Registration Dossier

Administrative data

First-aid measures

Emergency measure - Inhalation: Bring affected person in fresh air, consult physician.
Emergency measure - Eyes: Immediately flush eyes with plenty of water for 10 minutes and get medical attention.
Emergency measure - Skin: Immediately wash with water and soap and get medical attention.
Emergency measure - Ingestion: Rinse mouth with water and give plenty of water. Get medical attention immediately.

Fire-fighting measures

Extinguishing media: water fog, foam, dry chemical, CO2
Hazardous combustion products: CO, CO2, nitrogen oxides, HCN
Fire-Fighting equipment: Respiratory and eye protection required. Full protective equipment and a self-contained respirator with full face protection should be used.

Accidental release measures

Personal precautions: Evacuate immediate area. Remove all sources of ignition. Wear eye protection, inpermeable gloves and respirator.
Allow only skilled person with eye and breath protection.
Cover the spilt material with non-flammable absorbing
material. If possible use an industrial vaccuum cleaner.
Collect and keep in closed well-labelled containers.

Handling and storage

Handling: Avoid contact with skin and eyes. In case of emergency use
gasmask with full face protection.

Wear chemically resistant protection gloves, protective
clothes and goggles. Store contaminated clothes in a
container until cleaning.

Working places should have good air conditioning.

Installation of isocyanate monitor.

Storage: Container should be stored under normal safe conditions.

Use unbreakable containers. Safeguard against fall-down.
Avoid residue on outside of container.

Avoid direct sunlight. Storage under N2.

Provide good ventilation.

Transport information

Land transport (ADR/RID)

UN number:
2927
Proper shipping name and description:
TOXIC LIQUID, CORROSIVE, N.O.S.
Chemical name:
2,5(or 2,6)-bis(isocyanatomethyl)-2,5(or 2,6)-dimethylbicyclo[2.2.1]heptane
Language:
English
Class:
6.1
Classification code:
T1
Packaging group:
II
Labels:
T+ (very toxic)
SpecialProvisionsopen allclose all

Inland waterway transport (ADN(R))

UN number:
2927
Proper shipping name and description:
TOXIC LIQUID, CORROSIVE, N.O.S.
Chemical name:
2,5(or 2,6)-bis(isocyanatomethyl)-2,5(or 2,6)-dimethylbicyclo[2.2.1]heptane
Language:
English
Class:
6.1
Classification code:
T1
Packaging group:
II
Labels:
6
Remarksopen allclose all

Marine transport (IMDG)

UN number:
2927
Proper shipping name and description:
TOXIC LIQUID, CORROSIVE, N.O.S.
Chemical name:
2,5(or 2,6)-bis(isocyanatomethyl)-2,5(or 2,6)-dimethylbicyclo[2.2.1]heptane
Class:
6.1
Packaging group:
II
EmS code:
F-A, S-A
Labels:
6 (Toxic)
Remarks
SP274

Air transport ICAO/IATA

UN number:
2927
Proper shipping name and description:
TOXIC LIQUID, CORROSIVE, N.O.S.
Chemical name:
2,5(or 2,6)-bis(isocyanatomethyl)-2,5(or 2,6)-dimethylbicyclo[2.2.1]heptane
Class:
6.1
Packaging group:
II
Labels:
6 (Toxic)
Remarksopen allclose all
SpecialProvisionsopen allclose all

Exposure controls / personal protection

Engineering controls: Provide general ventilation. Use closed system or local exhaust ventilation. Provide safety shower and eye wash station near work area.

Personal protective equipment:
Respiratory protection: Chemical cartridge respirator with organic vapor cartridge(s), supplied-air purifying respirator, breathing apparatus.
Skin protection: Protective gloves, Safety helmet, protective clothing, safety boots and apron.
Eye protection: Safety glasses, goggles or face shield.

Stability and reactivity

Danger other than fire: Harmful when swallowed, absorbed by skin or inhalated.

Chemical reaction with water: Reacts with water: release of CO2 and NBDA - No dangerous reaction.

Disposal considerations

Industry - Possibility of recovery/recycling: None Industry - Possibility of destruction - other: Special waste treatment (substance as such). When causing reaction with alcohol, polyurethan is developed which can be treated like other polyurethanes. Public at large - Possibility of recovery/recycling: Substance does not enter public domain.