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EC number: 204-712-4 | CAS number: 124-76-5
- Life Cycle description
- Uses advised against
- Endpoint summary
- Appearance / physical state / colour
- Melting point / freezing point
- Boiling point
- Density
- Particle size distribution (Granulometry)
- Vapour pressure
- Partition coefficient
- Water solubility
- Solubility in organic solvents / fat solubility
- Surface tension
- Flash point
- Auto flammability
- Flammability
- Explosiveness
- Oxidising properties
- Oxidation reduction potential
- Stability in organic solvents and identity of relevant degradation products
- Storage stability and reactivity towards container material
- Stability: thermal, sunlight, metals
- pH
- Dissociation constant
- Viscosity
- Additional physico-chemical information
- Additional physico-chemical properties of nanomaterials
- Nanomaterial agglomeration / aggregation
- Nanomaterial crystalline phase
- Nanomaterial crystallite and grain size
- Nanomaterial aspect ratio / shape
- Nanomaterial specific surface area
- Nanomaterial Zeta potential
- Nanomaterial surface chemistry
- Nanomaterial dustiness
- Nanomaterial porosity
- Nanomaterial pour density
- Nanomaterial photocatalytic activity
- Nanomaterial radical formation potential
- Nanomaterial catalytic activity
- Endpoint summary
- Stability
- Biodegradation
- Bioaccumulation
- Transport and distribution
- Environmental data
- Additional information on environmental fate and behaviour
- Ecotoxicological Summary
- Aquatic toxicity
- Endpoint summary
- Short-term toxicity to fish
- Long-term toxicity to fish
- Short-term toxicity to aquatic invertebrates
- Long-term toxicity to aquatic invertebrates
- Toxicity to aquatic algae and cyanobacteria
- Toxicity to aquatic plants other than algae
- Toxicity to microorganisms
- Endocrine disrupter testing in aquatic vertebrates – in vivo
- Toxicity to other aquatic organisms
- Sediment toxicity
- Terrestrial toxicity
- Biological effects monitoring
- Biotransformation and kinetics
- Additional ecotoxological information
- Toxicological Summary
- Toxicokinetics, metabolism and distribution
- Acute Toxicity
- Irritation / corrosion
- Sensitisation
- Repeated dose toxicity
- Genetic toxicity
- Carcinogenicity
- Toxicity to reproduction
- Specific investigations
- Exposure related observations in humans
- Toxic effects on livestock and pets
- Additional toxicological data
Developmental toxicity / teratogenicity
Administrative data
- Endpoint:
- developmental toxicity
- Type of information:
- experimental study
- Adequacy of study:
- key study
- Study period:
- 22 April 1991 - 28 May 1991
- Reliability:
- 1 (reliable without restriction)
- Rationale for reliability incl. deficiencies:
- guideline study
Data source
Reference
- Reference Type:
- study report
- Title:
- Unnamed
- Year:
- 1 992
- Report date:
- 1992
Materials and methods
Test guideline
- Qualifier:
- according to guideline
- Guideline:
- OECD Guideline 414 (Prenatal Developmental Toxicity Study)
- GLP compliance:
- yes (incl. QA statement)
- Limit test:
- yes
Test material
- Reference substance name:
- Exo-1,7,7-trimethylbicyclo[2.2.1]hept-2-yl acetate
- EC Number:
- 204-727-6
- EC Name:
- Exo-1,7,7-trimethylbicyclo[2.2.1]hept-2-yl acetate
- Cas Number:
- 125-12-2
- Molecular formula:
- C12H20O2
- IUPAC Name:
- (1S,2S,4S) 1,7,7-trimethylbicyclo[2.2.1]hept-2-yl acetate
- Test material form:
- liquid
Constituent 1
Test animals
- Species:
- rat
- Strain:
- Wistar
- Details on test animals or test system and environmental conditions:
- TEST ANIMALS
- Source: Hoe: WISKf (SPF71)
- Age at study initiation: 65-70 days
- Weight at study initiation: 191 ± 6 g
- Housing: individually in plastic cages
- Diet (e.g. ad libitum): ad libitum
- Water (e.g. ad libitum): ad libitum
- Acclimation period: at least 7 days
ENVIRONMENTAL CONDITIONS
- Temperature (°C): 21-24 ° C
- Humidity (%): 49-53%
- Air changes (per hr): 16-20/h
- Photoperiod (hrs dark / hrs light): 12 light / 12 hours dark (450 Lux)
Administration / exposure
- Route of administration:
- oral: gavage
- Vehicle:
- other: sesame oil
- Details on exposure:
- PREPARATION OF DOSING SOLUTIONS: The substance was prepared fresh daily.
VEHICLE
- Concentration in vehicle: 200 g/L
- Amount of vehicle (if gavage): 5 mL/kg bw
OTHER:
- The stability and homogeneity of the solution was ensured for a period of 4 hours - Details on mating procedure:
- - Impregnation procedure: cohoused
- If cohoused: Females were mated overnight with fertile males.
