Registration Dossier
Registration Dossier
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EC number: 242-440-8 | CAS number: 18599-22-9
Guidance on Safe Use
Guidance on Safe Use
Administrative data
First-aid measures
4.1 Description of first aid measures
General advice : In the case of accident or if you feel unwell, seek medical advice immediately. When symptoms persist or in all cases of doubt seek medical advice.
Protection of first-aiders : First Aid responders should pay attention to self-protection, and use the recommended personal protective equipment when the potential for exposure exists (see section 8).
If inhaled : If inhaled, remove to fresh air. Get medical attention if symptoms occur.
In case of skin contact : In case of contact, immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Get medical attention. Wash clothing before reuse. Thoroughly clean shoes before reuse.
In case of eye contact : Flush eyes with water as a precaution. Get medical attention if irritation develops and persists.
If swallowed : If swallowed, DO NOT induce vomiting. Get medical attention if symptoms occur. Rinse mouth thoroughly with water.
4.2 Most important symptoms and effects, both acute and delayed
Risks : Causes skin irritation. May cause drowsiness or dizziness.
4.3 Indication of any immediate medical attention and special treatment needed
Treatment : Treat symptomatically and supportively.
General advice : In the case of accident or if you feel unwell, seek medical advice immediately. When symptoms persist or in all cases of doubt seek medical advice.
Protection of first-aiders : First Aid responders should pay attention to self-protection, and use the recommended personal protective equipment when the potential for exposure exists (see section 8).
If inhaled : If inhaled, remove to fresh air. Get medical attention if symptoms occur.
In case of skin contact : In case of contact, immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Get medical attention. Wash clothing before reuse. Thoroughly clean shoes before reuse.
In case of eye contact : Flush eyes with water as a precaution. Get medical attention if irritation develops and persists.
If swallowed : If swallowed, DO NOT induce vomiting. Get medical attention if symptoms occur. Rinse mouth thoroughly with water.
4.2 Most important symptoms and effects, both acute and delayed
Risks : Causes skin irritation. May cause drowsiness or dizziness.
4.3 Indication of any immediate medical attention and special treatment needed
Treatment : Treat symptomatically and supportively.
Fire-fighting measures
5.1 Extinguishing media
Suitable extinguishing media : Water spray, alcohol-resistant foam, carbon dioxide (CO2), dry chemical
Unsuitable extinguishing media : None known.
5.2 Special hazards arising from the substance or mixture
Specific hazards during fire-fighting : Exposure to combustion products may be a hazard to health.
Hazardous combustion products : Hydrogen fluoride, carbonyl fluoride, potentially toxic fluorinated compounds, aerosolized particulates, Carbon oxides
5.3 Advice for firefighters
Special protective equipment for firefighters : In the event of fire, wear self-contained breathing apparatus. Use personal protective equipment.
Specific extinguishing methods : Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Use water spray to cool unopened containers. Remove undamaged containers from fire area if it is safe to do so. Evacuate area.
Suitable extinguishing media : Water spray, alcohol-resistant foam, carbon dioxide (CO2), dry chemical
Unsuitable extinguishing media : None known.
5.2 Special hazards arising from the substance or mixture
Specific hazards during fire-fighting : Exposure to combustion products may be a hazard to health.
Hazardous combustion products : Hydrogen fluoride, carbonyl fluoride, potentially toxic fluorinated compounds, aerosolized particulates, Carbon oxides
5.3 Advice for firefighters
Special protective equipment for firefighters : In the event of fire, wear self-contained breathing apparatus. Use personal protective equipment.
Specific extinguishing methods : Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Use water spray to cool unopened containers. Remove undamaged containers from fire area if it is safe to do so. Evacuate area.
Accidental release measures
6.1 Personal precautions, protective equipment and emergency procedures
Personal precautions : Use personal protective equipment. Follow safe handling advice (see section 7) and personal protective equipment recommendations (see section 8).
6.2 Environmental precautions
Environmental precautions : Avoid release to the environment. Prevent further leakage or spillage if safe to do so. Prevent spreading over a wide area (e.g. by containment or oil barriers). Retain and dispose of contaminated wash water. Local authorities should be advised if significant spillages cannot be contained.
