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Physical & Chemical properties

Vapour pressure

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Link to relevant study record(s)

Reference
Endpoint:
vapour pressure
Type of information:
experimental study
Adequacy of study:
key study
Study period:
Between 02 March and 05 March 2012.
Reliability:
1 (reliable without restriction)
Rationale for reliability incl. deficiencies:
other: see 'Remark'
Remarks:
Study conducted in compliance with agreed protocols, with no or minor deviations from standard test guidelines and/or minor methodological deficiencies, which do not affect the quality of the relevant results. The study report was conclusive, done to a valid guideline and the study was conducted under GLP conditions.
Qualifier:
according to guideline
Guideline:
EU Method A.4 (Vapour Pressure)
Deviations:
no
GLP compliance:
yes
Type of method:
effusion method: vapour pressure balance
Specific details on test material used for the study:
Batch#: 9311205/008
Temp.:
25 °C
Vapour pressure:
< 0.005 Pa
Transition / decomposition:
no

Results

Recorded temperatures, mass differences and the resulting calculated values of vapor pressure are shown in the following tables. Figures are shown in Attachment 3 of this summary:

Run 6

Table 3.1 – Vapor Pressure Data 

Temperature (°C)

Temperature (K)

Reciprocal Temperature (K-1)

Mass Difference (µg)

Mass Difference (kg)

Vapor Pressure (Pa)

Log10Vp

25

298.15

0.003354016

3.38

3.380E-09

0.004692306

-2.328613678

26

299.15

0.003342805

2.83

2.830E-09

0.003928765

-2.405743943

27

300.15

0.003331667

3.77

3.770E-09

0.005233726

-2.281189029

28

301.15

0.003320604

2.67

2.670E-09

0.003706644

-2.431019117

29

302.15

0.003309614

3.85

3.850E-09

0.005344786

-2.272069649

30

303.15

0.003298697

3.14

3.140E-09

0.004359124

-2.360600731

31

304.15

0.003287851

4.32

4.320E-09

0.005997267

-2.222046632

32

305.15

0.003277077

4.24

4.240E-09

0.005886206

-2.230164522

33

306.15

0.003266373

4.87

4.870E-09

0.006760808

-2.170001418

34

307.15

0.003255738

4.95

4.950E-09

0.006871868

-2.162925180

35

308.15

0.003245173

5.49

5.490E-09

0.007621527

-2.117958034

No statistical analysis is given due to the nature of the plot.

Run 7

Table 3.2 – Vapor Pressure Data 

Temperature (°C)

Temperature (K)

Reciprocal Temperature (K-1)

Mass Difference (µg)

Mass Difference (kg)

Vapor Pressure (Pa)

Log10Vp

25

298.15

0.003354016

2.35

2.350E-09

0.003262402

-2.486462516

26

299.15

0.003342805

3.14

3.140E-09

0.004359124

-2.360600731

27

300.15

0.003331667

3.30

3.300E-09

0.004581245

-2.339016439

28

301.15

0.003320604

2.75

2.750E-09

0.003817705

-2.418197685

29

302.15

0.003309614

5.34

5.340E-09

0.007413288

-2.129989122

30

303.15

0.003298697

3.14

3.140E-09

0.004359124

-2.360600731

31

304.15

0.003287851

5.89

5.890E-09

0.008176829

-2.087415084

32

305.15

0.003277077

4.08

4.080E-09

0.005664085

-2.246870216

33

306.15

0.003266373

4.32

4.320E-09

0.005997267

-2.222046632

34

307.15

0.003255738

7.46

7.460E-09

0.010356391

-1.984791551

35

308.15

0.003245173

4.87

4.870E-09

0.006760808

-2.170001418

No statistical analysis is given due to the nature of the plot.