- M/F ratio per cage: 1 male/1 female
- Proof of pregnancy: Sperm in vaginal smear referred to as day 1 of pregnancy - Duration of treatment / exposure:
- Gestation days 7-16
- Frequency of treatment:
- Once daily
- Duration of test:
- 21 days
Doses / concentrations
- Dose / conc.:
- 1 000 mg/kg bw/day (actual dose received)
- No. of animals per sex per dose:
- 20 mated females: test group
21 mated females: control group - Control animals:
- yes, concurrent vehicle
- Details on study design:
- - Dose selection rationale: A preliminary range-finding test was performed with 3 pair of rats per dose, in a trial. Animals were exposed to 270, 500 and 1000 mg/kg bw/day between day 7-16 of gestation. On day 21, animals were sacrificed. No effects were observed at the highest dose related to maternal toxicity, embryotoxicity and teratogenicity.
Examinations
- Maternal examinations:
- DETAILED CLINICAL OBSERVATIONS: Yes
- Time schedule: Daily
FOOD CONSUMPTION: Yes
- Food consumption for each animal determined and mean daily diet consumption calculated as g food/100 g body weight/day: Yes
BODY WEIGHT: Yes
- Time schedule for examinations: Once a week and a day after the last application
POST-MORTEM EXAMINATIONS: Yes
- Sacrifice on gestation day # 21
- Organs examined: macroscopic examination and organ weighing of heart, liver, kidneys and spleen - Ovaries and uterine content:
- The ovaries and uterine content was examined after termination: Yes
Examinations included:
- Gravid uterus weight: Yes
- Number of corpora lutea: Yes
- Number of implantations: Yes
- Number of resorptions: Yes
- Other: diameter of fetal resorption and placental weight - Fetal examinations:
- - External examinations: Yes: all per litter
- Body weight: Yes: all per litter
- External/visceral examinations: Yes: all per litter (external/visceral, abdominal cavity, liver, kidney)
- Skeletal examinations: Yes: all per litter (skeleton, skull, thoracic vert. centra, sacral vert. arch/centra, caudal vert. centra, extra vertebrae/extra rib, sternebra, rib, extra rib, pectoral girdle, forepan, forepan-phalanx, pelvic girdle, hindpaw, hindpaw-phalanx)
- Head examinations: Yes: all per litter
- Other:
Body cross-sections for Wilson, photography: Yes: half per litter
Dead fetus in uterus were fixed, stained and examined microscopically.
Remaining fetus, were fixed in Bouin solution and examined under stereomicroscope. - Statistics:
- Comparisons between body weights and organ weights in the test and control group were performed with a classical analysis of variance (MANOVA); to evaluate the relative feed intake, a analysis of variance according to Puri & Sen (1985). Corpora lutea and implantations were performed with the Mantel-Haenszel x2 test (Mantel & Haenszel, 1959), as well as live and dead fetuses and resorptions. Other parameters according to an analysis of variance. The body cross-sectional study of fetuses and skeletal findings were studied with the Fisher Exact test.
Results and discussion
Results: maternal animals
General toxicity (maternal animals)
- Clinical signs:
- no effects observed
- Description (incidence and severity):
- No adverse effects were observed. At Day 11 of gestation one female showed hair loss in the forelimbs and at Day 19 in the belly, flanks and hind limbs.
- Dermal irritation (if dermal study):
- not examined
- Mortality:
- not specified
- Body weight and weight changes:
- no effects observed
- Description (incidence and severity):
- No effects were observed. The body weight of the treated animals was similar to control animals.
- Food consumption and compound intake (if feeding study):
- no effects observed
- Description (incidence and severity):
- No adverse effects were observed. At the end of the study the food consumption was slightly higher in the treated group comparing with the control group.
- Food efficiency:
- not examined
- Water consumption and compound intake (if drinking water study):
- not examined
- Ophthalmological findings:
- not examined
- Haematological findings:
- not examined
- Clinical biochemistry findings:
- not examined
- Urinalysis findings:
- not examined
- Behaviour (functional findings):
- not examined
- Immunological findings:
- not examined
- Organ weight findings including organ / body weight ratios:
- no effects observed
- Description (incidence and severity):
- Two females of the treatment group showed moderate enlargement of the right kidney. No other changes were observed.
The heart, kidney, liver and spleen weight did not differ from those of the control group. - Gross pathological findings:
- no effects observed
- Description (incidence and severity):
- Two females of the treatment group showed moderate enlargement of the right kidney. No other changes were observed.
- Neuropathological findings:
- not examined
- Histopathological findings: non-neoplastic:
- not examined
- Histopathological findings: neoplastic:
- not examined
- Other effects:
- no effects observed
Maternal developmental toxicity
- Number of abortions:
- no effects observed
- Description (incidence and severity):
- The treated groups had a number of live fetuses similar to the control group.
- Pre- and post-implantation loss:
- no effects observed
- Description (incidence and severity):
- All females gave birth to live fetuses except 1 dam in the 1000 mg/kg bw group. This dam had no fetus, and only 5 empty implantations were observed. The corporea lutea were quite small and could not be accurately determined. The treated groups had corporea lutea, number of implantations and number of live fetuses similar to the control group.