6.3 Methods and material for containment and cleaning up
Methods for cleaning up : Soak up with inert absorbent material. For large spills, provide dyking or other appropriate containment to keep material from spreading. If dyked material can be pumped, store recovered material in appropriate container. Clean up remaining materials from spill with suitable absorbent. Local or national regulations may apply to releases and disposal of this material, as well as those materials and items employed in the cleanup of releases. You will need to determine which regulations are applicable.
Sections 13 and 15 of this SDS provide information regarding certain local or national requirements.
Personal precautions : Use personal protective equipment. Follow safe handling advice (see section 7) and personal protective equipment recommendations (see section 8).
6.2 Environmental precautions
Environmental precautions : Avoid release to the environment. Prevent further leakage or spillage if safe to do so. Prevent spreading over a wide area (e.g. by containment or oil barriers). Retain and dispose of contaminated wash water. Local authorities should be advised if significant spillages cannot be contained.
6.3 Methods and material for containment and cleaning up
Methods for cleaning up : Soak up with inert absorbent material. For large spills, provide dyking or other appropriate containment to keep material from spreading. If dyked material can be pumped, store recovered material in appropriate container. Clean up remaining materials from spill with suitable absorbent. Local or national regulations may apply to releases and disposal of this material, as well as those materials and items employed in the cleanup of releases. You will need to determine which regulations are applicable.
Sections 13 and 15 of this SDS provide information regarding certain local or national requirements.
Handling and storage
7.1 Precautions for safe handling
Technical measures : See Engineering measures under EXPOSURE CONTROLS/PERSONAL PROTECTION section.
Local/Total ventilation : If sufficient ventilation is unavailable, use with local exhaust ventilation.
Advice on safe handling : Do not get on skin or clothing. Avoid breathing mist or vapours. Do not swallow. Avoid contact with eyes. Wash skin thoroughly after handling. Handle in accordance with good industrial hygiene and safety practice, based on the results of the workplace exposure assessment. Take care to prevent spills, waste and minimize release to the environment.
Hygiene measures : If exposure to chemical is likely during typical use, provide eye flushing systems and safety showers close to the working place. When using do not eat, drink or smoke. Wash contaminated clothing before re-use.
7.2 Conditions for safe storage, including any incompatibilities
Requirements for storage areas and containers : Keep in properly labelled containers. Store locked up. Keep in a cool, well-ventilated place. Store in accordance with the particular national regulations.
Advice on common storage : Do not store with the following product types: Strong oxidizing agents
Technical measures : See Engineering measures under EXPOSURE CONTROLS/PERSONAL PROTECTION section.
Local/Total ventilation : If sufficient ventilation is unavailable, use with local exhaust ventilation.
Advice on safe handling : Do not get on skin or clothing. Avoid breathing mist or vapours. Do not swallow. Avoid contact with eyes. Wash skin thoroughly after handling. Handle in accordance with good industrial hygiene and safety practice, based on the results of the workplace exposure assessment. Take care to prevent spills, waste and minimize release to the environment.
Hygiene measures : If exposure to chemical is likely during typical use, provide eye flushing systems and safety showers close to the working place. When using do not eat, drink or smoke. Wash contaminated clothing before re-use.
7.2 Conditions for safe storage, including any incompatibilities
Requirements for storage areas and containers : Keep in properly labelled containers. Store locked up. Keep in a cool, well-ventilated place. Store in accordance with the particular national regulations.
Advice on common storage : Do not store with the following product types: Strong oxidizing agents
Transport information
Land transport (UN RTDG/ADR/RID)
- UN number:
- Not regulated as a dangerous good
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Inland waterway transport (UN RTDG/ADN(R))
- UN number:
- Not regulated as a dangerous good
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Marine transport (UN RTDG/IMDG)
- UN number:
- Not regulated as a dangerous good
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Air transport (UN RTDG/ICAO/IATA)
- UN number:
- Not regulated as a dangerous good
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Exposure controls / personal protection
Engineering measures
Processing may form hazardous compounds (see section 10). Minimize workplace exposure concentrations. If sufficient ventilation is unavailable, use with local exhaust ventilation.
Personal protective equipment
Eye protection : Wear the following personal protective equipment: Safety glasses. Equipment should conform to I.S. EN 166.
