Registration Dossier

Diss Factsheets

Administrative data

First-aid measures

4.1 Eye contact:

      - Consult a doctor/medical service if irritation persists

      - Rinse immediately with plenty of water

      - Do not apply neutralizing agentss

4.2 Skin contact:

      - Consult a doctor/medical service if irritation persists

      - Soap may be used

      - Wash immediately with lots of water

      - Remove closing before washing

4.3 After inhalation:

      - Immediately consult a doctor/medical service

      - Remove the victim into fresh air

      - Unconscious: maintain adequate airway and respiration

4.4 After ingestion:

      - Immediately consult a doctor/medical service

      - Never give water to an unconscious person

      - Victim is fully conscious: immediately induce vomiting

      - give nothing or little to drink

Fire-fighting measures

5.1 Suitable extinguishing media:

      - Water spray

      - Polyvalent foam

      - ABC powder

      - Carbon dioxide

5.2 Unsuitable extinguishing media:

      - No data available

5.3 Special exposure hazards*

      - Combustible

      - Its dust is explosive with air

      - On burning: release of toxic and corrosive gases/vapours (nitrous vapours, carbon monooxide - carbon dioxide)

5.4 Instructions:

      - Dilute toxic gases with water spray

      - Take account of toxic firefighting water

      - Use firefighting water moderately and contain it

5.5 Special protective equipment for firefighters:

      - Heat/fire exposure: compressed air/oxigen apparatus

      - Dust cloud production: compressed air/oxygen apparatus

Accidental release measures

6.1 Personal protection/precautions:

      See heading 8.2/8.3/13

6.2 Environmental precautions:

      - Prevent soil and water pollution

      - Prevent spreading in sewers

      - Contain released substance, pump over in suitable containers

      - Plug the leak, cut off the suply

      - Dam up the solid spill

      - Knock down/dilute dust cloud with water spray

6.3 Methods for cleaning up:

      - Stop dust cloud by covering with sand/earth

      - Carefully collect the spill/leftovers

      - Scope solid spill into closing containers

      - Powderd: do not use compressed air for pumping over spills

      - Clean contaminated surfaces with an excess of water

      - Take collected spill to manufacturer/competent authority

      - Wash clothing and equipment after handling

Handling and storage

7.1 Handling:

      - Observe very strict hygiene - avoide contact

      - Avoid raising dust

      - Take precautions against electrostatic charges

      - Do not discharge the waste into the drain

      - Remove contaminated clothing immediately

7.2 Storage

      - Keep container tightly closed

      - Store in a dry area

      - Store in a dark area

      - Meet the legal requirements

      - keep away from: heat sources, ignition sources, oxidizing agents, water

     Storage temperature: < 40 degreeC

     Quantity limits: Not determined

     Storage life: Not determined

     Materials for packaging:

      - suitable: paper

      - to avoide: no data available

7.3 Specific uses:

      - See information supplied by the manufacturer

Transport information

Land transport (UN RTDG/ADR/RID)

UN number:
2811
Shipping information
Proper shipping name and description:
Toxic solid, organic, n.o.s.
Chemical name:
N-phenylmaleimide
Language:
English
Labels:
a diamond- shaped figure with 'UN 2811'
Special provisions / remarks
Special provisions:
'LQ'
Remarks:
in the case of different goods with different identification numbers within a single package

Inland waterway transport (UN RTDG/ADN(R))

UN number:
2811
Shipping information
Proper shipping name and description:
Toxic solid, organic, n.o.s.
Chemical name:
N-phenylmaleimide
Language:
English
Labels:
a diamond- shaped figure with 'UN 2811'
Remarksopen allclose all

Marine transport (UN RTDG/IMDG)

UN number:
2811
Shipping information
Proper shipping name and description:
Toxic solid, organic, n.o.s.
Chemical name:
N-phenylmaleimide
Labels:
a diamond- shaped figure with 'UN 2811'
Marine pollutant
Special provisions / remarks
Remarks:
96h-LC50 <1 mg/L, >0.1 mg/L

Air transport (UN RTDG/ICAO/IATA)

UN number:
2811
Shipping information
Proper shipping name and description:
Toxic solid, organic, n.o.s.
Chemical name:
N-phenylmaleimide
Labels:
a diamond- shaped figure with 'UN 2811'
Remarksopen allclose all

Additional transport information

Additional information
Special provisions / remarks / other:
none

Exposure controls / personal protection

8.1 Exposure limit value

      - Other route: <0.1 mg/m3 (Japanese ABS resin manufacturers association)

8.2 Exposure controls:

8.2.1 Occupational exposure controls:

         - Work under local exhaust/ventilation

8.2.2 Environmental exposure controls:

        See heading 13

8.3 Personal protection:

      - Air line hood or mask, gloves, full chemical suit, boots are recommended

8.3.1 respitarory protection:

         - Dust production: dust mask with filter type P3

8.3.2 hand protection:

         - Gloves

            suitable materials: Rubber

         - Breakthrough time: Not determined

8.3.3 eye protection:

         - Face shield

         - In case of dust production: protective goggles

8.3.4 skin protection:

         - Protective clothing

         - Incase of dust production: head/neck protection

            Suitable materials: Rubber

Stability and reactivity

10.1 Conditios to avoid/reactivity:

        - Unstable on exposure to moisture

        - Discolours on exposure to light

10.2 Materials to avoide:

        - Keep away from: heat sources, ignition sources, oxidizing agents, water

10.3 Hazardous decomposition products:

        - Hydrolyzes on exposure to water (moisture)

        - On burning: release of toxic and corrosive gases/vapours (nitrous vapours, carbon monooxide - carbon dioxide)

Disposal considerations

13.1 Provisions relating to waste:

        - Waste material code (Flanders) : 001

        - Hazardous waste (91/689/EEC)

13.2 Disposal methods:

        - Remove to an authorized incinerator equipped with an afterburner and a flue gas scrubber

        - Do not dischrge into drains or the environment

13.3 Packaging/Container:

        - Waste material code packaging (91/689/EEC, Council Decision 2001/118/EC, O.J. L47 of 16/2/2001): 15 01 10* (packaging residues of or contaminated by dangerous substances)