- Total litter losses by resorption:
- no effects observed
- Early or late resorptions:
- no effects observed
- Dead fetuses:
- no effects observed
- Changes in pregnancy duration:
- not specified
- Description (incidence and severity):
- Migrated Data from removed field(s)
Field "Effects on pregnancy duration" (Path: ENDPOINT_STUDY_RECORD.DevelopmentalToxicityTeratogenicity.ResultsAndDiscussion.ResultsMaternalAnimals.MaternalDevelopmentalToxicity.EffectsOnPregnancyDuration): not specified - Changes in number of pregnant:
- not specified
- Other effects:
- no effects observed
Effect levels (maternal animals)
open allclose all
- Key result
- Dose descriptor:
- NOEL
- Effect level:
- 1 000 mg/kg bw/day (actual dose received)
- Based on:
- test mat.
- Basis for effect level:
- other: maternal toxicity
- Remarks on result:
- other: No effect observed at the highest dose tested
- Key result
- Dose descriptor:
- NOEL
- Effect level:
- 1 000 mg/kg bw/day (actual dose received)
- Based on:
- test mat.
- Basis for effect level:
- other: maternal developmental toxicity
- Remarks on result:
- other: No effect observed at the highest dose tested
Maternal abnormalities
- Key result
- Abnormalities:
- no effects observed
Results (fetuses)
- Fetal body weight changes:
- no effects observed
- Description (incidence and severity):
- Fetus were normally developed. Body weight and body lengths were similar from those in the control group. In the 1000 mg/kg bw treatment group, the number of live fetuses weighing less than 3 g was lower than in the control group.
Migrated Data from removed field(s)
Field "Fetal/pup body weight changes" (Path: ENDPOINT_STUDY_RECORD.DevelopmentalToxicityTeratogenicity.ResultsAndDiscussion.ResultsFetuses.FetalPupBodyWeightChanges): no effects observed - Reduction in number of live offspring:
- no effects observed
- Description (incidence and severity):
- Early intrauterine deaths were observed in both groups. The total number of deaths in the treated group was low and did not differ from the control group. Only one dead fetus was observed in the control groups.
- Changes in sex ratio:
- no effects observed
- Description (incidence and severity):
- The sex ratio was balanced in both groups, predominating males.
- Changes in litter size and weights:
- no effects observed
- Changes in postnatal survival:
- no effects observed
- External malformations:
- no effects observed
- Description (incidence and severity):
- No fetal malformations were observed. The body section and cross-section observations showed 5 fetuses with hematoma in the liver overlap. Although it was statistically significant, it was in accordance with historical control values. In three fetuses at 1000 mg/kg bw group, blood was found in the abdominal cavity. Nine fetus in the control group showed enlarged renal pelvis.
- Skeletal malformations:
- no effects observed
- Description (incidence and severity):
- The skeletons were about the same stage of development in both treatment and control groups, corresponding to the 21 day of pregnancy. The number of fetuses with weak ossification of head bones, sternebrae and metacarpal 5 was significantly higher than in the control group. However, it was in line with historical control values. One fetus showed week ossidification of metatarsal 5, phalanx III, ischium and the pubis. Besides these findings, thoracic vertebra with a short or normal length, corrugated/thickened rib, short of fragmented cervical rib and displaces sternebrae were observed in both treatment and control groups. All the effects were within the historical control values.
- Visceral malformations:
- no effects observed
- Description (incidence and severity):
- Placental weight in live fetuses (including) macroscopic findings, were similar in both treatment and control groups.
The dead fetus of the control group was retarded in development, which is in accordance with weaker ossification. An examination of the internal organs was not possible because of the small size. - Other effects:
- no effects observed
Effect levels (fetuses)
- Key result
- Dose descriptor:
- NOEL
- Effect level:
- 1 000 mg/kg bw/day (actual dose received)
- Based on:
- test mat.
- Basis for effect level:
- other: Fetuses toxicity
- Remarks on result:
- other: No effect observed at the highest dose tested
Fetal abnormalities
- Key result
- Abnormalities:
- no effects observed
Overall developmental toxicity
- Key result
- Developmental effects observed:
- no
Applicant's summary and conclusion
- Conclusions:
- The NOEL for maternal and developmental toxicity after an oral exposure of isobornyl acetate was determined to be 1000 mg/kg bw/day in rats under test conditions.
- Executive summary:
A pre-natal developmental toxicity test was performed with isobornyl acetate according to OECD Guideline 414. 20 female Wistar rats were exposed by gavage to 0 (control) and 1000 mg/kg bw/day test item between Days 7 and 16 of gestation, in a limit test. On Day 21 of gestation, the animals were killed and both dams and fetus were examined. The investigations showed that the repeated oral exposure to the test item during the sensitive period of organogenesis, do not cause an impairment of the general health of dams, not disturbing the intrauterine development of fetus. The morphological examination of fetuses revealed no evidence for teratogenic effects of the substance. Therefore, the NOEL of isobornyl acetate for maternal and fetal developmental toxicity was determined to be 1000 mg/kg bw/day in rats.
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