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EC number: 202-992-2 | CAS number: 101-96-2
- Life Cycle description
- Uses advised against
- Endpoint summary
- Appearance / physical state / colour
- Melting point / freezing point
- Boiling point
- Density
- Particle size distribution (Granulometry)
- Vapour pressure
- Partition coefficient
- Water solubility
- Solubility in organic solvents / fat solubility
- Surface tension
- Flash point
- Auto flammability
- Flammability
- Explosiveness
- Oxidising properties
- Oxidation reduction potential
- Stability in organic solvents and identity of relevant degradation products
- Storage stability and reactivity towards container material
- Stability: thermal, sunlight, metals
- pH
- Dissociation constant
- Viscosity
- Additional physico-chemical information
- Additional physico-chemical properties of nanomaterials
- Nanomaterial agglomeration / aggregation
- Nanomaterial crystalline phase
- Nanomaterial crystallite and grain size
- Nanomaterial aspect ratio / shape
- Nanomaterial specific surface area
- Nanomaterial Zeta potential
- Nanomaterial surface chemistry
- Nanomaterial dustiness
- Nanomaterial porosity
- Nanomaterial pour density
- Nanomaterial photocatalytic activity
- Nanomaterial radical formation potential
- Nanomaterial catalytic activity
- Endpoint summary
- Stability
- Biodegradation
- Bioaccumulation
- Transport and distribution
- Environmental data
- Additional information on environmental fate and behaviour
- Ecotoxicological Summary
- Aquatic toxicity
- Endpoint summary
- Short-term toxicity to fish
- Long-term toxicity to fish
- Short-term toxicity to aquatic invertebrates
- Long-term toxicity to aquatic invertebrates
- Toxicity to aquatic algae and cyanobacteria
- Toxicity to aquatic plants other than algae
- Toxicity to microorganisms
- Endocrine disrupter testing in aquatic vertebrates – in vivo
- Toxicity to other aquatic organisms
- Sediment toxicity
- Terrestrial toxicity
- Biological effects monitoring
- Biotransformation and kinetics
- Additional ecotoxological information
- Toxicological Summary
- Toxicokinetics, metabolism and distribution
- Acute Toxicity
- Irritation / corrosion
- Sensitisation
- Repeated dose toxicity
- Genetic toxicity
- Carcinogenicity
- Toxicity to reproduction
- Specific investigations
- Exposure related observations in humans
- Toxic effects on livestock and pets
- Additional toxicological data
Toxicity to terrestrial plants
Administrative data
Link to relevant study record(s)
- Endpoint:
- toxicity to terrestrial plants: long-term
- Type of information:
- read-across from supporting substance (structural analogue or surrogate)
- Adequacy of study:
- key study
- Justification for type of information:
- Read-across from 7PPD, see read-across justification for more information.
- Reason / purpose for cross-reference:
- read-across source
- Species:
- Allium cepa
- Duration:
- 15 d
- Dose descriptor:
- NOEC
- Effect conc.:
- 97.5 mg/kg soil dw
- Nominal / measured:
- nominal
- Conc. based on:
- test mat.
- Basis for effect:
- seedling emergence
- Remarks on result:
- other: corrected for MW
- Species:
- Allium cepa
- Duration:
- 15 d
- Dose descriptor:
- NOEC
- Effect conc.:
- 97.5 mg/kg soil dw
- Nominal / measured:
- nominal
- Conc. based on:
- test mat.
- Basis for effect:
- other: survival
- Remarks on result:
- other: corrected for MW
- Species:
- Allium cepa
- Duration:
- 15 d
- Dose descriptor:
- NOEC
- Effect conc.:
- 48.8 mg/kg soil dw
- Nominal / measured:
- nominal
- Conc. based on:
- test mat.
