Registration Dossier

Administrative data

Endpoint:
auto-flammability
Type of information:
experimental study
Adequacy of study:
key study
Study period:
04 May 2004
Reliability:
1 (reliable without restriction)
Rationale for reliability incl. deficiencies:
other: Study conducted in compliance with agreed protocols, with no or minor deviations from standard test guidelines and/or minor methodological deficiencies, which do not affect the quality of relevant results.

Data source

Reference
Reference Type:
study report
Title:
Unnamed
Year:
2004
Report Date:
2004

Materials and methods

Test guideline
Qualifier:
according to
Guideline:
EU Method A.15 (Auto-Ignition Temperature (Liquids and Gases))
Deviations:
no
GLP compliance:
yes (incl. certificate)
Remarks:
(Date of inspection: 02 December 2002, Date of signature: 13 February 2003)

Test material

Reference
Name:
Unnamed
Type:
Constituent
Details on test material:
- Name of test material (as cited in study report): TIPX
- Substance type: Colourless liquid.
- Physical state: Liquid.
- Lot/batch No.: 042028.
- Storage condition of test material: Approximately 4ºC in the dark.

Results and discussion

Auto-ignition temperature (liquids / gases)
Auto-ignition temperature:
236 °C
Atm. press.:
101.54 - 102.55 kPa
Remarks on result:
other: Room temperature:      18 to 23°C Atmospheric pressure: 101.54 to 102.55kPa

Any other information on results incl. tables

Results

Test Temperature (ºC)

Test Volume (µl)

Ignition Delay (s)

Observations

50 (clean flask)

70

>300

No ignition.

100 (clean flask)

70

>300

No ignition.

150

70

>300

No ignition. Grey fumes were emitted.

200

70

>300

No ignition. Grey fumes were emitted.

250

70

>300

No ignition. Grey fumes were emitted.

300

70

>300

No ignition. Grey fumes were emitted.

350 (clean flask)

70

3

An orange flame. Grey fumes were emitted.

340

70

6

An orange flame. Grey fumes were emitted.

330 (clean flask)

70

8

An orange flame. Grey fumes were emitted.

320

70

12

An orange flame. Grey fumes were emitted.

310

70

>300

No ignition. Grey fumes were emitted.

316

70

>300

No ignition. Grey fumes were emitted.

318

70

14

An orange flame. Grey fumes were emitted.

316 (clean flask)

200

9

An orange flame. Grey fumes were emitted.

314 (clean flask)

200

8

An orange flame. Grey fumes were emitted.

312 (clean flask)

200

10

An orange flame. Grey fumes were emitted.

310 (clean flask)

200

10

An orange flame. Grey fumes were emitted.

308 (clean flask)

200

10

An orange flame. Grey fumes were emitted.

306 (clean flask)

200

10

An orange flame. Grey fumes were emitted.

304 (clean flask)

200

13

An orange flame. Grey fumes were emitted.

300 (clean flask)

200

17

An orange flame. Grey fumes were emitted.

280 (clean flask)

200

40

An orange flame. Grey fumes were emitted.

250

200

>300

No ignition. Grey fumes were emitted.

260 (clean flask)

200

>300

No ignition. Grey fumes were emitted.

266

200

>300

No ignition. Grey fumes were emitted.

274

200

>300

No ignition. Grey fumes were emitted.

278

200

49

An orange flame. Grey fumes were emitted.

276

200

55

An orange flame. Grey fumes were emitted.

274 (clean flask)

200

64

An orange flame. Grey fumes were emitted.

272

200

70

An orange flame. Grey fumes were emitted.

270

200

80

An orange flame. Grey fumes were emitted.

268 (clean flask)

200

110

An orange flame. Grey fumes were emitted.

266

200

>300

No ignition. Grey fumes were emitted.

266 (clean flask)

200

>300

No ignition. Grey fumes were emitted.

266 (clean flask)

400

71

An orange flame. Grey fumes were emitted.

260 (clean flask)

400

92

An orange flame. Grey fumes were emitted.

254 (clean flask)

400

156

An orange flame. Grey fumes were emitted.

246

400

>300

No ignition. Grey fumes were emitted.

250

400

>300

No ignition. Grey fumes were emitted.

252

400

>300

No ignition. Grey fumes were emitted.

252 (clean flask)

400

>300

No ignition. Grey fumes were emitted.

252 (clean flask)

600

98

An orange flame. Grey fumes were emitted.

248 (clean flask)

600

151

An orange flame. Grey fumes were emitted.

244 (clean flask)

600

>300

No ignition. Grey fumes were emitted.

246

600

201

An orange flame. Grey fumes were emitted.

244 (clean flask)

800

>300

No ignition. Grey fumes were emitted.

244 (clean flask)

1000

186

An orange flame. Grey fumes were emitted.

242

1000

>300

No ignition. Grey fumes were emitted.

242 (clean flask)

1000

>300

No ignition. Grey fumes were emitted.

242 (clean flask)

1200

>300

No ignition. Grey fumes were emitted.

242 (clean flask)

1400

>300

No ignition. Grey fumes were emitted.

242 (clean flask)

1600

156

An orange flame. Grey fumes were emitted.

240

1600

232

An orange flame. Grey fumes were emitted.

238

1600

>300

No ignition. Grey fumes were emitted.

238 (clean flask)

1600

>300

No ignition. Grey fumes were emitted.

238 (clean flask)

1800

183

An orange flame. Grey fumes were emitted.

236

1800

>300

No ignition. Grey fumes were emitted.

236 (clean flask)

1800

>300

No ignition. Grey fumes were emitted.

236 (clean flask)

2000

152

An orange flame. Grey fumes were emitted.

234 (clean flask)

2000

>300

No ignition. Grey fumes were emitted.

234 (clean flask)

2200

>300

No ignition. Grey fumes were emitted.

234 (clean flask)

2400

>300

No ignition. Grey fumes were emitted.

234 (clean flask)

2600

>300

No ignition. Grey fumes were emitted.

234 (clean flask)

2800

>300

No ignition. Grey fumes were emitted.

Applicant's summary and conclusion

Conclusions:
The test material has been determined to have an auto-ignition temperature of 236 ± 5°C.
Executive summary:

The test material has been determined to have an auto-ignition temperature of 236 ± 5°C using method A15.