Registration Dossier

Administrative data

First-aid measures

Description of first aid measures
Immediately remove contaminated clothing. If danger of loss of consciousness, place patient in recovery position and transport accordingly. Apply artificial respiration if necessary. First aid personnel should pay attention to their own safety.

If inhaled:
Keep patient calm, remove to fresh air, seek medical attention. Immediately inhale corticosteroid dose aerosol.

On skin contact:
Immediately wash thoroughly with plenty of water, apply sterile dressings, consult a skin specialist.

On contact with eyes:
Immediately wash affected eyes for at least 15 minutes under running water with eyelids held open, consult an eye specialist.

On ingestion:
Rinse mouth immediately and then drink plenty of water, seek medical attention.

Most important symptoms and effects, both acute and delayed
Symptoms: The most important known symptoms and effects are described in the labelling (see section 2) and/or in section 11.

Indication of any immediate medical attention and special treatment needed
Treatment: Treat according to symptoms (decontamination, vital functions), no known specific antidote. Pulmonary odema prophylaxis. Medical monitoring for at least 24 hours.

Fire-fighting measures

Extinguishing media
Suitable extinguishing media:
water spray, dry powder, foam, carbon dioxide

Special hazards arising from the substance or mixture

If product is heated above decomposition temperature, toxic vapours will be released.

Advice for fire-fighters
Special protective equipment:
Wear self-contained breathing apparatus and chemical-protective clothing.

Further information:
Dispose of fire debris and contaminated extinguishing water in accordance with official regulations.

Accidental release measures

Personal precautions, protective equipment and emergency procedures
Avoid inhalation. Avoid contact with the skin, eyes and clothing.

Environmental precautions
Do not discharge into drains/surface waters/groundwater.

Methods and material for containment and cleaning up
For small amounts: Pick up with suitable appliance and dispose of.
For large amounts: Pick up with suitable appliance and dispose of.

Reference to other sections
Information regarding exposure controls/personal protection and disposal considerations can be found in section 8 and 13.

Handling and storage

Precautions for safe handling
Ensure thorough ventilation of stores and work areas.
Protection against fire and explosion:
Prevent electrostatic charge - sources of ignition should be kept well clear - fire extinguishers should be kept handy.

Conditions for safe storage, including any incompatibilities
Segregate from acids and acid forming substances.
Further information on storage conditions: Containers should be stored tightly sealed in a dry place.

Storage stability:
Storage duration: 24 Months
From the data on storage duration in this safety data sheet no agreed statement regarding the warrantee of application properties can be deduced.

Transport information

Land transport (ADR/RID)

UN number:
UN 2386
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Class:
3
Packaging group:
II
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Inland waterway transport (ADN(R))

UN number:
UN 2386
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Class:
3
Packaging group:
II
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Marine transport (IMDG)

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Exposure controls / personal protection


Control parameters
Components with workplace control parameters

No occupational exposure limits known.

Exposure controls
Personal protective equipment
Respiratory protection:
Respiratory protection in case of vapour/aerosol release.

Hand protection:
Chemical resistant protective gloves (EN 374)
Suitable materials also with prolonged, direct contact (Recommended: Protective index 6, corresponding > 480 minutes of permeation time according to EN 374):
nitrile rubber (NBR) - 0.4 mm coating thickness
Manufacturer's directions for use should be observed because of great diversity of types.

Supplementary note: The specifications are based on tests, literature data and information of glove manufacturers or are derived from similar substances by analogy. Due to many conditions (e.g. temperature) it must be considered, that the practical usage of a chemical-protective glove in practice may be much shorter than the permeation time determined through testing.

Eye protection:
Tightly fitting safety goggles (cage goggles) (e.g. EN 166) and face shield.

Body protection:
Body protection must be chosen depending on activity and possible exposure, e.g. apron, protecting boots, chemical-protection suit (according to EN 14605 in case of splashes or EN ISO 13982 in case of dust).

General safety and hygiene measures
Handle in accordance with good industrial hygiene and safety practice. Wearing of closed work clothing is required additionally to the stated personal protection equipment. Avoid contact with the skin, eyes and clothing. Do not breathe vapour/spray.

Stability and reactivity

Reactivity
Formation of flammable gases:
Remarks: Forms no flammable gases in the presence of water.

Chemical stability

The product is stable if stored and handled as prescribed/indicated.

Possibility of hazardous reactions
Reacts with acids and strong oxidizing agents. Strong exothermic reaction.
Conditions to avoid
Avoid all sources of ignition: heat, sparks, open flame. See MSDS section 7 - Handling and storage.

Incompatible materials

Substances to avoid:
strong oxidizing agents, strong acids

Hazardous decomposition products
Hazardous decomposition products:
carbon oxides, nitrogen oxides, nitrous gases

Disposal considerations

Waste treatment methods

Incinerate in suitable incineration plant, observing local authority regulations.

A waste code in accordance with the European waste catalog (EWC) cannot be specified, due to dependence on the usage.
The waste code in accordance with the European waste catalog (EWC) must be specified in cooperation with disposal agency/manufacturer/authorities.


Contaminated packaging:
Contaminated packaging should be emptied as far as possible; then it can be passed on for recycling after being thoroughly cleaned.