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Please be aware that this old REACH registration data factsheet is no longer maintained; it remains frozen as of 19th May 2023.

The new ECHA CHEM database has been released by ECHA, and it now contains all REACH registration data. There are more details on the transition of ECHA's published data to ECHA CHEM here.

Diss Factsheets

Physical & Chemical properties

Stability: thermal, sunlight, metals

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Administrative data

Endpoint:
stability: thermal, sunlight, metals, other
Type of information:
other: MSDS
Adequacy of study:
supporting study
Reliability:
4 (not assignable)
Rationale for reliability incl. deficiencies:
secondary literature

Data source

Reference
Reference Type:
secondary source
Title:
Unnamed
Year:
2010

Materials and methods

GLP compliance:
not specified

Test material

Constituent 1
Reference substance name:
[hexane-1,6-diylbis[nitrilobis(methylene)]]tetrakisphosphonic acid, potassium salt
EC Number:
254-135-7
EC Name:
[hexane-1,6-diylbis[nitrilobis(methylene)]]tetrakisphosphonic acid, potassium salt
Cas Number:
38820-59-6
Molecular formula:
C10H28N2O12P4.xK
IUPAC Name:
[hexane-1,6-diylbis[nitrilobis(methylene)]]tetrakisphosphonic acid, potassium salt
Test material form:
solid - liquid: aqueous solution

Results and discussion

For thermal stability study

Test substance thermally stable:
yes
Operating temperature
Operating temp.:
> 200 °C
Transformation products:
yes
Identity of transformation productsopen allclose all
No.:
#1
Reference
Reference substance name:
Unnamed
IUPAC name:
phosphine
Inventory number:
InventoryMultipleMappingImpl [inventoryEntryValue=EC 232-260-8]
CAS number:
7803-51-2
Identity:
Phosphine
Molecular formula:
H3P
Molecular weight:
33.998
SMILES notation:
P
InChl:
InChI=1/H3P/h1H3
No.:
#2
Reference
Reference substance name:
Unnamed
IUPAC name:
Carbon oxides
Identifier:
common name
Identity:
Carbon oxides
No.:
#3
Reference
Reference substance name:
Unnamed
IUPAC name:
Phosphorus oxides
Identifier:
common name
Identity:
Phosphorus oxides

Any other information on results incl. tables

On combustion or on thermal decomposition (following the evaporation of water) the substance releases:

(Carbon oxides (CO + CO2)).

corrosive vapours. (Phosphorus oxides).

Above 200°C releases:(Phosphine)

The phosphine will burn on to phosphorus pentoxide unless there is insufficient fresh air

Applicant's summary and conclusion

Conclusions:
The test substance was observed to generate phosphine when heated to a high temperature of above 200°C.