- Basis for effect:
- other: shoot lenght
- Remarks on result:
- other: corrected for MW
- Species:
- Allium cepa
- Duration:
- 15 d
- Dose descriptor:
- NOEC
- Effect conc.:
- 48.8 mg/kg soil dw
- Nominal / measured:
- nominal
- Conc. based on:
- test mat.
- Basis for effect:
- other: shoot fresh weight
- Remarks on result:
- other: corrected for MW
- Species:
- Avena sativa
- Duration:
- 15 d
- Dose descriptor:
- NOEC
- Effect conc.:
- >= 390.1 mg/kg soil dw
- Nominal / measured:
- nominal
- Conc. based on:
- test mat.
- Basis for effect:
- seedling emergence
- Remarks on result:
- other: corrected for MW
- Species:
- Avena sativa
- Duration:
- 15 d
- Dose descriptor:
- NOEC
- Effect conc.:
- >= 390.1 mg/kg soil dw
- Nominal / measured:
- nominal
- Conc. based on:
- test mat.
- Basis for effect:
- other: survival
- Remarks on result:
- other: corrected for MW
- Species:
- Avena sativa
- Duration:
- 15 d
- Dose descriptor:
- NOEC
- Effect conc.:
- 97.5 mg/kg soil dw
- Nominal / measured:
- nominal
- Conc. based on:
- test mat.
- Basis for effect:
- other: shoot lenght
- Remarks on result:
- other: corrected for MW
- Species:
- Avena sativa
- Duration:
- 15 d
- Dose descriptor:
- NOEC
- Effect conc.:
- 97.5 mg/kg soil dw
- Nominal / measured:
- nominal
- Conc. based on:
- test mat.
- Basis for effect:
- other: shoot fresh weight
- Remarks on result:
- other: corrected for MW
- Species:
- Brassica napus
- Duration:
- 15 d
- Dose descriptor:
- NOEC
- Effect conc.:
- >= 97.5 mg/kg soil dw
- Nominal / measured:
- nominal
- Conc. based on:
- test mat.
- Basis for effect:
- seedling emergence
- Remarks on result:
- other: corrected for MW
- Species:
- Brassica napus
- Duration:
- 15 d
- Dose descriptor:
- NOEC
- Effect conc.:
- >= 97.5 mg/kg soil dw
- Nominal / measured:
- nominal
- Conc. based on:
- test mat.
- Basis for effect:
- other: survival
- Remarks on result:
- other: corrected for MW
- Species:
- Brassica napus
- Duration:
- 15 d
- Dose descriptor:
- NOEC
- Effect conc.:
- 6.1 mg/kg soil dw
- Nominal / measured:
- nominal
- Conc. based on:
- test mat.
- Basis for effect:
- other: shoot length
- Remarks on result:
- other: corrected for MW
- Species:
- Brassica napus
- Duration:
- 15 d
- Dose descriptor:
- NOEC
- Effect conc.:
- 24.4 mg/kg soil dw
- Nominal / measured:
- nominal
- Conc. based on:
- test mat.
- Basis for effect:
- other: shoot fresh weight
- Remarks on result:
- other: corrected for MW
- Species:
- Cucumis sativus
- Duration:
- 15 d
- Dose descriptor:
- NOEC
- Effect conc.:
- >= 97.5 mg/kg soil dw
- Nominal / measured:
- nominal
- Conc. based on:
- test mat.
- Basis for effect:
- seedling emergence
- Remarks on result:
- other: corrected for MW
- Species:
- Cucumis sativus
- Duration:
- 15 d
- Dose descriptor:
- NOEC
- Effect conc.:
- >= 97.5 mg/kg soil dw
- Nominal / measured:
- nominal
- Conc. based on:
- test mat.
- Basis for effect:
- other: survival
- Remarks on result:
- other: corrected for MW
- Species:
- Cucumis sativus
- Duration:
- 15 d
- Dose descriptor:
- NOEC
- Effect conc.:
- 48.8 mg/kg soil dw
- Nominal / measured:
- nominal
- Conc. based on:
- test mat.
