Registration Dossier

Administrative data

Endpoint:
thermal stability
Type of information:
experimental study
Adequacy of study:
key study
Reliability:
2 (reliable with restrictions)
Rationale for reliability incl. deficiencies:
guideline study

Data source

Reference
Reference Type:
study report
Title:
Unnamed
Year:
2011
Report Date:
2011

Materials and methods

Test guideline
Qualifier:
equivalent or similar to
Guideline:
OECD Guideline 113 (Screening Test for Thermal Stability and Stability in Air)
GLP compliance:
no
Other quality assurance:
ISO/IEC 17025 (General requirements for the competence of testing and calibration laboratories)

Test material

Reference
Name:
Unnamed
Type:
Constituent
Test material form:
liquid
Details on test material:
Name of test material (as cited in study report): Methylchlorformiat
Analytical purity: >98 %

Results and discussion

For thermal stability study

Test substance thermally stable:
yes
Operating temperature
Key result
Operating temp.:
>= 30 - <= 500 °C
Remarks on result:
other: 1st exothemic reaction: 830 J/g at onset temperatue 205°C; 2nd exothemic reaction: 20 J/g at onset temperatue 425°C

Any other information on results incl. tables

Results

1.Peak

exothermic

Onset-temperature

205 °C

Peak temperature       

295 °C

Energy release

830 J/g

The reaction is self-accelerating.

 

2.Reaction

exothermic

Onset-temperature

425 °C

Peak temperature       

442 °C

Energy release

20 J/g

The reaction was not examined for self-accelerating reaction behavior.

Applicant's summary and conclusion