Registration Dossier

Administrative data

First-aid measures

INHALATION
Move the exposed person to fresh air at once. Get medical attention.

INGESTION
Wash out mouth with water, provided person is conscious. Get medical attention.

SKIN CONTACT
Remove contaminated clothing and wash skin with soap and plenty of running water. Get medical attention.

EYE CONTACT
Rinse immediately eye with plenty of low pressure water for at least 15 minutes.
Remove any contact lenses. Get medical attention.

Fire-fighting measures

EXTINGUISHING MEDIA
Flashpoint 325 °C
To extinguish fire use water spray, dry powder, carbon dioxide, or foam.

SPECIAL FIRE FIGHTING PROCEDURES
Prevent run-off water from entering the sewer system.

UNUSUAL FIRE & EXPLOSION HAZARDS
Dust may form explosive mixture with air.

SPECIFIC HAZARDS
By fire toxic gases may be formed (Cox, NOx).

PROTECTIVE MEASURES IN FIRE
Self contained breathing apparatus and full protective clothing.

Accidental release measures

PERSONAL PRECAUTIONS
See section on exposure controls/personal protection

ENVIRONMENTAL PRECAUTIONS
Take precautionary measures against discharges into the environment.

SPILL CLEAN UP METHODS
Collect spilled material without creating dust, then place into a suitable closed container for disposal as chemical waste.

Handling and storage

USAGE PRECAUTIONS
Concentrated dust may present an explosion hazard.
Avoid contact with eyes or skin.
Wash thoroughly after handling and before eating, drinking or smoking.

STORAGE PRECAUTIONS
To protect product quality, store in sealed container in a cool place and out of direct sunlight.
Protect against static charge and keep away from source of ignition. Prevent dust formation.

Transport information

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Marine transport (IMDG)

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Exposure controls / personal protection

EXPOSURE LIMITS
None listed.

USE LIMITS
There are no data available for repeated dose toxicity and for developmental toxicity. Pregnant women should not handle this substance.
Only to be handled in an industrial environment as powder coating additive (as such or in a mixture).

PNECs:
aqua-freshwater: 0.008 mg/L
aqua-marine water: 0.0008 mg/L
aqua-intermittent: 0.08 mg/L
sewage treatment plant: 14 mg/L
sediment-freshwater: 0.012 mg/kg dw
sediment-marine water: 0.0012 mg/kg dw
soil: 10 mg/kg dw

DNELs:
The main derived long-term DNELs for systemic effects are:
Workers General population
Oral not relevant 0.80 mg/kg bw/day
Dermal 1.60 mg/kg bw/day 0.80 mg/kg bw/day
Inhalation 1.41 mg/m3/day 0.35 mg/m3/day

The ECETOC TRA Worker Tool 2010 (V2.0) model for this substance shows for indoor industrial activities taking more than 4 hours/day, with local exhaust ventilation present (and running), provided workers wear masks with at least 90% respiratory protection and gloves with at least 90% dermal protection, the following occupational exposures:

Inhalation dermal RCR RCR RCR
mg/m3 mg/kg/day inhalation dermal total
PROC5 0.005 0.00686 0.00355 0.00429 0.00748
Mixing or blending in batch processes (multistage and/or significant contact)
PROC7 0.005 0.214 0.00355 0.134 0.13755
Industrial spraying

The same ECETOC TRAM tool predicts the following for two relevant spERCs (CEPE7 and CEPE18) at a level of 1 t/y (fraction of tonnage to region = 1):
Total daily intake man via the environment regional 3.52E-012 (mg/kgbw/d), with RCR = 1.98E-06
CEPE7 = Formulation of Powder Coatings and Inks - Solids
CEPE18 = Powder spraying

PROTECTIVE EQUIPMENT
Protective gloves, safety goggles, breathing apparatus and protective clothing. Avoid any source of ignition and/or static charge.

RESPIRATORY EQUIPMENT
Breathing apparatus: Wear positive pressure self-contained breathing apparatus classified under EN137 : 2006 with at least 90% respiratory protection..

HAND PROTECTION
Protective gloves: Use chemical resistant gloves classified under Standard EN374, class 5.

EYE PROTECTION
Wear approved safety goggles.

HYGIENE MEASURES
Wash at the end of each work shift and before eating, drinking, smoking or using the toilet.

SKIN PROTECTION
Wear protective clothing.

Stability and reactivity

STABILITY
Stable under normal temperature conditions and recommended use.

MATERIALS TO AVOID
Strong oxidising agents

HAZARDOUS DECOMPOSITION PRODUCTS
By fire toxic gases (COx) may be formed

Disposal considerations

GENERAL INFORMATION
Place into a suitable closed container for disposal as chemical waste.

DISPOSAL METHODS
Dispose of in accordance with local and national regulations.