Registration Dossier

Data platform availability banner - registered substances factsheets

Please be aware that this old REACH registration data factsheet is no longer maintained; it remains frozen as of 19th May 2023.

The new ECHA CHEM database has been released by ECHA, and it now contains all REACH registration data. There are more details on the transition of ECHA's published data to ECHA CHEM here.

Diss Factsheets

Physical & Chemical properties

Boiling point

Currently viewing:

Administrative data

Link to relevant study record(s)

Referenceopen allclose all

Endpoint:
boiling point
Type of information:
experimental study
Adequacy of study:
key study
Study period:
From January 30, 2012 to February 02, 2012
Reliability:
2 (reliable with restrictions)
Rationale for reliability incl. deficiencies:
guideline study with acceptable restrictions
Qualifier:
according to guideline
Guideline:
EU Method A.2 (Boiling Temperature)
Deviations:
yes
Remarks:
see Principles of method if other than guideline
Qualifier:
according to guideline
Guideline:
OECD Guideline 103 (Boiling point/boiling range)
Deviations:
yes
Remarks:
see Principles if other than method
Principles of method if other than guideline:
For the tests on the melting and boiling point, two test series were performed in an atmosphere of air. The temperature maxima were chosen from the data of the tests on DDAC (Report no. CSL-11-0392.01) in order to investigate the processes also expected for the test substance:
1. The crucibles were heated up from 0°C to 80°C, 140°C, 210°C, 240°C and 300°C, respectively, with a heating rate of 3 K/min. Five measurements with fresh samples each were performed up to the maximum temperatures. When the maximum temperatures were reached, the DSC-apparatus were opened for visual inspection of the crucibles.
2. In the second test series, the samples were heated up from 0°C to the maximum temperatures with a heating rate of 3 K/min and cooled down again with a cooling rate of 3 K/min without opening the DSC-apparatus. The first of three measurements were performed with one sample, which was heated up three times to the maximum temperatures (80°C, 140°C and 210°C) and cooled down to 0°C again. The other two measurements were performed with fresh samples, which were heated up from 0°C to 240°C and 300°C, respectively, and cooled down to 25°C.
GLP compliance:
yes (incl. QA statement)
Type of method:
differential thermal analysis
Remarks:
Differential Scanning Calorimetry (DSC)
Key result
Atm. press.:
ca. 1 013 hPa
Decomposition:
yes
Decomp. temp.:
> 160 °C

First test series:

RT – 80°C: In the temperature range of 30 – 50°C an endothermic effect was detected. At 80°C the test substance was melted and its colour was unchanged. A slight mass loss of 0.09 mg (0.5 %) could be measured. This endothermic effect can be attributed to the melting of the test substance.

RT – 140°C: In the temperature range of 30 – 45°C an endothermic effect was detected which can be attributed to the melting of the test substance. At 140°C the test substance was melted and its colour was still slightly yellow. A slight mass loss of 0.2 mg (0.9 %) could be measured.

RT – 210°C: In the temperature range of 30 – 45°C an endothermic effect was detected which can be attributed to the melting of the test substance. The measurement showed a second endothermic effect in the temperature range of 160 – 210°C. At 210°C the colour of the test substance changed to slightly brown and a mass loss of 12.06 mg (48 %) could be measured.

RT – 240°C: In the temperature range of 30 – 50°C an endothermic effect was detected which can be attributed to the melting of the test substance. The measurement showed a second endothermic effect in the temperature range of 170 – 240°C. At 240°C the colour of the test substance changed to dark brown and a mass loss of 19.39 mg (75 %) could be measured.

RT – 300°C: In the temperature range of 30 – 45°C an endothermic effect was detected which can be attributed to the melting of the test substance. The measurement showed a second endothermic effect in the temperature range of 165 – 245°C. In the temperature range of 270 – 295 °C an exothermal effect could be observed. At 300°C the colour of the test substance changed to black and a mass loss of 28.02 mg (98 %) could be measured.

