Registration Dossier

Guidance on Safe Use

Guidance on Safe Use

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Administrative data

First-aid measures

General advice
When symptoms persist or in all cases of doubt seek medical advice. If unconscious, place in recovery position and get medical
attention immediately. Show this safety data sheet to the doctor in attendance.

Eye Contact:
Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Keep eye wide open while rinsing.
Immediate medical attention is required. Do no rub affected area.

Skin contact:
Wash off immediately with soap and plenty of water. Remove contaminated clothing and shoes. In the case of skin irritation or
allergic reactions contact a doctor. Wash contaminated clothing before reuse. Discard contaminated shoes.

Ingestion
If swallowed, rinse mouth with water (only if the person is conscious). Call a physician or poison control center immediately. Keep
victim warm and quiet. Loosen tight clothing such as a collar, tie, belt or waistband. If material has been swallowed and the
exposed person is conscious, give small quantities of water to drink. Stop if the exposed person feels sick as vomiting may be
dangerous. Never give anything by mouth to an unconscious person. Do NOT induce vomiting unless directed to do so by a
physician. If vomiting occurs spontaneously, keep head below hips to prevent aspiration. Maintain an open airway. If not breathing,
give artificial respiration. If breathing is difficult, give oxygen. Call a physician immediately.

Inhalation:
Remove to fresh air. If not breathing give artificial respiration. If breathing is difficult, give oxygen. Call a physician. Keep victim
warm and quiet. Loosen tight clothing such as a collar, tie, belt or waistband. Maintain an open airway. Persons who have inhaled
vapours or smoke fumes have to be put under medical observation for at least 48 hours, due to the delayed appearance of
poisoning.

Protection of first-aiders
Wear personal protective equipment. Ensure that medical personnel are aware of the material(s) involved and take precautions to
protect themselves.

Notes to physician
Treat symptomatically. Persons who have inhaled vapours or smoke fumes have to be put under medical observation for at least
48 hours, due to the delayed appearance of poisoning.

Fire-fighting measures

Extinguishing media
Suitable Extinguishing Media: Water spray, Foam, Dry powder, Carbon dioxide (CO 2).
Extinguishing media which shall not be used for safety reasons: Do not use a solid water stream as it may scatter and spread fire.

Special hazards arising from the substance or mixture
Fire will produce dense black acrid smoke. Thermal decomposition can lead to release of toxic and corrosive gases/vapours.
Decomposition products: Carbon dioxide, nitrogen oxides. Very toxic to aquatic life with long lasting effects. Runoff may pollute
waterways.

Advice for firefighters
Special protective equipment for fire-fighters: Positive pressure self-contained breathing apparatus (SCBA) and structural firefighters’ protective clothing willprovide adequate protection.
Special protective actions for fire-fighters: Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. Try to prevent the material fromentering drains or water courses. Collect contaminated fire extinguishing water separately. Do not allow entering drains or surface
water.

Accidental release measures

Personal precautions, protective equipment and emergency procedures:
Advice for non-emergency personnel: No action shall be taken involving any personal risk or without suitable training. Do not touch or walk throug spilled material. Avoid contact with skin, eyes and clothing. Wear personal protective equipment.
Evacuate personnel to safe areas. Ensure adequate ventilation. Do not touch damaged containers or spilled material unless
wearing appropriate protective clothing. Stop leak if you can do it without risk.

Advice for emergency responders: Contain and collect spillage with non-combustible absorbent material (e.g. sand, earth, diatomaceous earth,
vermiculite) and place in container for disposal according to local/national regulations (see Section 13). Refer to protective measures listed in sections 7 and 8 of the SDS.

Environmental Precautions:
Prevent further leakage or spillage if safe to do so. Clean up spill immediately. Prevent product and washings from entering drains,
sewers or surface water due to high toxicity to aquatic organisms. Local authorities should be advised if significant spillages cannot
be contained.

