ppt.
Insoluble material precipitated by hydrolysis during hydrometallurgical treatment of crude zinc sulfate solution. Consists primarily of cadmium, cobalt, copper, lead, manganese, nickel, thallium, tin and zinc.
EC No.:
293-311-8
| CAS No.:
91053-46-2
Leach residues, cadmium-contg. flue dust
The substance formed during oxidative leaching of cadmium containing flue dust. Consists primarily of cadmium, lead and zinc compounds with chlorine, oxygen and sulfur and contains other nonferrous metal compounds.
EC No.:
305-417-4
| CAS No.:
94551-70-9
Leach residues, zinc refining flue dust, cadmium-thallium ppt.
Sponge produced by leaching and precipitating cadmium and thallium fumes and flue dusts from lead/zinc smelting operations.
EC No.:
296-097-4
| CAS No.:
92257-11-9
Fatty acids, C14-18 and C18-unsatd., branched and linear, hydrogenated, cadmium salts
EC No.:
296-564-2
| CAS No.:
92797-28-9
Flue dust, lead-manufg., cadmium-rich
Residue obtained in the metallurgical treatment of lead concentrate in a lead blast furnace. The substance is composed of cadmium oxides, lead oxides, and impurities containing compounds of arsenic, chlorine, indium and tellurium.
EC No.:
285-554-3
| CAS No.:
85117-02-8
Waste solids, cadmium-electrolysis, thallium-rich
Residue obtained in the electrolysis of cadmium, composed primarily of thallium chromate. Other non-ferrous metals or metal compounds may also be present.
EC No.:
285-572-1
| CAS No.:
85117-20-0
Benzenesulfonic acid, mono-C10-13-alkyl derivs., cadmium salts
EC No.:
290-645-6
| CAS No.:
90194-35-7
Flue dust, copper-lead blast furnace, cadmium-indium-enriched
A cadmium-indium-enriched product obtained from the recirculation of copper-lead blast furnace flue dusts. Composed primarily of cadmium, indium and lead.
EC No.:
309-645-5
| CAS No.:
100656-55-1
Cadmium oxide (CdO), solid soln. with calcium oxide and titanium oxide (TiO2), praseodymium-doped
EC No.:
309-896-0
| CAS No.:
101356-99-4
Cadmium selenide (CdSe), solid soln. with cadmium sulfide, zinc selenide and zinc sulfide, aluminum and copper-doped
EC No.:
309-897-6
| CAS No.:
101357-00-0
Cadmium selenide (CdSe), solid soln. with cadmium sulfide, zinc selenide and zinc sulfide, copper and manganese-doped
EC No.:
309-898-1
| CAS No.:
101357-01-1
Cadmium selenide (CdSe), solid soln. with cadmium sulfide, zinc selenide and zinc sulfide, europium-doped
EC No.:
309-899-7
| CAS No.:
101357-02-2
Cadmium selenide (CdSe), solid soln. with cadmium sulfide, zinc selenide and zinc sulfide, gold and manganese-doped
EC No.:
309-900-0
| CAS No.:
101357-03-3
Cadmium selenide (CdSe), solid soln. with cadmium sulfide, zinc selenide and zinc sulfide, manganese and silver-doped
EC No.:
309-901-6
| CAS No.:
101357-04-4
Cadmium oxide (CdO), solid soln. with magnesium oxide, tungsten oxide (WO3) and zinc oxide
EC No.:
310-029-3
| CAS No.:
102110-30-5
Cadmium zinc sulfide yellow
This substance is identified in the Colour Index by Colour Index Constitution Number, C.I. 77205.
EC No.:
232-466-8
| CAS No.:
8048-07-5
Cadmium sulfoselenide orange
This substance is identified in the Colour Index by Colour Index Constitution Number, C.I. 77202.
EC No.:
235-758-3
| CAS No.:
12656-57-4
Dipotassium [[N,N'-ethylenebis[N-(carboxymethyl)glycinato]](4-)-N,N',O,O',ON,ON']cadmate(2-)
EC No.:
239-801-7
| CAS No.:
15708-29-9
Hydrogen [N,N-bis(carboxymethyl)glycinato(3-)-N,O,O',O'']cadmate
EC No.:
256-489-8
| CAS No.:
49784-44-3
Cadmium sulfide (CdS), solid soln. with zinc sulfide, copper chloride-doped
EC No.:
270-977-8
| CAS No.:
68512-49-2
Cadmium sulfide (CdS), solid soln. with zinc sulfide, copper and manganese-doped
EC No.:
270-978-3
| CAS No.:
68512-50-5
Cadmium sulfide (CdS), solid soln. with zinc sulfide, aluminum and copper-doped
EC No.:
270-979-9
| CAS No.:
68512-51-6
Cadmium sulfide (CdS), solid soln. with zinc sulfide, copper and silver-doped
EC No.:
271-511-6
| CAS No.:
68583-43-7
Cadmium sulfide (CdS), solid soln. with zinc sulfide, nickel and silver-doped
EC No.:
271-512-1
| CAS No.:
68583-44-8
Cadmium sulfide (CdS), solid soln. with zinc sulfide, silver chloride-doped
EC No.:
271-513-7
| CAS No.:
68583-45-9
Cadmium sulfide (CdS), solid soln. with zinc sulfide, aluminum and silver-doped
EC No.:
271-538-3
| CAS No.:
68584-41-8
Cadmium sulfide (CdS), solid soln. with zinc sulfide, copper and nickel-doped
EC No.:
271-539-9
| CAS No.:
68584-42-9
Cadmium, (29H,31H-phthalocyaninato(2-)-kappaN29,kappaN30,kappaN31,kappaN32)-, (SP-4-1)-
EC No.:
622-643-1
| CAS No.:
21328-74-5
Benzenediazonium, 4-(phenylamino)-, sulfate (1:1), polymer with formaldehyde, cadmium chloride complexes
EC No.:
-
| CAS No.:
68441-39-4
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