Run 8

Table 3.3 – Vapor Pressure Data

Temperature (°C)

Temperature (K)

Reciprocal Temperature (K-1)

Mass Difference (µg)

Mass Difference (kg)

Vapor Pressure (Pa)

Log10Vp

25

298.15

0.003354016

3.06

3.060E-09

0.004248064

-2.371808952

26

299.15

0.003342805

1.81

1.810E-09

0.002512744

-2.599851804

27

300.15

0.003331667

3.14

3.140E-09

0.004359124

-2.360600731

28

301.15

0.003320604

1.10

1.100E-09

0.001527082

-2.816137694

29

302.15

0.003309614

4.47

4.470E-09

0.006205505

-2.207222856

30

303.15

0.003298697

2.28

2.280E-09

0.003165224

-2.499595532

31

304.15

0.003287851

4.87

4.870E-09

0.006760808

-2.170001418

32

305.15

0.003277077

2.59

2.590E-09

0.003595584

-2.444230615

33

306.15

0.003266373

5.10

5.100E-09

0.007080107

-2.149960203

34

307.15

0.003255738

4.24

4.240E-09

0.005886206

-2.230164522

35

308.15

0.003245173

3.14

3.140E-09

0.004359124

-2.360600731

No statistical analysis is given due to the nature of the plot.

Run 9

Table 3.4 – Vapor Pressure Data 

Temperature (°C)

Temperature (K)

Reciprocal Temperature (K-1)

Mass Difference (µg)

Mass Difference (kg)

Vapor Pressure (Pa)

Log10Vp

25

298.15

0.003354016

2.12

2.120E-09

0.002943103

-2.531194518

26

299.15

0.003342805

2.12

2.120E-09

0.002943103

-2.531194518

27

300.15

0.003331667

2.67

2.670E-09

0.003706644

-2.431019117

28

301.15

0.003320604

1.26

1.260E-09

0.001749203

-2.757159834

29

302.15

0.003309614

2.67

2.670E-09

0.003706644

-2.431019117

30

303.15

0.003298697

2.28

2.280E-09

0.003165224

-2.499595532

31

304.15

0.003287851

2.51

2.510E-09

0.003484523

-2.457856657

32

305.15

0.003277077

4.00

4.000E-09

0.005553025

-2.255470387

33

306.15

0.003266373

1.81

1.810E-09

0.002512744

-2.599851804

34

307.15

0.003255738

4.47

4.470E-09

0.006205505

-2.207222856

35

308.15

0.003245173

3.22

3.220E-09

0.004470185

-2.349674507

No statistical analysis is given due to the nature of the plot.

Run 10

Table 3.5 – Vapor Pressure Data 

Temperature (°C)

Temperature (K)

Reciprocal Temperature (K-1)

Mass Difference (µg)

Mass Difference (kg)

Vapor Pressure (Pa)

Log10Vp

25

298.15

0.003354016

0.86

8.600E-10

0.001193900

-2.923031927

26

299.15

0.003342805

1.96

1.960E-09

0.002720982

-2.565274307

27

300.15

0.003331667

0.55

5.500E-10

0.000763541

-3.117167689

28

301.15

0.003320604

1.57

1.570E-09

0.002179562

-2.661630726

29

302.15

0.003309614

1.65

1.650E-09

0.002290623

-2.640046435

30

303.15

0.003298697

3.85

3.850E-09

0.005344786

-2.272069649

31

304.15

0.003287851

1.73

1.730E-09

0.002401683

-2.619484276

32

305.15

0.003277077

4.79

4.790E-09

0.006649747

-2.177194865

33

306.15

0.003266373

2.67

2.670E-09

0.003706644

-2.431019117

34

307.15

0.003255738

3.69

3.690E-09

0.005122665

-2.290504013

35

308.15

0.003245173

3.38

3.380E-09

0.004692306

-2.328613678

No statistical analysis is given due to the nature of the plot.

Conclusions:
The vapour pressure of the test item has been determined to be less than 5.1 x 10E-3 Pa at 25 °C.
Executive summary:

Test System

The determination was carried out using a procedure designed to be compatible with Method A4 Vapour Pressure of Commission Regulation (EC) No 440/2008 of 30 May 2008 and Method 104 of the OECD Guidelines for Testing of Chemicals, 23 March 2006.

Principle of the Test

The vapour pressure was determined using a vapour pressure balance with measurements being made at several temperatures and linear regression analysis used to calculate the vapor pressure at 25 °C.

Conclusion

The vapour pressure of the test item has been determined to be less than 5.1 x 10-3 Pa at 25 °C.

Description of key information

The vapour pressure was determined using a vapour pressure balance with measurements being made at several temperatures and linear regression analysis used to calculate the vapor pressure at 25 °C.

The vapour pressure of the test item has been determined to be less than 5.1 x 10-3 Pa at 25 °C.

Key value for chemical safety assessment

Vapour pressure:
0.005 Pa
at the temperature of:
25 °C

Additional information