Registration Dossier

Guidance on Safe Use

Guidance on Safe Use

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Administrative data

First-aid measures

Description of first aid measures:
Symptoms of poisoning may only appear several hours later.
If you feel unwell, seek medical advice (show the label where possible).
Remove contaminated or saturated clothing immediately and dispose of safely.

Inhalation:
Provide fresh air, seek medical advice if necessary.
If the casualty is not breathing: Perform mouth-to-mouth resuscitation, notify emergency physician immediately.
Observe self-protection.

Skin contact:
Wash off with soap and water.
Consult a physician immediately if skin is irritated or reddened.

Eye contact:
Rinse immediately with plenty of water for 15 minutes and seek advice of an eye specialist.

Ingestion:
Flush mouth immediately, then drink plenty of water, avoid vomiting, consult physician.

Most important symptoms and effects, both acute and delayed:
Symptoms:
Allergic reactions:
May cause irritations of the respiratory tract.

Hazards:
Carcinogenic effects.

Indication of any immediate medical attention and special treatment needed:
Treatment of symptoms.
Keep under medical supervision for at least 48 hours.

Fire-fighting measures

Extinguishing media:
Suitable extinguishing media:
Water spray, foam, CO2, dry powder.

Unsuitable extinguishing media:
Do not use a solid water stream as it may scatter and spread fire.

Special hazards arising from the substance or mixture:
Hazard-determining flue gases might develop in case of fire:
Nitrogen oxides (NOx)
Carbon oxides
Ammonia.

Advice for firefighters:
Contaminated extinguishing water must be treated at a suitable disposal plant in accordance with waste management laws.
In case of fire, remove the endangered barrels and bring to a safe place, if this can be done safely.
Keep out unprotected persons.
In case of fire cool containers or take them to a safe place.
Wear a self contained respiratory apparatus.
Full protective suit.

Accidental release measures

Personal precautions, protective equipment and emergency procedures:
Wear personal protective equipment.
Avoid formation of dust.
Ensure sufficient ventilation.

Environmental precautions:
Prevent substance from entering soil, natural bodies of water and sewer systems.
If the product contaminates rivers and lakes or drains inform respective authorities.

Methods and material for containment and cleaning up:
Collect up material.
Transfer into suitable containers for recovery or disposal.
Disposal according to local authority regulations.
Avoid dust formation.

Handling and storage

Precautions for safe handling:
Refill and handle product only in closed system.
Provide sufficient ventilation and exhaust at the workplace.
Ensure that apparatus and pipelines are free from leaks.
Do not ventilate into the open.
The product should only be handled by trained personnel.

Conditions for safe storage, including any incompatibilities:
Advice on protection against fire and explosion:
Keep away from combustion sources such as sparks, flames and unprotected light sources.
When using do not smoke.
Take precautionary measures against static charges, keep away from sources of ignition.

Storage:
Store in the original receptacle, keeping this tightly sealed, under cool and dry conditions.

Further information:
None.

Advice on common storage:
No special measures are required.
German storage class:
C - Combustible, acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects.

Transport information

Land transport (ADR/RID)

UN number:
UN 1709
Proper shipping name and description:
2,4-TOLUYLENEDIAMINE, SOLID
Chemical name:
2,4-Toluylenediamine (2,4-TDA)
Language:
English
Class:
6.1
Classification code:
T2
Packaging group:
III
Labels:
6.1
SpecialProvisionsopen allclose all

Inland waterway transport (ADN(R))

UN number:
UN 1709
Proper shipping name and description:
2,4-TOLUYLENEDIAMINE, SOLID
Chemical name:
2,4-Toluylenediamine (2,4-TDA)
Language:
English
Class:
6.1
Classification code:
T2
Packaging group:
III
Labels:
6.1
Remarksopen allclose all

Marine transport (IMDG)

UN number:
UN 1709
Proper shipping name and description:
2,4-TOLUYLENEDIAMINE, SOLID
Chemical name:
2,4-Toluylenediamine (2,4-TDA)
Class:
6.1
Packaging group:
III
EmS code:
F-A, S-A
Labels:
6.1
Marine pollutant
Remarksopen allclose all

Air transport ICAO/IATA

UN number:
UN 1709
Proper shipping name and description:
2,4-Toluylenediamine, solid
Chemical name:
2,4-Toluylenediamine (2,4-TDA)
Class:
6.1
Packaging group:
III
Labels:
6.1
Remarksopen allclose all

Additional transport information

Additional transport information
Loading instructions/Remarks:
IATA_C:
ERG-Code 6L
IATA_P:
ERG-Code 6L
Keep separate from foodstuffs, luxury foods, feedstuffs.

Exposure controls / personal protection

Exposure controls:
Engineering measures:
Refill and handle product only in closed system.
Do not add wastewater to a biological wastewater treatment plant.
All precautionary measures indicated have to be observed.
Provide for installation of emergency shower and eye bath.
Ensure suitable suction/aeration at the work place and with operational machinery.
In case product dust is released:
Exhaust ventilation equipped with filters.

Exposure controls:
Minimisation of emissions by means of suitable technical measures such as flanges and valves with low leakage rates, recirculation of vapours.
The substance must be handled under strictly controlled conditions in accordance with Article 17/18 of the REACH regulation.

Personal protective equipment:
Respiratory protection:
Accidental release measures:
In the case of respirable dust, use self-contained breathing apparatus.
Note time limit for wearing respiratory protective equipment.

Hand protection:
No protective glove type has been specified for use with this product.
The glove listed is only a preliminary, recommendation issued by Kächele-Cama Latex GmbH, Am Kreuzacker 9, D-36124 Eichenzell, www.kcl.de, which firm offers such protective gloves.
The glove must be changed immediately if any changes in it occur (e.g. swelling, wear).
Accidental release measures:
Recommendation: Butoject 898.

Eye protection:
Safety glasses with side-shields conforming to EN166.
Accidental release measures:
Close-fitting protective goggles (e.g. closed goggles).

Skin and body protection:
Select materials and equipment for physical protection depending on the concentration and volume of hazardous substances and the workplace involved.
In case of hazard of substance release:
For example
Chemical protective suit, disposable protective suit.
or
Complete protective clothing, which can be cleaned and decontaminated with water.

Hygiene measures:
Remove immediately all contaminated clothing.
Provide adequate ventilation.
Avoid contact with skin and eyes.
Do not eat, drink, smoke, or sniff while at work.
Wash your hands and/or face before breaks and before termination of work.

Protective measures:
Risk assessment and risk monitoring of all work places required.
Health, Safety and Emergency Management System recommended.
Written approval necessary in case of non-routine jobs, e.g. maintenance activities.
Regular safety training is a must.
All precautionary measures indicated have to be observed.

Stability and reactivity

Reactivity:
Chemical stability:
Possibility of hazardous reactions:
Reaction with strong oxidants.

Conditions to avoid:
No decomposition if used as directed.
Take precautionary measures against static discharges.
Avoid shock and friction.

Incompatible materials;
No specific hazards are known.

Hazardous decomposition products:
No hazardous decomposition products known.

Disposal considerations

Product:
Do not add wastewater to a biological wastewater treatment plant.
Bring used exhaust air filter for incineration.
Disposal according to local authority regulations.

Uncleaned packaging:
Uncontaminated packaging may be recycled.
Dispose of as special waste in compliance with local and national regulations.