Registration Dossier

Guidance on Safe Use

Guidance on Safe Use

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Administrative data

First-aid measures

Skin contact: take off contaminated clothes. Wash out skin with plenty of water with soap. Consult a doctor, if symptoms persist.
Eye contact: wash out with plenty of water with the eyelid hold wide open, for 10-15 min. Remove any contact lenses. Avoid powerful water stream – risk of cornea damage. Obtain medical attention immediately.
Ingestion: induce vomiting. rinse mouth with water; give plenty of water to drink. Consult a doctor – show the container or label. Do not give anything to drink to an unconscious person.
Inhalation: remove to fresh air, keep warm and calm. In case of some symptoms consult a doctor – show the container or label.

Fire-fighting measures

Extinguishing media
Suitable extinguishing media: dry extinguishing, carbon dioxide, water spray. Use extinguishing measures that are appropriate to the environment. Unsuitable extinguishing media: water jet – risk of the propagation of the flame.

Special hazards arising from the substance or mixture
May produce toxic fumes, eg. carbon oxide and nitrogen oxide if burning. Do not inhale combustion products – it can be dangerous for health.

Advice for firefighters
Flammable liquid and vapours. Vapours are heavier than air and may create explosive mixtures with it. Personal protection typical in case of fire. Self-contained breathing apparatus and protective clothing should be worn. Tanks exposed to fire or high temperatures to be cooled down with water, whenever possible, removed from the endangered area.

Accidental release measures

Personal precautions, protective equipment and emergency procedures
Limit the access for the outsiders into the breakdown area, until the suitable cleaning operations are completed. Wear adequate personal protective equipment. Avoid contact with skin and eyes. Remove all ignition sources. Do not smoke. Use means preventing electrostatic discharges. Ensure adequate ventilation. Avoid inhalation vapours.

Environmental precautions
In case of release of large amounts of the product, it is necessary to take appropriate steps to prevent it from spreading into the environment. Notify relevant emergency services.

Methods and material for containment and cleaning up
Reduce leak with dams. In case of a large leakage, collect the liquid or pump it to tight closed containers. Cover the remainder with neutral sorbent (sand, diatomaceous soil), collect to tight closed containers, and rinse the contaminated place with plenty of water or water acidified with diluted mineral acid. In case of a little leakage, rinse the liquid with plenty of water or acidified water. Forward the collected product to an authorized waste recipient.

Handling and storage

Precautions for safe handling
Handle in accordance with good occupational hygiene and safety practices. Ensure good ventilation of the rooms and ventilating hoods at workplaces. Do not inhale dusts. Before break and after work wash carefully hands. Avoid skin and eyes contamination. Keep not used containers tightly closed. Use only with purpose. Do not ingestion. Remove all ignition sources. Use means preventing electrostatic discharges.

Conditions for safe storage, including any incompabilities
Keep only in original, tightly closed containers in the atmosphere of nitrogen in dry, cool and well-ventilated place. Recommended storage temperature 5 – 30o C. Keep away from fire source. Use means of caution preventing electrostatic discharges. Protect against direct operation of solar rays, freezing, humidity, contact with air and oxygen. Keep away from flammable substances. Do not keep with oxidizing substances. Keep away from food, beverages or feed for animals. Recommended material for packages: : HDPE with Teflon seals, acid-resistant steel. Do not use natural and synthetic rubber and some plastics.

Transport information

Land transport (ADR/RID)

UN number:
ADR: 1993, classification code: F1, hazard distinctive identification number: 30

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Class:
ADR: 3

Classification code:
ADR: 1993, classification code: F1, hazard distinctive identification number: 30
Packaging group:
ADR: III
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Marine transport (IMDG)

UN number:
1993, EmS code: F-E, S-E
Proper shipping name and description:
FLAMMATORY LIQUID MATERIAL, I.N.O.
Chemical name:
(Diethylhydroxylamine, 98% solution)
Class:
IMDG: 3
Packaging group:
IMDG: III
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Air transport ICAO/IATA

UN number:
ICAO/IATA: 1993
Proper shipping name and description:
FLAMMATORY LIQUID MATERIAL, I.N.O.
Chemical name:
(Diethylhydroxylamine, 98% solution)
Class:
ICAO/IATA: 3
Packaging group:
ICAO/IATA: III
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Exposure controls / personal protection

Control parameters Product doesn’t contain any components with occupational exposure limit values at working place in Community. Please check any national occupational exposure limit values in your country.

Exposure controls
Use the product in accordance with good occupational hygiene and safety practices. Ensure that there is sufficient general ventilation with exchange of air and / or ventilating hoods in the work area. Avoid skin and eyes contamination. Do not inhale vapours. When handlings do not eat, drink or smoke. Before break and after work carefully wash hands. Do not use close to ignition sources and sources of high temperatures. In the case of insufficient ventilation, use means of protection of the respiratory system. Ensure a shower and a post for rinsing eyes. Hand and body protection Use gloves from PCV or rubber. Use natural protective clothing materials (cotton) or synthetic fibers and protective footwear.
The material that the gloves are made of must be impenetrable and resistant to the product’s effects. The selection of material must be performed with consideration of breakthrough time, penetration speed and degradation. Moreover, the selection of proper gloves depends not only on the material, but also on other quality features and changes depending on the manufacturer. The producer should provide detailed information regarding the exact breakthrough time. This information should be followed.
Eye/face protection
Use safety glasses (goggles) in the case of dust.
Respiratory protection Use mask with filt type A. Environmental exposure controls Do not allow the large quantity of mixture to contaminate surface water/ground water.

Stability and reactivity

Reactivity
It reacts with strong oxidizing.
Chemical stability
The product is stable.
Possibility of hazardous reactions
None.
Conditions to avoid
High temperature, humidity, ignition sources.
Incompatible materials
Oxidizers (perchlorates, peroxides), acids, nitrates.
Hazardous decomposition products
None.

Disposal considerations

Waste treatment methods
Disposal methods for the product: disposal in accordance with the local legislation. Do not remove with household garbage. Store remaining in original containers. Recycle, if possible.
Disposal methods for used packing: empty containers give for appropriate rubbish dump or for disposal in accordance with the local legislation. Dispose of uncleanable containers like of the product. Legal basis: Directive 2006/12/EC, 94/62/EC and 91/689/EEC.