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EC number: 202-993-8
CAS number: 101-97-3
The substance was not classified as flammable, flammable in contact with water, pyrophoric, self-reactive substance, self-heating substance and organic peroxide.
The test on the flammability
(Regulation (EC) No 440/2008 method A.10) was not performed as the test
item is a liquid. For liquids the primary value for ease of ignition is
the flash point conducted using Method A9 ‘Flash Point Method’ of
Council Regulation (EC) No 440/2008. The result of the Flash Point test
is used to allocate a liquid substance into the appropriate flammability
class. The flash point was reported to be 101 °C at 1013.25 hPa. Thus,
the substance has not to be classified as flammable liquid according to
Regulation (EC) No 1272/2008 or Directive 67/548/EEC.
In accordance with section 2.9.4 Annex
I of Regulation (EC) No 1272/2008 and ECHA guidance on the application
of CLP Criteria section 188.8.131.52 the classification procedure for
pyrophoric liquids need not to be applied when experience in
manufacturing or handling shows that the substance or mixture does not
ignite spontaneously when coming into contact with air at normal
temperatures. Based on the experience in handling and use the substance
is not known to ignite spontaneously when coming into contact with air
at normal temperatures. Thus, no study was conducted and consequently
the substance has not to be considered for classification as pyrophoric
Substances which, in contact
with water, emit flammable gases
In accordance with column 2 of REACH
Annex VI and with Regulation (EC) No 1272/2008 Annex I section 184.108.40.206
the classification procedure for this hazard class need not be applied
a) The chemical structure of the
substance or mixture does not contain metals or metalloids; or
b) Experience in handling and use
shows that the substance or mixture does not react with water, e.g. the
substance is manufactured with water or washed with water; or
c) The substance or mixture is known
to be soluble in water to form a stable mixture.
The substance did not contain metals
or metalloids. Therefore the substance has not to be considered for
classification as substances which, in contact with water, emit
Self-reactive substances and
In accordance with section R.220.127.116.11
ECHA guidance IR/CSA chapter R.7a, section 2.9.1 ECHA guidance on the
application of CLP criteria and UN-MTC section 5.1 appendix 6 the test
for self-reactive substances was waived.
The test item does not contain any
functional groups quoted in ‘UN Manual of Tests and Criteria’ (fifth
revised edition, appendix 6, table A 6.1 and A 6.2) or Bretherick’s –
Handbook (6th Edition, Volume 2, p 128 ff) which may indicate explosive
or self-reacting properties. Therefore, it can be concluded by expert
judgment that the test item does not meet the criteria for self-reactive
substances, Thus no classification procedures for self-reactive
substances was required and consequently the substance has not to be
considered for classification as self-reactive substances and mixtures.
Self-heating substances and
In accordance with ECHA guidance on
the Application of the CLP Criteria section 18.104.22.168 and ECHA guidance
on IR/CSA chapter R.7a section R22.214.171.124 the test does not to be
conducted as in general liquids are not classified as self-heating since
the phenomena applies only to solids. Furthermore the test method is not
applicable to liquids according to guidance on the Application of the
CLP Criteria section 126.96.36.199. Thus no classification procedure for
self-heating substances and mixtures was required and consequently and
the substance has not to be considered for classification as
self-heating substances and mixtures.
In accordance with Regulation (EC) No
1272/2008 Annex I section 2.15.1 only organic peroxides have to be
tested according to the UN-MTC, Part II test series A-H. Based on the
structure it can be concluded that the substance is not an organic
peroxide. Thus, no tests were conducted and the substance has not to be
considered for classification as organic peroxide.
Based on the study results, the molecular
structure and experience in handling and use, the substance was not
classified and labelled as flammable, flammable in contact with water,
pyrophoric, self-reactive substance, self-heating substance and organic
peroxide according to Directive 67/548/EEC (DSD) and Regulation (EC) No
Information on Registered Substances comes from registration dossiers which have been assigned a registration number. The assignment of a registration number does however not guarantee that the information in the dossier is correct or that the dossier is compliant with Regulation (EC) No 1907/2006 (the REACH Regulation). This information has not been reviewed or verified by the Agency or any other authority. The content is subject to change without prior notice.Reproduction or further distribution of this information may be subject to copyright protection. Use of the information without obtaining the permission from the owner(s) of the respective information might violate the rights of the owner.
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