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Guidance on Safe Use

Guidance on Safe Use

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Administrative data

First-aid measures

General advice
Remove contaminated, soaked clothing immediately and dispose of safely. Take affected person to fresh air. Adhere to personal protective measures when giving first aid. Keep warm, calm and covered up. By continuous complaints consult a physician. Alcohol increases the toxic effects.

If inhaled
Remove the casualty into fresh air and keep him calm. Get medical attention immediately.

In case of skin contact
Thaw frosted parts with lukewarm water. Do not rub affected area. Get immediate medical advice/attention.

In case of eye contact
In case of contact with eyes rinse thoroughly with plenty of water and seek medical advice. In case of irritation consult an occulist..

If swallowed
Summon a doctor immediately. Provide for body rest, protect against loss of heat. If individual is drowsy or unconscious place in recovery position (on left side, with head down).

Notes to physician
Hazards:
Danger of reduced reaction capability (sedativum) Risk of deterioration due to consumption of alcohol.

Symptoms:
Headache, Daze, Frostbite, Unconsciousness, Cough, Intoxication, CNS depression. When inhaled or swallowed depending on the time and amount, it can give rise to the following symptoms: Headaches, Giddiness, Tiredness, Nausea, Vomit, Heart beat distrubance, Intoxication, Unconciousness, Breathing stop, Death.

Treatment:
If ingested, irrigate the stomach using activated charcoal in addition. Treat frost-bitten areas as needed. Do not give drugs from adrenaline-ephedrine group.

Fire-fighting measures

Suitable extinguishing media
Dry powder, carbon dioxide

Special exposure hazards arising from the substance or preparation itself, its combustion products, or released gases
In case of fires, hazardous combustion gases are formed: Hydrogen chloride (HCl). May form explosive mixtures in air.

Special protective equipment for fire fighting
Wear full protective suit. Use self-contained breathing apparatus.

Additional information on firefighting
Cool endangered containers with water spray jet. Heating causes rise in pressure with risk of bursting.

Accidental release measures

Personal precautions
Keep away sources of ignition. Use personal protective clothing. Ensure adequate ventilation. Keep people away and stay on the upwind side.

Environmental precautions
Do not allow to enter drains or waterways. Do not discharge into the subsoil/soil.

Handling and storage

Part of this substance is handled under Strictly Controlled Conditions in accordance with REACH regulation Article 18(4) transported intermediates. Site documentation to support safe handling arrangements including the selection of engineering, administrative and personal protective equipment controls in accordance with risk-based management systems is available at each Manufacturing site. Written confirmation of application of Strictly Controlled Conditions has been received from affected Distributor and Downstream Manufacturer/User of the Registrant's intermediate.

Advice on safe handling
Perform filling operations only at stations with exhaust ventilation facilities. Keep container tightly closed. Handle and open container with care. Take precautionary measures against static discharges. Keep away from sources of ignition. Use explosion-proof equipment/fittings and non-sparking tools.


Storage space and container requirements
Store product in closed containers. Use stainless steel containers. Use glass containers. Suitable material for sealings: fluororubber, polytetrafluoroethylene, polyfluotthenpropene, graphite.

Unsuitable materials for containers
zinc, Aluminium. Nicht in Behältern aus Leichtmetall oder Legierungen lagern und transportieren.

Hints on storage assembly
Do not store with strong oxidizing agents. Do not store with combustible materials.

Storage specifications
Keep container tightly closed in a cool, well-ventilated place, open and handle carefully.

VCI storage category
2A: Gases (except aerosol dispensers and lighters)

Temperature class
T1

Specific end use(s)
Specific use(s): see exposure scenario

Transport information

Land transport (UN RTDG/ADR/RID)

UN number:
1037
Shippingopen allclose all
Labels:
2.1
Special provisions / remarks
Remarks:
Risk No. 23, Tunnel restriction code (B/D)

Inland waterway transport (UN RTDG/ADN(R))

UN number:
1037
Shippingopen allclose all
Labels:
2.1
Remarksopen allclose all

Marine transport (UN RTDG/IMDG)

UN number:
1037
Shipping information
Proper shipping name and description:
Ethyl chloride
Labels:
2.1
Remarksopen allclose all

Air transport (UN RTDG/ICAO/IATA)

UN number:
1037
Shipping information
Proper shipping name and description:
Ethyl chloride
Labels:
2.1
Special provisions / remarks
Remarks:
ICAO / IATA cargo aircraft only
SpecialProvisionsopen allclose all

Exposure controls / personal protection

Part of this substance is handled under Strictly Controlled Conditions in accordance with REACH regulation Article 18(4) transported intermediates. Site documentation to support safe handling arrangements including the selection of engineering, administrative and personal protective equipment controls in accordance with risk-based management systems is available at each Manufacturing site. Written confirmation of application of Strictly Controlled Conditions has been received from affected Distributor and Downstream Manufacturer/User of the Registrant's intermediate.

Respiratory protection
If workplace limits are exceeded, a respirations protection approved for this particular job must be worn. Self-contained breathing apparatus.Short term: filter apparatus, filter AX

Hand protection: insulated gloves
Suitable material: Butyl caoutchouc (butyl rubber)
Material thickness: >= 0.5 mm
Break through time: > 10 min
Evaluation: suitable
Note: Dichloromethane

Eye protection
Safety glasses with side protection shield

Skin and body protection
protective overall, rubber

General protective and hygiene
Do not inhale gases/vapours/aerosols. Avoid contact with eyes and skin. Remove soiled or soaked clothing immediately.

Stability and reactivity

Thermal decomposition: > 400 °C

Chemical stability The product is chemically stable.

Hazardous reactions: Explosive reaction with: Alkali metals, Aluminium, zinc.

Conditions to avoid: temperatures above 200 °C. Formation of explosive gas/air mixtures.
Keep away from heat sources, sparks and open flames.

Materials to avoid: Alkali metals, Magnesium, Zinc, Aluminium, Oxidizing agents.

Hazardous decomposition products: Hydrogen chloride (HCl)

Disposal considerations

Disposal considerations In accordance with regulations for special waste, must be taken, after pretreatment, to an authorised special waste incineration plant.