Registration Dossier

Administrative data

First-aid measures

Emergency measure - Inhalation: If inhaled, provide fresh air, warmth, rest and seek medical
advice.
Emergency measure - Eyes: Wash out eyes thoroughly with plenty of water for fifteen
minutes. If necessary, seek medical advice.
Emergency measure - Skin: Take off contaminated clothing and shoes immediately. Immediately wash contaminated skin with soap and large
quantities of water for fifteen minutes. If necessary, seek
medical advice.
Emergency measure - Ingestion: Do NOT induce vomiting. Drink plenty of water and seek medical advice.

Fire-fighting measures

Recommended extinguishing agent: To suit local surroundings (dry chemical, water spray, foam).
Recommended protective equipment: Full protective clothing and self-contained breathing apparatus must be worn.
Fight the fire from a safe distance or protected location.


Product arising from burning: The substance is combustible and will burn if involved in a
fire, evolving noxious fumes (eg carbon, nitrogen and
silicone oxides).

Product determined by test: N

Protective equipment: Full protective clothing and self-contained breathing
apparatus must be worn.


Fight the fire from a safe distance or protected location.

Accidental release measures

Emergency measures in case of spillage: Evacuate personnel from immediate vicinity. Prevent release to drains and waterways.
Wear appropriate personal protective equipment depending on the nature of the spill. PPE may include tight fitting safety goggles, lab coat and impervious gloves and respiratory protection. For larger spills additional protective clothing and equipment such as a self-contained breathing apparatuswith coverall of low permeability may be needed.

Wet down to avoid dust formation. Absorb spillages of solutions with a suitable inert material (eg. sand or soil). Contain and collect spillage and place in to waste containers for disposal. Use a sealed industrial vacuum machine (HEPA) or moisten materials to minimize dust generation during pick-up. Clean area wih detergent and water after spill pick-up if appropriate. Dispose of waste material in accordance with local regulations.

Handling and storage

Handling: The substance should be stored, handled and used under conditions of good industrial hygiene and in conformity with
any local regulations in order to avoid exposure. Engineering controls are necessary to reduce exposure to the substance.
When exposure cannot be prevented or adequately controlled appropriate personal protective equipment should be worn.
Such protective equipment should conform to the appropriate international or national standards.
Furthermore, when respiratory protective equipment has to be used, it must be capable of adequately controlling
exposure, be suitable for the purpose, and conform to the appropriate international or national standards.
Storage: Store in a cool dry place away from sources of ignition. Keep containers tightly closed when not in use. Protect against light.
Packaging of the substance and or preparation: UN approved fibre drums.

Transport information

Land transport (ADR/RID)

UN number:
Not classified
Shippingopen allclose all
Class:
Not applicable
Classification code:
Not applicable
Packaging group:
Not applicable
Labels:
Not applicable
SpecialProvisionsopen allclose all

Inland waterway transport (ADN(R))

UN number:
Not classified
Shippingopen allclose all
Class:
Not applicable
Classification code:
Not applicable
Packaging group:
Not applicable
Labels:
Not applicable
Remarksopen allclose all

Marine transport (IMDG)

UN number:
Not classified
Proper shipping name and description:
Not applicable
Chemical name:
Not applicable
Class:
Not applicable
Packaging group:
Not applicable
EmS code:
Not applicable
Labels:
Not applicable
Remarksopen allclose all

Air transport ICAO/IATA

UN number:
not classified
Proper shipping name and description:
Not applicable
Chemical name:
Not applicable
Class:
Not applicable
Packaging group:
Not applicable
Labels:
Not applicable
Remarksopen allclose all

Additional transport information

Additional transport information
Transport code: Not classified
Transport: Avoid crushing the containers. In the event of a spillage, observe the warning labels on the container.

Exposure controls / personal protection

Critical points for possible workplace exposure are product charging, sampling, and cleaning and disposal of drums. Engineering controls in the form of closed transfer systems with local exhaust ventilation are provided during charging. When they are not sufficient to control exposure, approved respiratory protection should be worn. Respiratory protection should be selected based on exposure potential and according to standard EN 140/EN 136 (half full face respirators), EN 12941/EN12942 (powdered air purifying respirators; loose-fitting/full face) or EN 139 (full face supplied air respirator). For manufacturing areas skin protection should be provided in the form of coveralls (EN 1149-1) or full air suits (EN 465) along with impervious nitrile, rubber or latex gloves (EN374, EN 420). Gloves should be changed regularly and removed after overt contamination. Chemical safety goggles should be worn if a full-face respirator is not being worn (EN 166).

Stability and reactivity

Stable under recommended storage conditions.
Danger other than fire: None known.
Chemical reaction with water: None which is hazardous.
Hazardous decomposition products formed under fire conditions: carbon oxides(COx), nitrogen oxides (NOx) and SiOx
Dust explosion: Although material has not been specifically tested, fine dust suspended in air in sufficient concentration and in the
presence of an ignition source may pose a potential explosion hazard. Provide appropriate bonding and grounding
protection to control static charge. Powder handling quipment such as dust collectors, dryers, and mills may
require additional protective measures (e.g. explosive venting).

Disposal considerations

Disposal should be in accordance with applicable regional, national and local laws and regulations. Disposal by incineration in recommended.

Industry - Possibility of recovery/recycling: Discharge to the environment will be minimal. Recovery from minor spillages or accidental discharge is not economically or technically feasible, and such waste material will be disposed of by incineration. In principle, it may be possible to recover larger spillages of uncontaminated material for subsequent use.

Industry - Possibility of neutralisation: The notification tests have shown that the substance is irritating to the eyes. No chemical treatment is practicable to neutralise the hazardous health or hazardous environmental properties.

Industry - Possibility of destruction:
-Controlled discharge: Contaminated containers or spillages of solutions mixed with inert material (eg. sand or soil) may be disposed of by incineration in accordance with local regulations.
- Incineration: Incineration is recommended for larger quantities of waste. A closed-cycle incinerator with scrubbers should be employed
- Water purification: Biological oxidation occurs at the waste water treatment plants. Trace quantities are destroyed by biological oxidation in the WWTP on site and trace quantities in aqueous washes can be treated in secondary biological WWTP before discharge to municipal treatment works. The substance should not normally be discharged directly to the sewage system or the aqueous environment. However, adverse effects on sewage treatment systems would be unlikely.