Registration Dossier

Guidance on Safe Use

Guidance on Safe Use

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Administrative data

First-aid measures

General advice:
Remove contaminated clothing.

If inhaled:
Keep patient calm, remove to fresh air, seek medical attention.

On skin contact:
Wash thoroughly with soap and water.

On contact with eyes:
Wash affected eyes for at least 15 minutes under running water with eyelids held open. If irritation develops, seek medical attention.

On ingestion:
Rinse mouth and then drink plenty of water. Seek medical attention.

Fire-fighting measures

Suitable extinguishing media:
water fog, foam, dry extinguishing media

Special protective equipment:
Wear self-contained breathing apparatus and chemical-protective clothing.

Further information:
Collect contaminated extinguishing water separately, do not allow to reach sewage or effluent systems.

Accidental release measures

Personal precautions:
Use breathing apparatus if exposed to vapours/dust/aerosol.

Environmental precautions:
Do not discharge into the subsoil/soil. Do not discharge into waterways or sewer systems without proper authorization.

Methods for cleaning up or taking up:
For small amounts: Sweep/shovel up. Dispose of absorbed material in accordance with regulations.
For large amounts: Sweep/shovel up. Dispose of absorbed material in accordance with regulations

Handling and storage

Handling
Protection against fire and explosion:
Take precautionary measures against static discharges. Sources of ignition should be kept well clear.

Storage
Segregate from acids and acid forming substances.

Suitable materials for containers: Stainless steel 1.4301 (V2)
Further information on storage conditions: Store containers in a cool, well-ventilated, fire resistant location.

Transport information

Land transport (ADR/RID)

UN number:
UN 3176
Proper shipping name and description:
FLAMMABLE SOLID, ORGANIC, MOLTEN, N.O.S. (contains 1,3,5-TRIOXANE (TRIOXYMETHYLENE))
Chemical name:
1,3,5-Trioxane
Language:
English
Class:
4.1
Packaging group:
II
Labels:
4.1
SpecialProvisionsopen allclose all

Inland waterway transport (ADN(R))

UN number:
UN 3176
Proper shipping name and description:
FLAMMABLE SOLID, ORGANIC, MOLTEN, N.O.S. (contains 1,3,5-TRIOXANE (TRIOXYMETHYLENE))
Chemical name:
1,3,5-Trioxane
Language:
English
Class:
4.1
Packaging group:
II
Labels:
4.1
Remarksopen allclose all

Marine transport (IMDG)

UN number:
UN 3176
Proper shipping name and description:
FLAMMABLE SOLID, ORGANIC, MOLTEN, N.O.S. (contains 1,3,5-TRIOXANE (TRIOXYMETHYLENE))
Chemical name:
1,3,5-Troxane
Class:
4.1
Packaging group:
II
Labels:
4.1
Remarksopen allclose all

Air transport ICAO/IATA

UN number:
UN 3176
Proper shipping name and description:
FLAMMABLE SOLID, ORGANIC, MOLTEN, N.O.S. (contains 1,3,5-TRIOXANE (TRIOXYMETHYLENE))
Chemical name:
1,3,5-Trioxane
Class:
4.1
Packaging group:
II
Labels:
4.1
Remarksopen allclose all
SpecialProvisionsopen allclose all

Exposure controls / personal protection

Occupational Exposure Limit
CT-Freetext: Germany

Occupational Exposure Limit
RE-Freetext: BASF AG, Safety data sheet 1,3,5-TRIOXAN SCHUPPEN., 24.05.2005

Occupational Exposure Limit
SO-Freetext: TRGS 900 (Germany), 08/2004

Occupational Exposure Limit
Type of limit MAK (DE) other: no MAK-value established

Stability and reactivity

Disposal considerations