Registration Dossier

Administrative data

First-aid measures

In case of skin contact:
Immediately take off all contaminated clothing and shoes.
OBTAIN IMMEDIATE MEDICAL ATTENTION.
Immediately remove any contaminated clothing, shoes or stockings.
After contact with skin, wash immediately with soap and plenty of water.
In case of eye contact:
Wash immediately and thoroughly with running water, keeping eyelids regularly raised, for at least 15 minutes. Cold water
may be used. Check for and remove any contact lenses at once. OBTAIN A MEDICAL EXAMINATION.
Protect the eyes with a sterile gauze or a clean, dry handkerchief.
In case of ingestion:
Give nothing to eat or drink.
If symptoms persist consult doctor.
In case of inhalation:
Remove casualty to fresh air and keep warm and at rest.

Most important symptoms and effects, both acute and delayed
Eye irritation
Eye damage

Indication of any immediate medical attention and special treatment needed
In case of accident or unwellness, seek medical advice immediately (show directions for use or safety data sheet if possible).

Fire-fighting measures

Extinguishing media
Suitable extinguishing media:
Water, CO2, foam, chemical powders, according to the materials involved in the fire.
In case of fire, use foam, dry chemical, CO2.
Unsuitable extinguishing media:
None in particular.

Special hazards arising from the substance or mixture
Do not inhale explosion and combustion gases.
Burning produces heavy smoke.

Advice for fire-fighters
Use suitable breathing apparatus .
Collect contaminated fire extinguishing water separately. This must not be discharged into drains.
Move undamaged containers from immediate hazard area if it can be done safely.

Accidental release measures

Personal precautions, protective equipment and emergency procedures
Wear personal protection equipment.
Remove persons to safety.

Environmental precautions
Do not allow to enter into soil/subsoil. Do not allow to enter into surface water or drains.
Retain contaminated washing water and dispose of it following local legislation.
In case of gas escape or of entry into waterways, soil or drains, inform the responsible authorities if required.
Suitable material for taking up: dry and inert absorbing material (e.g. vermiculite, sand, earth).

Methods and material for containment and cleaning up
Suitable material for taking up: dry and inert absorbing material (e.g. vermiculite, sand, earth).
Wash with plenty of water.

Handling and storage

Precautions for safe handling:
Avoid contact with skin and eyes, inhalation of vapours and mists.
Don't use empty container before they have been cleaned.
Before making transfer operations, assure that there aren't any incompatible material residuals in the containers.
Contamined clothing should be changed before entering eating areas.
Do not eat or drink while working.

Conditions for safe storage, including any incompatibilities
Store in a tightly closed container in a cool, dry, well-ventilated area.
Incompatible materials:
None in particular.
Instructions as regards storage premises:
Adequately ventilated premises.

Specific end use(s)
Recommendation(s)
Storage Temperature < 25°C
Industrial sector specific solutions:
None in particular.

Transport information

Land transport (ADR/RID)

UN number:
3077
Shippingopen allclose all
Class:
9
Packaging group:
III
Labels:
Exempted for ADR: No
ADR-Label: 9
ADR-Upper number: 90
ADR-Special Provisions: N/A
ADR-Transport category (Tunnel restriction code): (E)
SpecialProvisionsopen allclose all
Shippingopen allclose all
Remarksopen allclose all

Marine transport (IMDG)

UN number:
3077
Proper shipping name and description:
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (2-[(4-aminophenyl)azo]-1,3-dimethyl-1H-imidazolium chloride)
Chemical name:
(2-[(4-aminophenyl)azo]-1,3-dimethyl-1H-imidazolium chloride)
Class:
9
Packaging group:
III
EmS code:
F-A, S-F
Labels:
IMDG-Stowage Code: Category: A
IMDG-Stowage Note: N/A
IMDG-Sub Risk: N/A
IMDG-Special Provisioning: N/A
IMDG-Page: N/A
IMDG-Label: 9
IMDG-EMS: F-A, S-F
IMDG-MFAG: N/A
Marine pollutant
Remarksopen allclose all

Air transport ICAO/IATA

UN number:
3077
Proper shipping name and description:
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (2-[(4-aminophenyl)azo]-1,3-dimethyl-1H-imidazolium chloride)
Chemical name:
(2-[(4-aminophenyl)azo]-1,3-dimethyl-1H-imidazolium chloride)
Class:
9
Packaging group:
III
Labels:
IATA-Passenger Aircraft: 956
IATA-Cargo Aircraft: 956
IATA-Label: 9
IATA-Sub Risk: N/A
IATA-Erg: 9L
IATA-Special Provisioning: N/A
Remarksopen allclose all
SpecialProvisionsopen allclose all

Exposure controls / personal protection

Control parameters
No Data Available

Exposure controls
Eye/face protection:
Eye glasses with side protection.

Skin protection:
Chemical protection clothing.

Hand protection:
NBR (nitrile rubber).

Respiratory protection:
Filtering Half-face mask (DIN EN 149).

Hygienic and Technical measures
Not Available

Stability and reactivity

Reactivity
Data not Available.

Chemical stability
Data not Available.

Possibility of hazardous reactions
Burning produces carbon monoxide and/or carbon dioxide.

Conditions to avoid
Data not Available.

Incompatible materials
Data not Available.

Hazardous decomposition products
Data not Available.

Disposal considerations

Waste treatment methods
Recover, if possible. Send to authorised disposal plants or for incineration under controlled conditions. In so doing, comply with the local and national regulations currently in force.