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Diss Factsheets

Physical & Chemical properties

Flammability

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Administrative data

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Endpoint:
substances / mixtures which in contact with water emit flammable gases
Type of information:
experimental study
Adequacy of study:
weight of evidence
Reliability:
1 (reliable without restriction)
Rationale for reliability incl. deficiencies:
guideline study
Qualifier:
according to guideline
Guideline:
EU Method A.12 (Flammability (Contact with Water))
Deviations:
no
Qualifier:
according to guideline
Guideline:
UN Manual of Tests and Criteria: Test N.5 (Test method for substances which in contact with water emit flammable gases)
Qualifier:
according to guideline
Guideline:
other: United Nations (UN), UN no. ST/SG/AC.10/11/Rev.5: Recommendations on the Transport of Dangerous Goods, Appendix 6: “Screening Procedures”, 2009.
GLP compliance:
yes (incl. QA statement)
Remarks on result:
no reaction with water observed
Remarks:
The test substance does not contain groups that might lead to ignition in contact with water and/or to the evolution of a flammable gas.

A test substance is considered highly flammable when it ignites spontaneously in contact with water, or evolves a flammable gas at a minimum rate of ≥ 1 litre/kg of the substance per hour. The test substance does not contain groups that might lead to ignition in contact with water and/or to the evolution of a flammable gas. In conclusion, CH03220 is considered ‘not highly flammable’ in contact with water.

Interpretation of results:
not classified based on GHS criteria
Remarks:
Migrated information
Conclusions:
CH03220 is not highly flammable in contact with water, based on the molecular structure.
Endpoint:
flammable solids
Type of information:
experimental study
Adequacy of study:
weight of evidence
Reliability:
1 (reliable without restriction)
Rationale for reliability incl. deficiencies:
guideline study
Qualifier:
according to guideline
Guideline:
EU Method A.10 (Flammability (Solids))
Deviations:
no
Qualifier:
according to guideline
Guideline:
UN Manual of Tests and Criteria: Test N.1 (Test method for readily combustible solids)
Version / remarks:
2009
GLP compliance:
yes (incl. QA statement)
Test procedure:
burning rate test: preliminary screening test
Burning time:
0 s
Remarks on result:
substance does not ignite and propagate combustion either by burning with flame or smouldering along 200 mm of the powder train within the 2 minutes test period

In contact with the flame of the gas burner the test substance melted and turned into a black residue with a blue and purple glow. White smoke was observed. After removal of the ignition source, no propagation of combustion of the test substance was observed.

Interpretation of results:
not classified based on GHS criteria
Conclusions:
The preliminary screening test was performed for the determination of the flammability of CH03220.
No propagation of combustion of the test substance along 200 mm length of the pile within 4 minutes was observed. According to the guidelines, performance of the burning rate test is not required. Based on the results obtained, the test substance is considered ‘not highly flammable’.
Endpoint:
flammable solids
Type of information:
experimental study
Adequacy of study:
weight of evidence
Study period:
1998
Reliability:
1 (reliable without restriction)
Rationale for reliability incl. deficiencies:
guideline study
Qualifier:
according to guideline
Guideline:
EU Method A.10 (Flammability (Solids))
Qualifier:
according to guideline
Guideline:
other: VDI 2263: "Test methods for the determination of the safety characteristics of dusts" May 1990
GLP compliance:
not specified
Test procedure:
burning time over 250 mm for metal powders or metal alloys
Remarks:
At both room temperature and 100°C
Burning time:
0 s
Remarks on result:
substance does not ignite and propagate combustion either by burning with flame or smouldering along 200 mm of the powder train within the 2 minutes test period

The test substance melted and coloured black in contact with the ignition source.

Interpretation of results:
GHS criteria not met
Conclusions:
V84139 is not highly flammable.

Description of key information

Based on the results obtained, the test substance is considered ‘not highly flammable’. CH03220 is also considered ‘not highly flammable’ in contact with water. CH03220 has no pyrophoric properties.

Key value for chemical safety assessment

Flammability:
not classified

Additional information

Justification for classification or non-classification