Registration Dossier

Classification & Labelling & PBT assessment

GHS

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General Information

Implementation:
EU
Remarks:
Substances in Annex VI: CAS Numbers 68476-55-1 / 68477-35-0 / 91995-41-4 / 68477-50-9

Related composition

Related composition:
Composition 4

Classificationopen allclose all

Explosives
Reason for no classification:
data conclusive but not sufficient for classification
Flammable gases and chemically unstable gases
Reason for no classification:
data conclusive but not sufficient for classification
Aerosols
Reason for no classification:
data conclusive but not sufficient for classification
Oxidising gases
Reason for no classification:
data conclusive but not sufficient for classification
Gases under pressure
Reason for no classification:
data conclusive but not sufficient for classification
Flammable liquids
Hazard category:
Flam. Liquid 1
Hazard statement:
H224: Extremely flammable liquid and vapour.
Flammable solids
Reason for no classification:
data conclusive but not sufficient for classification
Self-reactive substances and mixtures
Reason for no classification:
data conclusive but not sufficient for classification
Pyrophoric liquids
Reason for no classification:
data conclusive but not sufficient for classification
Pyrophoric solids
Reason for no classification:
data conclusive but not sufficient for classification
Self-heating substances and mixtures
Reason for no classification:
data conclusive but not sufficient for classification
Substances and mixtures which in contact with water emit flammable gases
Reason for no classification:
data conclusive but not sufficient for classification
Oxidising liquids
Reason for no classification:
data conclusive but not sufficient for classification
Oxidising solids
Reason for no classification:
data conclusive but not sufficient for classification
Organic peroxides
Reason for no classification:
data conclusive but not sufficient for classification
Corrosive to metals
Reason for no classification:
data conclusive but not sufficient for classification
Desensitized explosives
Reason for no classification:
data lacking
Acute toxicity - oral
Hazard category:
Acute Tox. 4
Hazard statement:
H302: Harmful if swallowed.
Acute toxicity - dermal
Hazard category:
Acute Tox. 4
Hazard statement:
H312: Harmful in contact with skin.
Acute toxicity - inhalation
Reason for no classification:
data conclusive but not sufficient for classification
Skin corrosion / irritation
Hazard category:
Skin Irrit. 2
Hazard statement:
H315: Causes skin irritation.
Serious eye damage / eye irritation
Hazard category:
Eye Irrit. 2
Hazard statement:
H319: Causes serious eye irritation.
Respiratory sensitisation
Reason for no classification:
data conclusive but not sufficient for classification
Skin sensitisation
Reason for no classification:
data conclusive but not sufficient for classification
Aspiration hazard
Hazard category:
Asp. Tox. 1
Hazard statement:
H304: May be fatal if swallowed and enters airways.
Reproductive toxicity
Hazard category:
Repr. 2
Hazard statement:
H361: Suspected of damaging fertility or the unborn child <state specific effect if known> <state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard>.
Specific effect:
In rodents, foetotoxic effects such as reduced pup body weight, increased pup mortality, and decreased pup survival observed at oral doses equal to or below those that produced significant maternal toxicity in adult females.
Route of exposure:
Oral
Effects on or via lactation
Reason for no classification:
data conclusive but not sufficient for classification
Germ cell mutagenicity
Hazard category:
Muta. 1B
Hazard statement:
H340: May cause genetic defects <state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard>.
Carcinogenicity
Hazard category:
Carc. 1B
Hazard statement:
H350: May cause cancer <state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard>.
1. Specific target organ toxicity - single
Hazard category:
STOT Single Exp. 3
Hazard statement:
H336: May cause drowsiness or dizziness.
Affected organs:
central nervous system
Route of exposure:
Inhalation
2. Specific target organ toxicity - single
Hazard category:
STOT Single Exp. 3
Hazard statement:
H335: May cause respiratory irritation.
Affected organs:
respiratory tract
Route of exposure:
Inhalation
1. Specific target organ toxicity - repeated
Hazard category:
STOT Rep. Exp. 2
Hazard statement:
H373: May cause damage to organs <or state all organs affected, if known> through prolonged or repeated exposure <state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard>.
Affected organs:
Nervous system
Route of exposure:
Inhalation
Hazardous to the aquatic environment (acute / short-term)
Hazard category:
Aquatic Acute 1
Hazard statement:
H400: Very toxic to aquatic life.
Hazardous to the aquatic environment (long-term)
Hazard category:
Aquatic Chronic 2
Hazard statement:
H411: Toxic to aquatic life with long lasting effects.
M-Factor acute:
1
Hazardous to the ozone layer
Reason for no classification:
data lacking

Labelling

Signal word:
Danger

Hazard pictogram

GHS02: flame
GHS08: health hazard
GHS07: exclamation mark
GHS09: environment

Hazard statements

H224: Extremely flammable liquid and vapour.
H350: May cause cancer <state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard>.
H340: May cause genetic defects <state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard>.
H361: Suspected of damaging fertility or the unborn child <state specific effect if known> <state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard>.
H304: May be fatal if swallowed and enters airways.
H336: May cause drowsiness or dizziness.
H335: May cause respiratory irritation.
H319: Causes serious eye irritation.
H315: Causes skin irritation.
H312: Harmful in contact with skin.
H302: Harmful if swallowed.
H400: Very toxic to aquatic life.
H411: Toxic to aquatic life with long lasting effects.

Precautionary statements

P202: Do not handle until all safety precautions have been read and understood.
P210: Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
P243: Take actions to pevent static discharges.
P303+P361+P353: IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water [or shower].
P301+P310: IF SWALLOWED: Immediately call a POISON CENTER/doctor/…
P331: Do NOT induce vomiting.
P273: Avoid release to the environment.
P391: Collect spillage.

Additional labelling requirements

EUH066: Repeated exposure may cause skin dryness or cracking.

Notes