Methods and materials for containment and cleaning up:
Methods for Containment: Prevent further leakage or spillage if safe to do so. Dike to collect large liquid spills. Contain and collect spillage with
non-combustible absorbent material (e.g. sand, earth, diatomaceous earth, vermiculite) and place in container for disposal according to local/national regulations (see Section 13 of the SDS).
Methods for cleaning up: Take up with sand or other noncombustable absorbent material and place into containers for later disposal. Clean contaminated surface thoroughly. Prevent product and washings from entering drains, sewers or surface water due to high toxicity to aquatic
organisms.

Handling and storage

Precautions for safe handling
Advice on safe handling
Do not handle until all safety precautions have been read and understood. Handle product only in closed system or provide
appropriate exhaust ventilation at machinery. Do not breathe vapours/dust. Avoid contact with skin, eyes and clothing. Wear
personal protective equipment. In case of insufficient ventilation, wear suitable respiratory equipment. See also section 8. Consider
technical advances and process upgrades (including automation) for the elimination of releases. Minimise exposure using
measures such as closed systems, dedicated facilities and suitable general/local exhaust ventilation. Drain down systems and
clear transfer lines prior to breaking containment. Clean/flush equipment, where possible, prior to maintenance. Where there is
potential for exposure: restrict access to authorised persons; provide specific activity training to operators to minimise exposures;
wear suitable gloves and coveralls to prevent skin contamination; wear respiratory protection when its use is identified for certain
contributing scenarios; clear up spills immediately and dispose of wastes safely. Ensure safe systems of work or equivalent
arrangements are in place to manage risks. Regularly inspect, test and maintain all control measures. Consider the need for
risk-based health surveillance.
Advices on general occupational hygiene
Handle in accordance with good industrial hygiene and safety practice. Ensure that eyewash stations and safety showers are close
to the workstation location. Use personal protection recommended in Section 8. It is a good industrial hygiene practice to minimize
skin contact. Do no eat, drink or smoke when using this product. Wash hands before breaks and at the end of workday. Remove
and wash contaminated clothing before re-use. Keep away from food, drink and animal feeding stuffs.

Conditions for safe storage, including any incompatibilities
Technical measures/Storage conditions
Keep containers tightly closed in a dry, cool and well-ventilated place. Keep away from direct sunlight. Keep away from contact with
oxidizing materials. Keep in properly labelled containers. Use appropriate containment to avoid environmental contamination.
Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Store in accordance with local
regulations.
Packaging material
Recommended: Store in original container.

Transport information

Land transport (ADR/RID)

UN number:
UN2922
Proper shipping name and description:
CORROSIVE LIQUID, TOXIC, N.O.S.
Chemical name:
N,N'-di-sec-butyl-p-phenylenediamine
Language:
English
Class:
8
Packaging group:
III
Labels:
8 + 6.1
Special Provisions:
Environmental hazard

Inland waterway transport (ADN(R))

UN number:
UN2922
Proper shipping name and description:
CORROSIVE LIQUID, TOXIC, N.O.S.
Chemical name:
N,N'-di-sec-butyl-p-phenylenediamine
Language:
English
Class:
8
Packaging group:
III
Labels:
8 + 6.1
Remarks
Environmental hazard

Marine transport (IMDG)

UN number:
UN2922
Proper shipping name and description:
CORROSIVE LIQUID, TOXIC, N.O.S.
Chemical name:
N,N'-di-sec-butyl-p-phenylenediamine
Class:
8
Packaging group:
III
EmS code:
F-A, S-B
Labels:
8 + 6.1 + Environmental hazard
Marine pollutant
Remarks
Environmental hazard

Air transport ICAO/IATA

UN number:
UN2922
Proper shipping name and description:
CORROSIVE LIQUID, TOXIC, N.O.S.
Chemical name:
N,N'-di-sec-butyl-p-phenylenediamine
Class:
8
Packaging group:
III
Labels:
8 + 6.1
Remarks
Subject to ICAO/IATA Environmentally Hazardous Substance marking requirement (IATA 7.1.6.3)
SpecialProvisionsopen allclose all

Exposure controls / personal protection

Stability and reactivity

Disposal considerations