Registration Dossier

Administrative data

First-aid measures

General information
In case of accident or if you feel unwell, seek medical advice immediately. Remove contaminated clothing and shoes immediately, and launder thoroughly before reusing. If the patient is likely to become unconscious, place and transport in stable sideways position.
After inhalation
Remove affected person from the immediate area. Ensure supply of fresh air. Irregular breathing/no breathing: artificial respiration. Call a doctor immediately.
After skin contact
Wash off immediately with soap and water. Seek medical attention.
After eye contact
Separate eyelids, wash the eyes thoroughly with water (15 min.). Seek medical assistance.
After ingestion
Do not induce vomiting. Rinse out mouth and give plenty of water to drink. Call a doctor immediately. Never give anything by mouth to an unconscious person.

Fire-fighting measures

Extinguishing media
Suitable extinguishing media
Foam; Dry chemical extinguisher; Water spray jet
Unsuitable extinguishing media
High power water jet
Special hazards arising from the substance or mixture
In the event of fire, the following can be released: Carbon dioxide (CO2); Carbon monoxide (CO), nitrogene oxides
Advice for firefighters
Fire-fighting operations, rescue and clearing work under effect of combustion and smoulder gases just may be done with breathing apparatus. Wear protective clothing. Cool endangered containers with water spray jet. Run-off water from fire fighting must not be discharged into drains or enter surface water.

Accidental release measures

Personal precautions, protective equipment and emergency procedures
For non-emergency personnel
Refer to protective measures listed in sections 7 and 8. Avoid contact with skin, eyes and clothing. Ensure adequate ventilation.
For emergency responders
No data available. Personal protective equipment (PPE) - see Section 8.
Environmental precautions
Do not discharge into the drains/surface waters/groundwater. Do not discharge into the subsoil/soil.
Methods and material for containment and cleaning up
Take up with absorbent material (e.g., sand, kieselguhr, universal binder). When picked up, treat material as prescribed under heading "Disposal considerations".

Handling and storage

Precautions for safe handling
Advice on safe handling
Product inherent handling risks must be minimised taking the appropriate measures for protection and preventive actions. The working process should be designed to rule out the release of hazardous substances or skin contact as far it is possible by the state of the art.
General protective and hygiene measures
Do not eat, drink or smoke during work time. Keep away from foodstuffs and beverages. Avoid contact with eyes and skin. Remove soiled or soaked clothing immediately. Wash hands before breaks and after work. Provide eye wash fountain in work area. Have emergency shower available. Do not inhale vapours.
Advice on protection against fire and explosion
Keep away from sources of heat and ignition.
Conditions for safe storage, including any incompatibilities
Technical measures and storage conditions
Keep container tightly closed in a cool, well-ventilated place.
Requirements for storage rooms and vessels
Containers which are opened must be carefully closed and kept upright to prevent leakage. Always keep in containers of same material as the original one.
Advice on storage assembly
None known

Transport information

Land transport (ADR/RID)

UN number:
2735
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Class:
8
Packaging group:
II (precautionary)
No human data are available. Since the sole available animal study (Harada 2002) allows evaluation after 4 h exposure only, it cannot be excluded, that necrosis could appear after an exposure time of more than three minutes but not more than 60 minutes, which requires classification into group II. All 3 animals in the study of Harada (2002) showed 24 h after exposure uniformly full area necrosis (highest evaluation score 4), which persisted until day 7.
Pagaging gruop III is definetely required as the substance caused full thickness destruction of intact skin tissue within an observation period up to 14 days starting after the exposure time of more than 60 minutes but not more than 4 hours in accordance with UN Recommendations on the Transport of Dangerous Goods 14th edition (2006, Part 2).
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Marine transport (IMDG)

UN number:
2735
Class:
8
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Air transport ICAO/IATA

UN number:
2735
Class:
8
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Exposure controls / personal protection

Appropriate engineering controls
No data available.
Personal protective equipment
Respiratory protection
Local exhaust ventilation required for open use. If workplace exposure limits are exceeded, a respiration protection approved for this particular job must be worn. In case of aerosol and mist formation, take appropriate measures for breathing protection in the event workplace threshold values are not specified. Breathing apparatus: gas filter A, code colour: brown
Eye / face protection
Safety glasses with side protection shield (EN 166)
Hand protection
Sufficient protection is given wearing suitable protective gloves checked according to i.e. EN 374, in the event of risk of skin contact with the product . Check in any case suitability of protective glove for the specific workplace conditions (e.g. mechanical resistance, product compatibility, antistatic properties). Adhere to the manufacturer’s instructions and information relating to the use, storage, care and replacement of protective gloves.
Appropriate Material neoprene
Other
Normal chemical work clothing. Check suitability of protective clothing for the specific workplace conditions. Chemical resistance of the protective equipment should be discussed with the manufacturer of the protective equipment.
Environmental exposure controls
No data available.

Stability and reactivity

Reactivity
No data available.
Chemical stability
No data available.
Possibility of hazardous reactions
No data available.
Conditions to avoid
None known
Incompatible materials
None known.
Hazardous decomposition products
no hazardous decomposition products known

Disposal considerations

Waste treatment methods
Product
Allocation of a waste code number, according to the European Waste Catalogue, should be carried out in agreement with the regional waste disposal company.
Packaging
Residuals must be removed from packaging and when emptied completely disposed of in accordance with the regulations for waste removal. Incompletely emptied packaging must be disposed of in the form of disposal specified by the regional disposer.