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Please be aware that this old REACH registration data factsheet is no longer maintained; it remains frozen as of 19th May 2023.

The new ECHA CHEM database has been released by ECHA, and it now contains all REACH registration data. There are more details on the transition of ECHA's published data to ECHA CHEM here.

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Reference
Endpoint:
relative self-ignition temperature (solids)
Type of information:
experimental study
Adequacy of study:
key study
Study period:
2018-06-26 to 2018-08-02
Reliability:
1 (reliable without restriction)
Rationale for reliability incl. deficiencies:
guideline study
Qualifier:
according to guideline
Guideline:
other: UN Recommendations on the TRANSPORT OF DANGEROUS GOODS: Manual of Tests and Criteria, Rev. 6 (2015)
Version / remarks:
2015
Deviations:
no
Qualifier:
according to guideline
Guideline:
other: VDI 2263 (1990), sheet 1, Grewer Oven
Version / remarks:
1990
Deviations:
no
GLP compliance:
yes (incl. QA statement)
Key result
Remarks on result:
no self-ignition observed up to the melting point

In the investigation of self-ignition in the Grewer Oven the pure test item showed an endothermic effect in the temperature range of 210 - 240 °C, which can be assigned to the melting of the test item. No further thermal effects could be observed up to the maximum test temperature of 412 °C. After the test the wire basket was empty.

Conclusions:
The pure test indicated no self-heating at atmospheric pressure up to its melting point starting at a temperature of approx. 210 °C.
According to this result of the tests on the self-ignition in the Grewer Oven the test item is classified as follows:
UN Transport Regulation: The test item is not classified as self-heating substance in class 4, division 4.2 according to the UN Transport Regulation.
GHS/CLP Regulation EC 1272/2008 Annex 1: 2.11: The test item is not classified as self-heating substance according to GHS/CLP Regulation EC 1272/2008 Annex 1: 2.11, respectively.

Description of key information

The pure test indicated no self-heating at atmospheric pressure up to its melting point starting at a temperature of approx. 210 °C.

According to this result of the tests on the self-ignition in the Grewer Oven the test item is classified as follows:

UN Transport Regulation: The test item is not classified as self-heating substance in class 4, division 4.2 according to the UN Transport Regulation.

GHS/CLP Regulation EC 1272/2008 Annex 1: 2.11: The test item is not classified as self-heating substance according to GHS/CLP Regulation EC 1272/2008 Annex 1: 2.11, respectively.

Key value for chemical safety assessment

Additional information