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Environmental fate & pathways

Additional information on environmental fate and behaviour

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Administrative data

Endpoint:
additional information on environmental fate and behaviour
Type of information:
experimental study
Adequacy of study:
supporting study
Reliability:
3 (not reliable)
Rationale for reliability incl. deficiencies:
other: No OECD guideline followed. Not GLP. Only brief description of test setup and results available.

Data source

Reference
Reference Type:
publication
Title:
Beständigkeit gegen Auslaugen von p-phenylenediamin-Derivaten.
Author:
Spirk, E.; Stefanik, P.; Orlik I.; Collonge, J.
Year:
1981
Bibliographic source:
Gummi, Asbest, Kunststoffe 1981, 34 (11), p. 734-735.

Materials and methods

Test guideline
Qualifier:
no guideline followed
Principles of method if other than guideline:
T-shaped rubber samples of defined composition are immersed in distilled water of pH 4 for 15 days. Water samples were analyzed for p-phenylenediamine derivatives by UV-spectrophotometric measurements using a calibration curve.
GLP compliance:
no

Test material

Constituent 1
Chemical structure
Reference substance name:
1,4-Benzenediamine, N,N'-mixed Ph and tolyl derivs.
EC Number:
273-227-8
EC Name:
1,4-Benzenediamine, N,N'-mixed Ph and tolyl derivs.
Cas Number:
68953-84-4
Molecular formula:
C18-20H16-20N2
IUPAC Name:
Reaction mass of N-phenyl,N'-o-tolyl-phenylene diamine, N,N'-diphenyl-p-phenylene diamine and N,N'-di-o-tolyl-phenylene diamine

Results and discussion

Any other information on results incl. tables

After 15 days of contact between the rubber samples and the water, approximately 1,6% of the 1,4-benzenediamine, N,N'-mixed Ph and tolyl derivs. leached from the rubber into the water phase. Two other tested p-phenylenediamines (N-isopropyl-N'-phenyl-p-phenylenediamine and N-(1,3-dimethylbutyl)-N'-phenyl-p-phenylenediamine) respectively showed 86.2 and 44.7% of antioxidant leaching from the rubber samples.

Applicant's summary and conclusion