- Basis for effect:
- other: shoot length
- Remarks on result:
- other: corrected for MW
- Species:
- Cucumis sativus
- Duration:
- 15 d
- Dose descriptor:
- NOEC
- Effect conc.:
- 48.8 mg/kg soil dw
- Nominal / measured:
- nominal
- Conc. based on:
- test mat.
- Basis for effect:
- other: shoot fresh weight
- Remarks on result:
- other: corrected for MW
- Species:
- Lycopersicon esculentum
- Duration:
- 15 d
- Dose descriptor:
- NOEC
- Effect conc.:
- >= 97.5 mg/kg soil dw
- Nominal / measured:
- nominal
- Conc. based on:
- test mat.
- Basis for effect:
- seedling emergence
- Remarks on result:
- other: corrected for MW
- Species:
- Lycopersicon esculentum
- Duration:
- 15 d
- Dose descriptor:
- NOEC
- Effect conc.:
- >= 97.5 mg/kg soil dw
- Nominal / measured:
- nominal
- Conc. based on:
- test mat.
- Basis for effect:
- other: survival
- Remarks on result:
- other: corrected for MW
- Species:
- Lycopersicon esculentum
- Duration:
- 15 d
- Dose descriptor:
- NOEC
- Effect conc.:
- 19.5 mg/kg soil dw
- Nominal / measured:
- nominal
- Conc. based on:
- test mat.
- Basis for effect:
- other: shoot length
- Remarks on result:
- other: corrected for MW
- Species:
- Lycopersicon esculentum
- Duration:
- 15 d
- Dose descriptor:
- NOEC
- Effect conc.:
- 43.6 mg/kg soil dw
- Nominal / measured:
- nominal
- Conc. based on:
- test mat.
- Basis for effect:
- other: shoot fresh weight
- Remarks on result:
- other: corrected for MW
- Species:
- Pisum sativum
- Duration:
- 15 d
- Dose descriptor:
- NOEC
- Effect conc.:
- 195.1 mg/kg soil dw
- Nominal / measured:
- nominal
- Conc. based on:
- test mat.
- Basis for effect:
- seedling emergence
- Remarks on result:
- other: corrected for MW
- Species:
- Pisum sativum
- Duration:
- 15 d
- Dose descriptor:
- NOEC
- Effect conc.:
- >= 390.1 mg/kg soil dw
- Nominal / measured:
- nominal
- Conc. based on:
- test mat.
- Basis for effect:
- other: survival
- Remarks on result:
- other: corrected for MW
- Species:
- Pisum sativum
- Duration:
- 15 d
- Dose descriptor:
- NOEC
- Effect conc.:
- 97.5 mg/kg soil dw
- Nominal / measured:
- nominal
- Conc. based on:
- test mat.
- Basis for effect:
- other: shoot length
- Remarks on result:
- other: corrected for MW
- Species:
- Pisum sativum
- Duration:
- 15 d
- Dose descriptor:
- NOEC
- Effect conc.:
- 97.5 mg/kg soil dw
- Nominal / measured:
- nominal
- Conc. based on:
- test mat.
- Basis for effect:
- other: shoot fresh weight
- Remarks on result:
- other: corrected for MW
- Validity criteria fulfilled:
- yes
- Remarks:
- The validity criteria were fulfilled as seedling emergence in the control was ≥ 70% and seedling survival in the control was ≥ 90% for all six test species. No phytotoxicity was observed in the controls.
- Conclusions:
- The chronic toxicity of 7PPD to terrestrial plants was tested according to OECD Guideline 208 (Terrestrial Plants Test: Seedling Emergence and Seedling Growth Test). Five to seven different test item concentrations per species were tested against a solvent control (acetone) with each of the six plant species. No significant effect on seedling emergence or mortality was observed for any of the six test species. Effects were observed for shoot length and fresh weight. Shoot length and shoot fresh weight of B. napus seedlings was significantly reduced at concentrations of 15.6 and 62.5 mg 7PPD/kg soil dw, respectively. Hence, B. napus was the most sensitive species with regard to shoot length and weight.
