Registration Dossier

Data platform availability banner - registered substances factsheets

Please be aware that this old REACH registration data factsheet is no longer maintained; it remains frozen as of 19th May 2023.

The new ECHA CHEM database has been released by ECHA, and it now contains all REACH registration data. There are more details on the transition of ECHA's published data to ECHA CHEM here.

Diss Factsheets

Physical & Chemical properties

Melting point / freezing point

Currently viewing:

Administrative data

Link to relevant study record(s)

Reference
Endpoint:
melting point/freezing point
Type of information:
experimental study
Adequacy of study:
key study
Study period:
May 03, 2004
Reliability:
1 (reliable without restriction)
Rationale for reliability incl. deficiencies:
guideline study
Qualifier:
according to guideline
Guideline:
EU Method A.1 (Melting / Freezing Temperature)
Deviations:
no
Qualifier:
according to guideline
Guideline:
OECD Guideline 102 (Melting point / Melting Range)
Deviations:
no
GLP compliance:
yes (incl. QA statement)
Type of method:
thermal analysis
Key result
Atm. press.:
101.325 kPa
Decomposition:
yes
Decomp. temp.:
ca. 250 °C
Remarks on result:
other: No melting observed below decomposition temperature.

Reaction or decomposition of the test substance started in the temperature range 250°C – 251°C (523 K – 524 K).

Conclusions:
Under the study conditions, the glass transition temperature was evaluated as -42°C (231 K). Reaction or decomposition of the test substance started in the temperature range 250°C – 251°C (523 K – 524 K).
Executive summary:

A study was conducted to determine the melting point of the test substance according to OECD Guideline 102 and EU Method A.1. The test substance is a viscous liquid at room temperature. It does not crystallize upon cooling, but it forms a glassy state. On heating, the test substance transfers from the glassy state to the (supercooled) liquid state. Melting (i.e. transition from crystalline state to liquid state) is therefore not observed for this test substance. The glass transition region of the test substance was from -45°C to -33°C (228 K to 240 K). Under the study conditions, the glass transition temperature was evaluated as -42°C (231 K). Reaction or decomposition of the test substance started in the temperature range 250°C – 251°C (523 K – 524 K) (van der Baan-Treur, 2004).

Description of key information

The melting point was determined according to OECD Guideline 102 and EU Method A.1 (van der Baan-Treur, 2004).

Key value for chemical safety assessment

Melting / freezing point at 101 325 Pa:
-42 °C

Additional information

The melting point was evaluated as the glass transition temperature.