Registration Dossier

Administrative data

First-aid measures

After inhalation:
Supply fresh air.
Seek medical treatment in case of complaints.


After skin contact:
Immediately wash with water and soap and rinse thoroughly. Call a doctor immediately.

After eye contact:
Rinse opened eye for several minutes under running water. Remove contact lenses, if present and easy to do. Continue rinsing. Seek medical treatment.

After swallowing:
Do not induce vomiting. Rinse mouth. If you feel unwell, seek medical advice.

Indication of any immediate medical attention and special treatment needed:
First Aid, decontamination, treatment of symptoms.

Fire-fighting measures

Suitable extinguishing agents:
Use fire extinguishing methods suitable to surrounding conditions.
Water haze
Water spray
Foam
Fire-extinguishing powder
Carbon dioxide (CO2)

For safety reasons unsuitable extinguishing agents: Water with full jet.

Advice for firefighters:
Protective equipment: Wear self-contained respiratory protective device.

Additional information: Move undamaged containers from immediate hazard area if it can be done safely.

Accidental release measures

Personal precautions, protective equipment and emergency procedures Wear personal protection equipment.

Environmental precautions:
Dumping into the environment must be prevented.
Do not allow to penetrate the ground/soil.
In case of seepage into the ground inform responsible authorities.
Do not allow to enter sewers/ surface or ground water.
Inform respective authorities in case of seepage into water course or sewage system.

Methods and material for containment and cleaning up:
Pick up mechanically.
Ensure adequate ventilation.
Dispose of the material collected according to regulations.
Avoid dust formation.

Handling and storage

Precautions for safe handling:
Prevent formation of dust.
Ensure adequate ventilation.

Information about fire - and explosion protection: Usual measures for fire prevention:

Storage:
Requirements to be met by storerooms and receptacles:
Store only in the original container.
Keep container tightly closed in a well-ventilated place.

Information about storage in one common storage facility: Keep away from food, drink and animal feeding stuffs.

Further information about storage conditions:
Keep container tightly sealed.
Ensure that local, federal and national legislation on storage conditions are observed.

Transport information

Land transport (ADR/RID)

UN number:
UN3077
Proper shipping name and description:
3077 ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID,
N.O.S. (Phenyl 4-hydroxybenzoate)
Class:
9 Miscellaneous dangerous substances and articles.
Packaging group:
III
Labels:
9
Special Provisions:
Special marking: Symbol (fish and tree)

Inland waterway transport (ADN(R))

UN number:
UN3077
Proper shipping name and description:
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S.
(Phenyl 4-hydroxybenzoate)
Class:
9 Miscellaneous dangerous substances and articles.
Packaging group:
III
Labels:
9
Remarksopen allclose all

Marine transport (IMDG)

Packaging group:
III
Remarksopen allclose all

Air transport ICAO/IATA

UN number:
UN3077
Proper shipping name and description:
ENVIRONMENTALLY HAZAR
Class:
9 Miscellaneous dangerous substances and articles.
Packaging group:
III
Labels:
9
Remarksopen allclose all

Additional transport information

Additional transport information
Special marking (IATA): Symbol (fish and tree)

Exposure controls / personal protection

Additional information about design of technical facilities:
Technical measures and the application of adequate working methods take priority over the use of personal protection equipment.

Ingredients with limit values that require monitoring at the workplace: Not required.

General protective and hygienic measures:
Ensure that washing facilities are available at the work place.
Avoid contact with the eyes and skin.
Be sure to clean skin thoroughly after work and before breaks.
Do not eat, drink, smoke or sniff while working.

Respiratory protection:
If technical suction or ventilation measures are not possible or are insufficient, protective breathing apparatus must be worn.
The filter class must be suitable for the maximum contaminant concentration (gas/vapour/aerosol/particulates) that may arise
when handling the product. If the concentration is exceeded, a self-contained breathing apparatus must be used!

Protection of hands:
Tested protective gloves are to be worn. When handling chemical substances, chemical protective gloves must be worn with CE
label including a four digit code. Type of chemical protective gloves to choose depends on the concentration and quantity of
dangerous substances as well as on work place specifications. In the cases of special applications, it is recommended to check
the chemical resistance with the manufacturer of the gloves.
The glove material has to be impermeable and resistant to the product/ the substance/ the preparation.

Material of gloves:
The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and varies from
manufacturer to manufacturer.

Penetration time of glove material:
The exact break through time has to be found out by the manufacturer of the protective gloves and has to be observed.

Eye protection: Safety glasses.

Limitation and supervision of exposure into the environment: Dumping into the environment must be prevented.

Stability and reactivity

Reactivity The product is stable under standard conditions (temperature, pressure) of storage and handling.

Chemical stability The product is stable under standard conditions (temperature, pressure) of storage and handling.

Possibility of hazardous reactions No dangerous reactions known.

Disposal considerations

Waste treatment methods
Recommendation:
Must not be disposed together with household garbage. Do not allow product to reach sewage system.
Waste disposal according to official state regulations.
Dumping into the environment must be prevented.

Uncleaned packaging:
Recommendation:
Empty contaminated packagings thoroughly. They may be recycled after thorough and proper cleaning.
Packagings that may not be cleansed are to be disposed of in the same manner as the product.