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EC number: 700-071-4
CAS number: 932742-30-8
Sika Hardener LI is not classified as flammable liquid, flammable in contact with water, pyrophoric, self-reactive substance, self-heating substance or organic peroxide.
The test on the flammability (Regulation
(EC) No 440/2008 method A.10) was not performed as the test item is a
liquid. For liquids the primary value for ease of ignition is the flash
point conducted using Method A9 ‘Flash Point Method’ of Council
Regulation (EC) No 440/2008. The result of the Flash Point test is used
to allocate a liquid substance into the appropriate flammability class.
In accordance with section 2.9.4 Annex I of
Regulation (EC) No 1272/2008 and ECHA guidance on the application of CLP
Criteria section 188.8.131.52 the classification procedure for pyrophoric
liquids need not to be applied when experience in manufacturing or
handling shows that the substance or mixture does not ignite
spontaneously when coming into contact with air at normal temperatures.
Based on the experience in handling and use the substance is not known
to ignite spontaneously when coming into contact with air at normal
temperatures. Thus, no study was conducted.
Substances which, in contact with water,
emit flammable gases
In accordance with column 2 of REACH Annex
VI and with Regulation (EC) No 1272/2008 Annex I section 184.108.40.206 The
classification procedure for this hazard class need not be applied if:
a) The chemical structure of the substance
or mixture does not contain metals or metalloids; or
b) Experience in handling and use shows that
the substance or mixture does not react with water, e.g. the substance
is manufactured with water or washed with water; or
c) The substance or mixture is known to be
soluble in water to form a stable mixture.
Based on the experience in handling and use
the substance does not react with water and in addition the test
substance is not pyrophoric . Thus, no study was conducted.
Self-reactive substances and mixtures
In accordance with section R.220.127.116.11 ECHA
guidance IR/CSA chapter R.7a, section 2.9.1 ECHA guidance on the
application of CLP criteria and UN-MTC section 5.1 appendix 6 the test
for self-reactive substances was waived.
The test item does not contain any
functional groups quoted in ‘UN Manual of Tests and Criteria’ (fifth
revised edition, appendix 6, table A 6.1 and A 6.2) or Bretherick’s –
Handbook (6th Edition, Volume 2, p 128 ff) which may indicate explosive
or self-reacting properties. Therefore, it can be concluded by expert
judgment that the test item does not meet the criteria for self-reactive
substances, Thus no classification procedures for self-reactive
substances was is required.
Self-heating substances and mixtrures
In accordance with column 2 of Regulation
(EC) No 1907/2006Annex VII and section R.18.104.22.168 of ECHA guidance
IR/CSA, the UN Test method N.4 for self-heating substances and mixtures
do not need to be conducted as the substance is a liquid with no flash
point up to 200 °C
In accordance with Regulation (EC) No
1272/2008 Annex I section 2.15.1 only organic peroxides have to be
tested according to the UN-MTC, Part II test series A-H. Based on the
structure it can be concluded that the substance is not an organic
peroxide. Thus, no tests were conducted.
Based on the determined flash point (204.2
°C, Key study), the molecular structure and experience in handling and
use, the substance was not classified and labelled as flammable,
flammable in contact with water, pyrophoric, self-reactive substance,
self-heating substance and organic peroxide according to Directive
67/548/EEC (DSD) and Regulation (EC) No 1272/2008 (CLP).
In accordance with UN-Transport regulations
the substance has not to be classified as readily combustible solid and
self reactive substance in Class 4 Division 4.1 , as self-heating
substance in Class 4 Division 4.2, as substances which in contact with
water emit flammable gases in Class 4 Division 4.3 and as organic
peroxide in Class 5 division 5.2.
Information on Registered Substances comes from registration dossiers which have been assigned a registration number. The assignment of a registration number does however not guarantee that the information in the dossier is correct or that the dossier is compliant with Regulation (EC) No 1907/2006 (the REACH Regulation). This information has not been reviewed or verified by the Agency or any other authority. The content is subject to change without prior notice.Reproduction or further distribution of this information may be subject to copyright protection. Use of the information without obtaining the permission from the owner(s) of the respective information might violate the rights of the owner.
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