Registration Dossier

Administrative data

First-aid measures

Description of first aid measures
Inhalation
Keep at rest. Aerate with fresh air. When symptoms persist or in all cases of doubt seek medical advice.
Skin
Wash off immediately with plenty of water for at least 15 minutes. When symptoms persist or in all cases of doubt seek medical advice.
Eyes
Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Remove contact lenses. Immediate medical attention is required.
Ingestion
Call a physician immediately. Do not induce vomiting without medical advice.

Most important symptoms and effects, both acute and delayed
Main symptoms: cough, nausea, gastrointestinal discomfort, vomiting.
Special hazard: Lung irritation, Liver effects, Kidney disorders.

Indication of any immediate medical attention and special treatment needed
General advice: Remove contaminated, soaked clothing immediately and dispose of safely. First aider needs to protect himself.

Treat symptomatically. If ingested, irrigate the stomach using activated charcoal.

Fire-fighting measures

Extinguishing media
Suitable extinguishing media: alcohol-resistant foam, dry chemical, carbon dioxide (CO2), water spray.
Unsuitable Extinguishing Media: Do not use a solid water stream as it may scatter and spread fire.


Special hazards arising from the substance or mixture
Under conditions giving incomplete combustion, hazardous gases produced may consist of: carbon monoxide (CO), carbon dioxide (CO2).

Combustion gases of organic materials must in principle be graded as inhalation poisons
Vapours are heavier than air and may spread along floors
Vapour/air-mixtures are explosive at intense warming


Advice for firefighters
Special protective equipment for firefighters: Fire fighter protection should include a self-contained breathing apparatus (NIOSH-approved or EN 133) and full fire-fighting turn out gear.
Precautions for firefighting: Cool containers / tanks with water spray. Dike and collect water used to fight fire. Keep people away from and upwind of fire.

Accidental release measures

Personal precautions, protective equipment and emergency procedures
For non-emergency personnel: For personal protective equipment see SDS. Avoid contact with skin and eyes.
Avoid breathing vapors or mists. Keep people away from and upwind of spill/leak. Ensure adequate ventilation, especially in confined areas. Keep away from heat and sources of ignition. For emergency responders: Personal protection see SDS.

Environmental precautions
Prevent further leakage or spillage. Do not discharge product into the aquatic environment without pretreatment (biological treatment plant).

Methods and material for containment and cleaning up
Methods for containment: Stop the flow of material, if possible without risk. Dike spilled material, where this is possible.
Methods for cleaning up: Soak up with inert absorbent material. Keep in suitable, closed containers for disposal. If liquid has been spilt in large quantities clean up promptly by scoop or vacuum. Dispose of in accordance with local regulations. Take necessary action to avoid static electricity discharge (which might cause ignition of organic vapours).

Handling and storage

Precautions for safe handling
Advice on safe handling: Avoid contact with skin, eyes and clothing. Wash hands before breaks and immediately after handling the product. Provide sufficient air exchange and/or exhaust in work rooms.

Hygiene measures. When using, do not eat, drink or smoke. Take off all contaminated clothing immediately. Wash hands before breaks and immediately after handling the product.

Incompatible products: strong acids, strong oxidizing agents.

Conditions for safe storage, including any incompatibilities

Advice on protection against fire and explosion: Keep away from sources of ignition - No smoking. Take necessary action to avoid static electricity discharge (which might cause ignition of organic vapours). In case of fire, emergency cooling with water spray should be available. Ground and bond containers when transferring material. Vapour/air-mixtures are explosive at intense warming.

Technical measures/Storage conditions: Keep containers tightly closed in a cool, well-ventilated place. Handle and open container with care.

Temperature class: T2

Transport information

Land transport (ADR/RID)

Proper shipping name and description:
not restricted
SpecialProvisionsopen allclose all

Inland waterway transport (ADN(R))

UN number:
ID 9006
Proper shipping name and description:
ADN Tanker

Environmentally hazardous substance, liquid, n.o.s.
Class:
9
N3, F
Remarksopen allclose all

Marine transport (IMDG)

Proper shipping name and description:
not restricted
Remarksopen allclose all

Air transport ICAO/IATA

Proper shipping name and description:
not restricted
Remarksopen allclose all
SpecialProvisionsopen allclose all

Exposure controls / personal protection

Appropriate Engineering controls
General or dilution ventilation is frequently insufficient as the sole means of controlling employee exposure. Local ventilation is usually preferred. Explosion-proof equipment (for example fans, switches, and grounded ducts) should be used in mechanical ventilation systems. Engineering and risk Management measures should maintain strictly controlled conditions. This also applies to environmental exposure controls.

Personal protective equipment
General industrial hygiene practice: Avoid contact with skin, eyes and clothing. Do not breathe dust or mist. Ensure that eyewash stations and safety showers are close to the workstation location.

Hygiene measures: When using, do not eat, drink or smoke. Take off all contaminated clothing immediately. Wash hands before breaks and immediately after handling the product.

Eye protection
Tightly fitting safety goggles. In addition to goggles, wear a face shield if there is a reasonable chance for splash to the face. Equipment should conform to EN 166

Hand protection: Wear protective gloves. Recommendations are listed below. Other protective material may be used, depending on the situation, if adequate degradation and permeation data is available. If other chemicals are used in conjunction with this chemical, material selection should be based on protection for all chemicals present.

Suitable material: nitrile rubber
Reference substance: 2-Ethylhexanol
Evaluation: according to EN 374: level 6
Glove thickness: approx 0,55 mm
Break through time: > 480 min
Suitable material: polyvinylchloride / nitrile rubber
Reference substance: 2-Ethylhexanol
Evaluation: according to EN 374: level 6
Glove thickness: approx 0,9 mm
Break through time: > 480 min

Skin and body protection: Impervious clothing. Wear face-shield and protective suit for abnormal processing problems.

Respiratory protection: Respirator with A filter. Full mask with above mentioned filter according to producers using requirements or self-contained breathing apparatus. Equipment should conform to EN 136 or EN 140 and EN 143.

Environmental exposure controls: If possible use in closed systems. If leakage can not be prevented, the substance needs to be suck off at the emersion point, if possible without danger. If recycling is not practicable, dispose of in compliance with local regulations. Inform the responsible authorities in case of leakage into the atmosphere, or of entry into waterways, soil or drains.

Stability and reactivity

Reactivity: The reactivity of the product corresponds to the typical reactivity shown by the substance group as described in any text book on organic chemistry.

Chemical stability: Stable under recommended storage conditions.

Possibility of hazardous reactions: Vapour/air-mixtures are explosive at intense warming. Hazardous polymerisation does not occur.

Conditions to avoid: Avoid contact with heat, sparks, open flame and static discharge. Avoid any source of ignition.

Incompatible materials: strong acids, strong oxidizing agents.

Hazardous decomposition products: No decomposition if used as directed.

Disposal considerations

Product Information: Disposal required in compliance with all waste management related state and local regulations. The choice of the appropriate method of disposal depends on the product composition by the time of disposal as well as the local statutes and possibilities for disposal.
Hazardous waste according to European Waste Catalogue (EWC)

Uncleaned empty packaging: Contaminated packaging should be emptied as far as possible and after appropriate cleansing may be taken for reuse.