Registration Dossier

Guidance on Safe Use

Guidance on Safe Use

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First-aid measures

Description of first aid measures
Remove contaminated clothing.

If inhaled:
Keep patient calm, remove to fresh air, seek medical attention.

On skin contact:
Wash thoroughly with soap and water. If irritation develops, seek medical attention.

On contact with eyes:
Wash affected eyes for at least 15 minutes under running water with eyelids held open. If irritation develops, seek medical attention.

On ingestion:
Rinse mouth immediately and then drink plenty of water, seek medical attention.

Most important symptoms and effects, both acute and delayed
Symptoms: The most important known symptoms and effects are described in the labelling (see section 2) and/or in section 11., Further symptoms are possible

Indication of any immediate medical attention and special treatment needed
Treatment: Treat according to symptoms (decontamination, vital functions), no known specific antidote.

Fire-fighting measures

Extinguishing media
Suitable extinguishing media:
water spray, dry powder, foam, carbon dioxide

Special hazards arising from the substance or mixture
nitrogen oxides, carbon oxides
The substances/groups of substances mentioned can be released in case of fire. Under certain conditions in case of fire other hazardous combustion products may be generated.

Advice for fire-fighters
Special protective equipment:
Wear self-contained breathing apparatus and chemical-protective clothing.

Further information:
Collect contaminated extinguishing water separately, do not allow to reach sewage or effluent systems.

Accidental release measures

Personal precautions, protective equipment and emergency procedures
Avoid inhalation. Avoid contact with the skin, eyes and clothing.

Environmental precautions
Do not empty into drains.

Methods and material for containment and cleaning up
For large amounts: Pump off product.
For residues: Pick up with suitable absorbent material (e.g. sand, sawdust, general-purpose binder, kieselguhr). Dispose of absorbed material in accordance with regulations.

Reference to other sections
Information regarding exposure controls/personal protection and disposal considerations can be found in section 8 and 13.

Handling and storage

Precautions for safe handling
Ensure thorough ventilation of stores and work areas. Prevent contact with air/oxygen (formation of peroxide).

Protection against fire and explosion:
Take precautionary measures against static discharges. Sources of ignition should be kept well clear.

Conditions for safe storage, including any incompatibilities
Further information on storage conditions: Keep under inert gas.

Storage stability:
Storage duration: 24 Months
From the data on storage duration in this safety data sheet no agreed statement regarding the warrantee of application properties can be deduced.

Specific end use(s)
For the relevant identified use(s) listed in Section 1 the advice mentioned in this section 7 is to be observed.

Transport information

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Marine transport (IMDG)

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Exposure controls / personal protection

Control parameters

Components with workplace control parameters

No occupational exposure limits known.

Exposure controls
Personal protective equipment
Respiratory protection:
Wear respiratory protection if ventilation is inadequate.

Hand protection:
Chemical resistant protective gloves (EN 374)
Suitable materials short-term contact and/or splashes (recommended: At least protective index 2, corresponding > 30 minutes of permeation time according to EN 374)
fluoroelastomer (FKM) - 0.7 mm coating thickness
Manufacturer's directions for use should be observed because of great diversity of types.
Supplementary note: The specifications are based on tests, literature data and information of glove manufacturers or are derived from similar substances by analogy. Due to many conditions (e.g. temperature) it must be considered, that the practical usage of a chemical-protective glove in practice may be much shorter than the permeation time determined through testing.

Eye protection:
Safety glasses with side-shields (frame goggles) (e.g. EN 166)

General safety and hygiene measures
Handle in accordance with good industrial hygiene and safety practice. Avoid contact with the skin, eyes and clothing. Do not breathe vapour/spray. Wearing of closed work clothing is required additionally to the stated personal protection equipment.

Stability and reactivity

Reactivity
Vapours may form explosive mixture with air.

Corrosion to metals: No corrosive effect on metal.
Reactions with water/air: Reaction with: air
Peroxides: yes

Formation of flammable gases: Remarks: Forms no flammable gases in the presence of water.

Chemical stability
The product is stable if stored and handled as prescribed/indicated.

Possibility of hazardous reactions
Evolution of heat under influence of acids. Possibility of peroxide formation. Hazardous reactions in presence of mentioned substances to avoid.

Conditions to avoid
Avoid all sources of ignition: heat, sparks, open flame.

Incompatible materials

Substances to avoid:
acids, thiols, alcohols, amides

Hazardous decomposition products

Possible decomposition products:
peroxides

Disposal considerations

Waste treatment methods

Incinerate in suitable incineration plant, observing local authority regulations.
A waste code in accordance with the European waste catalog (EWC) cannot be specified, due to dependence on the usage.
The waste code in accordance with the European waste catalog (EWC) must be specified in cooperation with disposal agency/manufacturer/authorities.

Contaminated packaging:
Contaminated packaging should be emptied as far as possible; then it can be passed on for recycling after being thoroughly cleaned.