Hand protection
Material : Neoprene
Remarks : Choose gloves to protect hands against chemicals depending on the concentration and quantity of the hazardous substance and specific to place of work. For special applications,
we recommend clarifying the resistance to chemicals of the aforementioned protective gloves with the glove manufacturer. Wash hands before breaks and at the end of workday. Breakthrough time is not determined for the product. Change gloves often!
Skin and body protection : Select appropriate protective clothing based on chemical resistance data and an assessment of the local exposure potential. Skin contact must be avoided by using impervious protective clothing (gloves, aprons, boots, etc).
Respiratory protection : If adequate local exhaust ventilation is not available or exposure assessment demonstrates exposures outside the recommended guidelines, use respiratory protection. Equipment should conform to I.S. EN 137.
Filter type : Self-contained breathing apparatus
Processing may form hazardous compounds (see section 10). Minimize workplace exposure concentrations. If sufficient ventilation is unavailable, use with local exhaust ventilation.
Personal protective equipment
Eye protection : Wear the following personal protective equipment: Safety glasses. Equipment should conform to I.S. EN 166.
Hand protection
Material : Neoprene
Remarks : Choose gloves to protect hands against chemicals depending on the concentration and quantity of the hazardous substance and specific to place of work. For special applications,
we recommend clarifying the resistance to chemicals of the aforementioned protective gloves with the glove manufacturer. Wash hands before breaks and at the end of workday. Breakthrough time is not determined for the product. Change gloves often!
Skin and body protection : Select appropriate protective clothing based on chemical resistance data and an assessment of the local exposure potential. Skin contact must be avoided by using impervious protective clothing (gloves, aprons, boots, etc).
Respiratory protection : If adequate local exhaust ventilation is not available or exposure assessment demonstrates exposures outside the recommended guidelines, use respiratory protection. Equipment should conform to I.S. EN 137.
Filter type : Self-contained breathing apparatus
Stability and reactivity
10.1 Reactivity : Not classified as a reactivity hazard.
10.2 Chemical stability : Stable under normal conditions.
10.3 Possibility of hazardous reactions
Hazardous reactions : Can react with strong oxidizing agents. Hazardous decomposition products will be formed at elevated temperatures.
10.4 Conditions to avoid
Conditions to avoid : None known.
10.5 Incompatible materials
Materials to avoid : Oxidizing agents
10.6 Hazardous decomposition products
Thermal decomposition : Hydrofluoric acid, Carbonyl difluoride, Carbon dioxide, Carbon monoxide
10.2 Chemical stability : Stable under normal conditions.
10.3 Possibility of hazardous reactions
Hazardous reactions : Can react with strong oxidizing agents. Hazardous decomposition products will be formed at elevated temperatures.
10.4 Conditions to avoid
Conditions to avoid : None known.
10.5 Incompatible materials
Materials to avoid : Oxidizing agents
10.6 Hazardous decomposition products
Thermal decomposition : Hydrofluoric acid, Carbonyl difluoride, Carbon dioxide, Carbon monoxide
Disposal considerations
13.1 Waste treatment methods
Product : Dispose of in accordance with local regulations. According to the European Waste Catalogue, Waste Codes are not product specific, but application specific. Waste codes should be assigned by the user, preferably in discussion with the waste disposal authorities.
Contaminated packaging : Empty containers should be taken to an approved waste handling site for recycling or disposal. If not otherwise specified: Dispose of as unused product.
Product : Dispose of in accordance with local regulations. According to the European Waste Catalogue, Waste Codes are not product specific, but application specific. Waste codes should be assigned by the user, preferably in discussion with the waste disposal authorities.
Contaminated packaging : Empty containers should be taken to an approved waste handling site for recycling or disposal. If not otherwise specified: Dispose of as unused product.
Information on Registered Substances comes from registration dossiers which have been assigned a registration number. The assignment of a registration number does however not guarantee that the information in the dossier is correct or that the dossier is compliant with Regulation (EC) No 1907/2006 (the REACH Regulation). This information has not been reviewed or verified by the Agency or any other authority. The content is subject to change without prior notice.
Reproduction or further distribution of this information may be subject to copyright protection. Use of the information without obtaining the permission from the owner(s) of the respective information might violate the rights of the owner.