Second test series:

0 – 80 – 0 – 140 – 0 – 210 – 25°C: During heating up from 0 °C to 80 °C an endothermic effect in the temperature range of 25 – 50°C was observed. During cooling down from 80°C to 0°C, the subsequent heating up from 0°C to 140°C and cooling down again from 140°C to 0°C neither endothermic nor exothermic effects were observed. During the subsequent heating up to 210°C an endothermic effect could be observed in the temperature range of 175 – 210°C. The cooling down to 25°C showed no thermal effect. A mass loss of 12.35 mg (49 %) could be measured.

0 – 240 – 25 °C: During heating up from 0 °C to 240 °C a first endothermic effect in the temperature range from 25 – 50 °C and a second endothermic effect in the temperature range of approximately 160 – 240 °C was observed. During cooling down from 240 °C to 25 °C neither endothermic nor exothermic effects were observed. A mass loss of 27.13 mg (100 %) could be measured.

0 – 300 – 25°C: During heating up from 0°C to 300°C a first endothermic effect in the temperature range from 25 – 50°C and a second endothermic effect in the temperature range of 150 – 250°C was observed. In the temperature range of approximately 260 – 295°C an exothermal effect was measured. During cooling down from 300°C to 25°C neither endothermic nor exothermic effects were observed. A mass loss of 25.57 mg (98 %) could be measured.

Conclusions:
Under the study conditions, the test substance had no boiling point at atmospheric pressure (1013 hPa). The test substance decomposed before boiling at a temperature of >160°C (DSC).
Executive summary:

A study was concducted to determine the boiling point of the test substance, C12-16 ADBAC (purity: 99.2%) according to OECD Guideline 103 and EU Method A.2, in compliance with GLP. Differential scanning calorimetry (DSC) was used in this experiment. For the tests, two test series were performed in an atmosphere of air. The temperature maxima were chosen from the data of the tests on DDAC (Report no. CSL-11-0392.01) in order to investigate the processes also expected with the test substance. In the first experiement, the crucibles were heated up from 0°C to 80°C, 140°C, 210°C, 240°C and 300°C, respectively, with a heating rate of 3 K/min. Five measurements with fresh samples each were performed up to the maximum temperatures. When the maximum temperatures were reached, the DSC-apparatus were opened for visual inspection of the crucibles. In the second experiement, the samples were heated up from 0°C to the maximum temperatures with a heating rate of 3 K/min and cooled down again with a cooling rate of 3 K/min without opening the DSC-apparatus. The first of three measurements were performed with one sample, which was heated up three times to the maximum temperatures (80°C, 140°C and 210°C) and cooled down to 0°C again. The other two measurements were performed with fresh samples, which were heated up from 0°C to 240°C and 300°C, respectively, and cooled down to 25°C. Under the study conditions, the test substance had no boiling point at atmospheric pressure (1013 hPa). The test substance decomposed before boiling at a temperature of >160°C (Moller, 2012).

Endpoint:
boiling point
Type of information:
experimental study
Adequacy of study:
supporting study
Study period:
1996
Reliability:
2 (reliable with restrictions)
Rationale for reliability incl. deficiencies:
comparable to guideline study with acceptable restrictions
Qualifier:
according to guideline
Guideline:
EU Method A.2 (Boiling Temperature)
Version / remarks:
ASTM E 537-86, ASTM E 473-93a and ASTM E 472-86, cited as Directive 92/69/EEC, A.2
Deviations:
no
GLP compliance:
no
Type of method:
differential scanning calorimetry
Key result
Boiling pt.:
102 °C
Atm. press.:
1 013 hPa
Decomposition:
no
Conclusions:
Under the study conditions, the boiling point of 50% aqueous solution of the test substance was found to be 102°C (DSC).
Executive summary:

A study was conducted to determine the melting point / freezing point of the test substance, C12-16 ADBAC (50% active in water) according to EU Method A.2 (Differential Scanning Calorimetry). Under the study conditions, the boiling point of the 50% aqueous solution of the test substance was found to be 102°C (Schuurman, 1996).

Description of key information

The boiling point was determined using the DSC method according to OECD Guideline 103 and EU Method A.2 (Moller, 2012 and Schuurman, 1996)

Key value for chemical safety assessment

Additional information

Pure substance: Decomposition at >160°C; no boiling temperature (BP) identified (Moller, 2012); 50% aqueous solution: BP = 102°C (Schuurman, 1986)