- Executive summary:
For 44PD, read-across is done from 7PPD. The chronic toxicity of 7PPD to terrestrial plants was tested according to OECD Guideline 208 (Terrestrial Plants Test: Seedling Emergence and Seedling Growth Test). Five to seven different test item concentrations per species were tested against a solvent control (acetone) with each of the six plant species.
Seeds of two monocot species, Allium cepa (onion) and Avena sativa (oat), and four dicot species, Brassica napus (rape), Cucumis sativus (cucumber), Lycopersicon esculentum (tomato) and Pisum sativum (pea) were planted in a natural sandy loam soil (standard soil LUFA Sp2.3) immediately after test item application and left to grow under controlled conditions for up to 15 days. Each species was tested at 5 out of 7 test item concentrations (dose response test) ranging from 7.8 to 500 mg 7PPD/kg soil dry weight. Test item was dissolved in acetone and mixed into portions of fine quarts sand. After complete evaporation of the solvent the spiked sand was mixed into the soil. A control soil and a solvent control soil were prepared by adding either pure sand or acetone spiked sand (without test item) to soil aliquots. Plants were allowed to emerge and grow for up to 15 days following 50% emergence of the control plants. Soils were supplied with water or nutrient solution by bottom watering. The test was performed in growth chambers equipped with artificial lighting (16 hours per day) and air conditioning (air temperature ranging from 22 to 27°C The pots were placed randomly at the beginning of the test and were re-arranged weekly. At half-time of the test seedlings were evaluated visually. Final counting, visual evaluation, and harvest to determine shoot length and shoot fresh weight took place at test end on day 14 or 15.
The test item significantly reduced seedling emergence of A. cepa by 42% at 250 mg 7PPD/kg soil dw (195.1 mg 44PD/kg soil dw). At this concentration none of the seedlings survived. Seedling emergence of P. sativum was significantly reduced by 62% at 500 mg 7PPD/kg soil dw (390.1 mg 44PD/kg soil dw). For all other tested species adverse effects were observed neither on emergence nor on survival
Visual evaluation revealed discoloured leaves at the highest test concentrations.
Shoot length and shoot fresh weight of B. napus seedlings was significantly reduced at concentrations of 15.6 and 62.5 mg 7PPD/kg soil dw, respectively. After correction for molecular weight, his corresponds to concentrations of 12.17 and 48.8 mg 44PD/kg soil dw, respectively. Hence, B. napus was the most sensitive species with regard to shoot length and weight.
Reference
Description of key information
For 44PD, read-across from 7PPD was done. For 7PPD, the chronic toxicity to terrestrial plants was tested according to OECD Guideline 208 (Terrestrial Plants Test: Seedling Emergence and Seedling Growth Test). Five to seven different test item concentrations per species were tested against a solvent control (acetone) with each of the six plant species. No significant effect on seedling emergence or mortality was observed for any of the six test species. Effects were observed for shoot length and fresh weight. Shoot length and shoot fresh weight of B. napus seedlings were significantly reduced at concentrations of 15.6 and 62.5 mg 7PPD/kg soil dw, respectively. After correction for molecular weight, this corresponds to 12.2 and 48.8 mg 44PD/kg soil dw. Hence, B. napus was the most sensitive species with regard to shoot length and weight.
Key value for chemical safety assessment
- Long-term EC10, LC10 or NOEC for terrestrial plants:
- 6.1 mg/kg soil dw
Additional information
Information on Registered Substances comes from registration dossiers which have been assigned a registration number. The assignment of a registration number does however not guarantee that the information in the dossier is correct or that the dossier is compliant with Regulation (EC) No 1907/2006 (the REACH Regulation). This information has not been reviewed or verified by the Agency or any other authority. The content is subject to change without prior notice.
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