Butyl (dialkyloxy(dibutoxyphosphoryloxy))titanium(trialkyloxy)titanium phosphate

Guidance on Safe Use

First-aid measures

General : In all cases of doubt, or when symptoms persist, seek medical attention. Never give anything by mouth to an unconscious person. If unconscious, place in recovery position and seek medical advice.

Inhalation : Remove to fresh air. Keep person warm and at rest. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel.

Skin contact: Remove contaminated clothing and shoes. Wash skin thoroughly with soap and water or use recognized skin cleanser. Do NOT use solvents or thinners.

Eye contact: Check for and remove any contact lenses. Immediately flush eyes with running water for at least 15 minutes, keeping eyelids open. Seek immediate medical attention/advice.

Ingestion: Remove dentures if any. Remove victim to fresh air and keep at rest in a position comfortable for breathing. Do not induce vomiting unless directed to do so by medical personnel. If vomiting occurs, the head should be kept low so that vomit does not enter the lungs. Get medical attention. If necessary, call a poison center or physician. Give nothing by mouth. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband.

Protection of first-aiders: No action shall be taken involving any personal risk or without suitable training. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation.

Indication of any immediate medical attention and special treatment needed :

Treat symptomatically. Contact poison treatment specialist immediately if large quantities have been ingested or inhaled.  No specific treatment.

Fire-fighting measures

Suitable Extinguishing media : Recommended:, alcohol-resistant foam, CO₂, powders, water spray

Extinguishing media not to be used : Do not use water jet.

Hazards from the substance or mixture: Highly flammable liquid and vapor. In a fire or if heated, a pressure increase will occur and the container may burst, with the risk of a subsequent explosion. Runoff to sewer may create fire or explosion hazard. This material is toxic to aquatic life with long lasting effects. Fire water contaminated with this material must be contained and prevented from being discharged to any waterway, sewer or drain.

Hazardous thermal decomposition products:

Fire will produce dense black smoke. Exposure to decomposition products may cause a health hazard.

Decomposition products may include the following materials: carbon dioxide, carbon monoxide.

Special protective actions for fire-fighters: Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. Move containers from fire area if this can be done without risk. Use water spray to keep fire-exposed containers cool. Do not release runoff from fire to drains or watercourses.

Special protective equipment for fire-fighters: Fire-fighters should wear appropriate protective equipment and self-contained

breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode. Clothing for fire-fighters (including helmets, protective boots and gloves) conforming to European standard EN 469 will provide a basic level of protection for chemical incidents.

Accidental release measures

Personal precautions, protective equipment and emergency procedures:

For non-emergency personnel: No action shall be taken involving any personal risk or without suitable training. Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilled material. Shut off all ignition sources. No flares, smoking or flames in hazard area. Avoid breathing vapor or mist. Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment.

For emergency responders : If specialised clothing is required to deal with the spillage, take note of any information in Section 8 on suitable and unsuitable materials. See also the information in "For non-emergency personnel".

Environmental precautions:

Do not allow to enter drains or watercourses. If the product contaminates lakes, rivers, or sewers, inform the appropriate authorities in accordance with local regulations.

Methods and materials for containment and cleaning up:

Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations (see Section 13). Preferably clean with a detergent. Avoid using solvents.

Handling and storage

Precautions for safe handling:

Vapors are heavier than air and may spread along floors. Vapors may form explosive mixtures with air. Prevent the creation of flammable or explosive concentrations of vapors in air and avoid vapor concentrations higher than the occupational exposure limits. In addition, the product should only be used in areas from which all naked lights and other sources of ignition have been excluded. Electrical equipment should be protected to the appropriate standard. To dissipate static electricity during transfer, ground drum and connect to receiving container with bonding strap. Operators should wear antistatic footwear and clothing and floors should be of the conducting type. Keep container tightly closed. Keep away from heat, sparks and flame. No sparking tools should be used. Avoid contact with skin and eyes. Avoid the inhalation of dust, particulates, spray or mist arising from the application of this mixture.

Remove contaminated clothing and protective equipment before entering eating areas. Workers should wash hands and face before eating, drinking and smoking. Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Put on appropriate personal protective equipment (see Section 8). Always keep in containers made from the same material as the original one. Comply with the health and safety at work laws.

Conditions for safe storage, including any incompatibilities:

Store in accordance with all local, regional, national and international regulations. Store in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10). Observe label precautions. Keep container tightly closed and in a well-ventilated place. Keep away from sources of ignition - No smoking. Prevent unauthorized access. Containers that have been opened must be carefully resealed and kept upright to prevent leakage.

Transport information

Land transport (UN RTDG/ADR/RID)

UN number:

UN1993

Shipping

SpecialProvisions

Shipping

Remarks

Marine transport (UN RTDG/IMDG)

UN number:

UN1993

Shipping information

Proper shipping name and description:

FLAMMABLE LIQUID, N.O.S. (propan-2-ol, Titanium chelate)

Marine pollutant

Remarks

Air transport (UN RTDG/ICAO/IATA)

UN number:

UN1993

Shipping information

Proper shipping name and description:

FLAMMABLE LIQUID, N.O.S. (propan-2-ol, Titanium chelate)

Remarks

SpecialProvisions

Exposure controls / personal protection

Recommended monitoring procedures:

If this product contains ingredients with exposure limits, personal, workplace atmosphere or biological monitoring may be required to determine the effectiveness of the ventilation or other control measures and/or the necessity to use respiratory protective equipment. Reference should be made to monitoring standards, such as the following: European Standard EN 689 (Workplace atmospheres - Guidance for the assessment of exposure by inhalation to chemical agents for comparison with limit values and measurement strategy) European Standard EN 14042 (Workplace atmospheres - Guide for the application and use of procedures for the assessment of exposure to chemical and biological agents) European Standard EN 482 (Workplace atmospheres - General requirements for the performance of procedures for the measurement of chemical agents) Reference to national guidance documents for methods for the determination of hazardous substances will also be required.

Individual protection measures:

Hygiene measures - Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period. Appropriate techniques should be used to remove potentially contaminated clothing. Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location.

Respiratory protection - Use a properly fitted, air-purifying or air-fed respirator complying with an approved standard if a risk assessment indicates this is necessary. Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator.

Body protection - Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. When there is a risk of ignition from static electricity, wear anti-static protective clothing. For the greatest protection from static discharges, clothing should include anti-static overalls, boots and gloves. Refer to European Standard EN 1149 for further information on material and design requirements and test methods.

Hand protection - Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary.

Gloves - For prolonged or repeated handling, use the following type of gloves: Recommended: butyl rubber, foil, fluor rubber.

May be used: neoprene, nitrile rubber

Not recommended: PVC

Other skin protection : Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product.

Eye/face protection: Use safety eyewear designed to protect against splash of liquids.

Environmental exposure controls: Do not allow to enter drains or watercourses.

Stability and reactivity

Chemical stability : Stable under recommended storage and handling conditions.

Possibility of hazardous reactions: Under normal conditions of storage and use, hazardous reactions will not occur.

Conditions to avoid: Avoid all possible sources of ignition (spark or flame).

Incompatible materials: Keep away from the following materials to prevent strong exothermic reactions, oxidizing agents, strong alkalis, strong acids.

Hazardous decomposition products: Under normal conditions of storage and use, hazardous decomposition products should not be produced.

Disposal considerations

Waste treatment methods: Do not allow to enter drains or watercourses. Dispose of according to all federal, state and local applicable regulations.

Methods of disposal : The generation of waste should be avoided or minimized wherever possible. Empty containers or liners may retain some product residues. This material and its container must be disposed of in a safe way. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers.