Registration Dossier
Registration Dossier
Data platform availability banner - registered substances factsheets
Please be aware that this old REACH registration data factsheet is no longer maintained; it remains frozen as of 19th May 2023.
The new ECHA CHEM database has been released by ECHA, and it now contains all REACH registration data. There are more details on the transition of ECHA's published data to ECHA CHEM here.
Diss Factsheets
Use of this information is subject to copyright laws and may require the permission of the owner of the information, as described in the ECHA Legal Notice.
EC number: 204-528-4 | CAS number: 122-20-3
- Life Cycle description
- Uses advised against
- Endpoint summary
- Appearance / physical state / colour
- Melting point / freezing point
- Boiling point
- Density
- Particle size distribution (Granulometry)
- Vapour pressure
- Partition coefficient
- Water solubility
- Solubility in organic solvents / fat solubility
- Surface tension
- Flash point
- Auto flammability
- Flammability
- Explosiveness
- Oxidising properties
- Oxidation reduction potential
- Stability in organic solvents and identity of relevant degradation products
- Storage stability and reactivity towards container material
- Stability: thermal, sunlight, metals
- pH
- Dissociation constant
- Viscosity
- Additional physico-chemical information
- Additional physico-chemical properties of nanomaterials
- Nanomaterial agglomeration / aggregation
- Nanomaterial crystalline phase
- Nanomaterial crystallite and grain size
- Nanomaterial aspect ratio / shape
- Nanomaterial specific surface area
- Nanomaterial Zeta potential
- Nanomaterial surface chemistry
- Nanomaterial dustiness
- Nanomaterial porosity
- Nanomaterial pour density
- Nanomaterial photocatalytic activity
- Nanomaterial radical formation potential
- Nanomaterial catalytic activity
- Endpoint summary
- Stability
- Biodegradation
- Bioaccumulation
- Transport and distribution
- Environmental data
- Additional information on environmental fate and behaviour
- Ecotoxicological Summary
- Aquatic toxicity
- Endpoint summary
- Short-term toxicity to fish
- Long-term toxicity to fish
- Short-term toxicity to aquatic invertebrates
- Long-term toxicity to aquatic invertebrates
- Toxicity to aquatic algae and cyanobacteria
- Toxicity to aquatic plants other than algae
- Toxicity to microorganisms
- Endocrine disrupter testing in aquatic vertebrates – in vivo
- Toxicity to other aquatic organisms
- Sediment toxicity
- Terrestrial toxicity
- Biological effects monitoring
- Biotransformation and kinetics
- Additional ecotoxological information
- Toxicological Summary
- Toxicokinetics, metabolism and distribution
- Acute Toxicity
- Irritation / corrosion
- Sensitisation
- Repeated dose toxicity
- Genetic toxicity
- Carcinogenicity
- Toxicity to reproduction
- Specific investigations
- Exposure related observations in humans
- Toxic effects on livestock and pets
- Additional toxicological data
Skin sensitisation
Administrative data
- Endpoint:
- skin sensitisation: in vivo (non-LLNA)
- Remarks:
- in vivo
- Type of information:
- experimental study
- Adequacy of study:
- key study
- Study period:
- 1986
- Reliability:
- 1 (reliable without restriction)
- Rationale for reliability incl. deficiencies:
- guideline study
Data source
Reference
- Reference Type:
- study report
- Title:
- Unnamed
- Year:
- 1 986
- Report date:
- 1986
Materials and methods
Test guideline
- Qualifier:
- equivalent or similar to guideline
- Guideline:
- EPA OPP 81-6 (Skin Sensitisation)
- GLP compliance:
- yes
- Type of study:
- other: Modification of the Maguire method (H.C. Maguire, 1973. The Bioassay of Contact Allergens in the Guinea Pig. J. Soc. Cosmet. Chem., 24, 151-162.)
- Justification for non-LLNA method:
- Currently no LLNA study is available for assessment. The Modified Maguire method has been carried out as an animal test to predict human sensitization and is recommended by international test guidelines such as EPA.
Test material
- Reference substance name:
- 1,1',1''-nitrilotripropan-2-ol
- EC Number:
- 204-528-4
- EC Name:
- 1,1',1''-nitrilotripropan-2-ol
- Cas Number:
- 122-20-3
- Molecular formula:
- C9H21NO3
- IUPAC Name:
- 1-[bis(2-hydroxypropyl)amino]propan-2-ol
Constituent 1
- Specific details on test material used for the study:
- 22.9% triisopropanolamine in water
In vivo test system
Test animals
- Species:
- guinea pig
- Strain:
- Hartley
- Sex:
- male
- Details on test animals and environmental conditions:
- The skin sensitization test was conducted on male Hartley albino guinea pigs weighing between 260 and 325 g (Charles River Breeding Laboratories, Inc., Kingston, NY). Upon arrival at the laboratory the guinea pigs were examined for health status by the laboratory veterinarian. Animals were housed five per wire-bottom cage in rooms designed to control temperature at approximately 22C, relative humidity at approximately 50% and a twelve-hour photocycle. Animal care facilities are fully accredited by the American Association for Accreditation of Laboratory Animal Care. They were supplied with Purina Certified Guinea Pig Chow #5026 (Ralston Purina Company, St. Louis, Missouri) and tap water ad libitum. Analysis of the certified feed was performed by the Ralston Purina Company to confirm that the diet provided adequate nutrition and to quantitate low levels of selected chemical contaminants. Analysis of the tap water (municipal water supply) was routinely performed according to the Standard Operating Procedures of the Mammalian and Environmental Toxicology Research Laboratory. All animals were acclimated to the laboratory environment at least one week prior to initiation of the study. Each animal was identified by a numbered metal ear tag and was randomly assigned to treatment groups.
Study design: in vivo (non-LLNA)
Induction
- Route:
- epicutaneous, semiocclusive
- Vehicle:
- water
- Concentration / amount:
- 22.9% / 0.1 mL
- Day(s)/duration:
- 4 applications within 10-day period
Challenge
- No.:
- #1
- Route:
- epicutaneous, open
- Vehicle:
- water
- Concentration / amount:
- 22.9% / 0.1 mL
- Day(s)/duration:
- single application after 2 weeks
- No. of animals per dose:
- 10
- Details on study design:
- The back of each guinea pig was clipped free of hair approximately 48 hours prior to study initiation. Twenty-four hours prior to the first application, Neet (hair cream remover) was applied over the clipped area to remove any remaining hair. Following this procedure, ten guinea pigs received four applications of the test material within ten days during the insult phase of the study. An additional group of ten guinea pigs received DER 331 epoxy resin as a 10% solution in DOWANOL DPM/Tween 80 (9:1). This epoxy resin is a known skin sensitizer and served as a positive control. Each insult application consisted of 0.1 mL of the test material or the positive control applied to an approximately 15 mm x 15 mm gauze square patch placed on the back of the guinea pig. This patch was covered with Micropore and secured with adhesive tape. At the time of the third application, a total of 0.2 mL of Freund's Adjuvant (Bacto-Adjuvant complete, H37RA DIFCO Laboratories, Detroit, Michigan) was injected intradermally at multiple points adjacent to the insult site. Observations for redness and/or edema were recorded each time the insult patches were removed. At the time of the last observation, the toe nails and distal portion of both rear feet were wrapped with adhesive tape. The animals were allowed to rest for at least two weeks. After the rest period, both flanks of the animal were clipped and the left flank was challenged with the test material or positive control. The right flanks of controls were challenged with solvent. The challenge application was not covered. Skin responses at these sites were recorded at 24 and 48 hours post-application. Guinea pigs were weighed weekly throughout the study.
Routine monitoring was limited to animal husbandry procedures required to ensure the availability of food and water. All guinea pigs were humanely euthanatized at study termination. - Challenge controls:
- The right flanks of controls were challenged with solvent.
- Positive control substance(s):
- yes
- Remarks:
- DER 331 epoxy resin as a 10% solution in Dowanol DPM/Tween 80 (9:1)
Results and discussion
- Positive control results:
- Slight to marked hyperemia was observed on ten of ten guinea pigs challenged with DER 331. The observed response in each animal was considered to be a positive response.
In vivo (non-LLNA)
Resultsopen allclose all
- Reading:
- 1st reading
- Hours after challenge:
- 24
- Group:
- test chemical
- Dose level:
- 22.9%
- No. with + reactions:
- 0
- Total no. in group:
- 10
- Remarks on result:
- no indication of skin sensitisation
- Reading:
- 2nd reading
- Hours after challenge:
- 48
- Group:
- test chemical
- Dose level:
- 22.9%
- No. with + reactions:
- 0
- Total no. in group:
- 10
- Remarks on result:
- no indication of skin sensitisation
- Reading:
- 1st reading
- Hours after challenge:
- 24
- Group:
- positive control
- Dose level:
- 10%
- No. with + reactions:
- 10
- Total no. in group:
- 10
- Clinical observations:
- slight to marked hyperemia
- Remarks on result:
- positive indication of skin sensitisation
- Reading:
- 2nd reading
- Hours after challenge:
- 48
- Group:
- positive control
- Dose level:
- 10%
- No. with + reactions:
- 10
- Total no. in group:
- 10
- Clinical observations:
- slight to marked hyperemia
- Remarks on result:
- positive indication of skin sensitisation
- Group:
- negative control
- Remarks on result:
- other: no information
Any other information on results incl. tables
None of the guinea pigs challenged with the test material revealed any signs of hyperemia or edema.
Applicant's summary and conclusion
- Interpretation of results:
- GHS criteria not met
Information on Registered Substances comes from registration dossiers which have been assigned a registration number. The assignment of a registration number does however not guarantee that the information in the dossier is correct or that the dossier is compliant with Regulation (EC) No 1907/2006 (the REACH Regulation). This information has not been reviewed or verified by the Agency or any other authority. The content is subject to change without prior notice.
Reproduction or further distribution of this information may be subject to copyright protection. Use of the information without obtaining the permission from the owner(s) of the respective information might violate the rights of the owner.