Registration Dossier

Administrative data

First-aid measures

General advice: Take off all contaminated clothing immediately.
If inhaled: Take the person into the fresh air and keep him warm, let him rest; if there is difficulty in breathing, medical advice is required.
In case of skin contact: In case of skin contact wash affected areas thoroughly with soap and plenty of water. Consult a doctor in the event of a skin reaction.
In case of eye contact: Hold the eyes open and rinse with preferably lukewarm water for a sufficiently long period of time (at least 10 minutes). Contact an ophthalmologist.
If swallowed: DO NOT induce the patient to vomit, medical advice is required.

Most important symptoms and effects, both acute and delayed
Notes to physician: Basic first aid, decontamination, symptomatic treatment.

Indication of any immediate medical attention and special treatment needed
Therapeutic measures: No information available.

Fire-fighting measures

Extinguishing media: Carbon dioxide (CO2), foam, extinguishing powder, in cases of larger fires, water spray should be used.
Unsuitable extinguishing media: High volume water jet

Special hazards arising from the substance or mixture:
Burning releases carbon monoxide, carbon dioxide, oxides of nitrogen and traces of hydrogen cyanide. In the event of fire and/or explosion do not breathe fumes.

Advice for fire-fighters:
Firemen must wear self-contained breathing apparatus.
Do not allow contaminated extinguishing water to enter the soil, ground-water or surface waters.

Accidental release measures

Personal precautions, protective equipment and emergency procedures:
Put on protective equipment (see section 8). Ensure adequate ventilation/exhaust extraction. Keep unauthorized persons away.

Environment related measures:
Do not allow to escape into waterways, wastewater or soil.

Methods and material for containment and cleaning up
Take up with absorbent for chemicals or, if necessary with dry sand and store in closed containers.

Reference to other sections
For further disposal measures see on section disposal concideration.

Handling and storage

Precautions for safe handling:
Handle in accordance with good industrial hygiene and safety practice. Avoid contact with skin and eyes.

In all workplaces or parts of the plant where high concentrations of aerosols and/or vapors may be generated (e.g. during pressure release, mold venting or when cleaning mixing heads with an air blast), appropriately located exhaust ventilation must be provided in such a way that the WEL is not exceeded. The air should be drawn away from the personnel handling the product The efficiency of the exhaust equipment should be periodically checked.

Precautions should generally be taken against electrostatic charges according to the equipment used and the way the product is handled and packaged.
Keep away from foodstuffs, drinks and tobacco. Wash hands before breaks and at the end of workday. Keep working clothes separately. Change contaminated or soaked clothing immediately.

Conditions for safe storage, including any incompatibilities:
Keep container tightly closed and dry.
Further specific information see :"Technical Information"
Storage class (TRGS 510) : 10: Combustible liquids

Transport information

Land transport (ADR/RID)

UN number:
3082
Proper shipping name and description:
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S.
(Mixture of mannich bases)
Class:
9
Classification code:
90
Packaging group:
III
Labels:
GHS05, GHS08, GHS07, GHS09
Special Provisions:
Limited quantity regulations applicable in accordance with chapter 3.4 ADR/RID in compliance with threshold value.
Remarks:
Environmental hazards: yes

Inland waterway transport (ADN(R))

UN number:
3082
Proper shipping name and description:
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (Mixture of mannich bases)
Class:
9
Classification code:
90
Packaging group:
III
Labels:
GHS05, GHS08, GHS07, GHS09
Remarks
This classification data does not apply to transportation by tanker. If required, additional information can be requested from the manufacturer.
Environmental hazards: yes

Marine transport (IMDG)

UN number:
3082
Proper shipping name and description:
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (Mixture of mannich bases)
Class:
9
Packaging group:
III
Labels:
GHS05, GHS08, GHS07, GHS09
Remarks
Environmental hazards: yes

Air transport ICAO/IATA

UN number:
3082
Proper shipping name and description:
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (Mixture of mannich bases)
Class:
9
Packaging group:
III
Labels:
GHS05, GHS08, GHS07, GHS09
Remarks
Environmental hazards: yes

Additional transport information

Additional transport information
- Environmentally hazardous substance. Avoid heat above +40 °C. Keep away from foodstuffs, acids and alkalis.
- Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code
Not applicable.

Exposure controls / personal protection

Control parameters:
No information on Exposure Limit Values necessary according to EC directive 2006/121/EG
For technical protective measures to limit exposure see also "Handling and storage".

Exposure controls:
Respiratory protection:
Unless the product is entirely enclosed, do not handle it until you have studied the respiratory precautions issued by the appropriate authority or accident prevention association. If vapors form, respirators must be used. Put on full-mask respirator with filter type ABEK.

Eye protection:
Wear eye/face protection.
Skin and body protection:

Wear suitable protective clothing.
Safety precautions for handling freshly molded polyurethane parts:

Depending on the production parameters, any uncovered surfaces of freshly molded polyurethane parts using this raw material may contain traces of substances (e. g. starting and reaction products, catalysts, release agents) with hazardous characteristics. Skin contact with traces of these substances must be avoided. Therefore, during demolding or other handling of fresh molded parts, protective gloves tested according to DIN-EN 374 (e.g. nitrile rubber >= 1.3 mm thick, breakthrough time >= 480 min, or according to recommendations from glove makers thinner gloves that need to be changed in compliance with breakthrough times more frequently) must be used. Depending on formulation and processing conditions, the requirements may be different from handling of the pure substances. Closed protective clothing is required for the protection of other areas of skin.

Stability and reactivity

Reactivity:
This information is not available.

Chemical stability:
No decomposition below initial boiling point.

Possibility of hazardous reactions:
No hazardous reactions when used as directed.

Conditions to avoid:
This information is not available.

Incompatible materials:
This information is not available.

Hazardous decomposition products:
No hazardous decomposition products when stored and handled correctly.

Disposal considerations

Dispose in accordance with applicable international, national and local laws, ordinances and statutes.
For disposal within the EC, the appropriate code according to the European Waste Catalogue (EWC) should be used.

Waste treatment methods:
After containers have been emptied as thoroughly as possible (e.g. by pouring, scraping or draining until "drip-dry"), they can be sent to an appropriate collection point set up within the framework of the existing take-back scheme of the chemical industry. Containers must be recycled in compliance with national legislation and environmental regulations.
None disposal into waste water.