Registration Dossier

Guidance on Safe Use

Guidance on Safe Use

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Administrative data

First-aid measures

Description of first aid measures:
Pay attention to self-protection.
Remove victims from hazardous area.
Immediately remove soiled or soaked clothing and remove it to a safe distance.
Keep victim warm, in a stabilized position and covered. Do not leave victims unattended.
If the casualty is unconscious: Place the victim in the recovery position.

Potential for exposure by inhalation if aerosols or mists are generated.
Move victims into fresh air.
With labored breathing: Provide with oxygen.
Consult a doctor if the casualty is not breathing: Perform mouth-to-mouth resuscitation, notify emergency physician immediately.

Skin contact:
Wash off affected area immediately with plenty of water.
Continue decontamination with polyethylene glycol 400 after initial rinsing with water and then wash with water and soap.
If symptoms persist, consult a physician for treatment.

Eye contact:
With eye held open, thoroughly rinse immediately with plenty of water for at least 10 minutes.
Consult an ophthalmologist immediately if the symptoms persist.

Rinse out mouth.
Immediately give large quantities of water to drink.
Consult a physician immediately.

Most important symptoms and effects, both acute and delayed:

daze, headache, dizziness, somnolence (drowsiness), nausea.
May cause lung damage if swallowed.
Health injuries may be delayed.

Harmful in contact with skin and if swallowed.Vapours may cause drowsiness and dizziness.

Indication of any immediate medical attention and special treatment needed:
After accidental absorption in the body, the pathology and clinical findings are dependent on the kinetics of the noxious substance (quantity of absorbed substance, the absorption time, and the effectiveness of early elimination measures (first aid)/ excretion - metabolism).
Continue with first aid measures.
Depending on the pathology and clinical findings, patient monitoring and symptomatic treatment are necessary.

Fire-fighting measures

Suitable extinguishing media:
Water, mist, dry powder, foam

Unsuitable extinguishing media:
Do not use a solid water stream as it may scatter and spread fire.

Special hazards arising from the substance or mixture:
Danger of decomposition under influence of heat.
Hazard-determining flue gases might develop in case of fire:
Hydro-cyanic acid, Carbon monoxide.
Risk determining decomposition products: Allylamine.

Special protective equipment for fire-fighters:
In the event of fire, wear self-contained breathing apparatus.
Full protective suit.

Advice for firefighters:
In case of fire, remove the endangered containers and bring to a safe place, if this can be done safely.
In case of fire cool containers or take them to a safe place.
Contaminated extinguishing water must be treated at a suitable disposal plant in accordance with waste management laws.
Take precautionary measures against static discharges.
Ensure there are sufficient retaining facilities for water used to extinguish fire.
Fire residues should be disposed of in accordance with the regulations.
Keep out unprotected persons.

Accidental release measures

Personal precautions, protective equipment and emergency procedures:
Keep unauthorized persons away.

Environmental precautions:
Prevent substance from entering soil, natural bodies of water and sewer systems.
If the product contaminates rivers and lakes or drains inform respective authorities.

Methods and material for containment and cleaning up:
Absorb with liquid-binding material, e. g.: diatomaceous earth sand universal binder.
Dispose of absorbed material in accordance with the regulations.
Pack and label wastes like the pure substance. Do not detach label from the delivery containers prior to disposal.

Reference to other sections:
Wear personal protective equipment; see section 8.

Handling and storage

Precautions for safe handling:
Wear personal protective equipment.
Handle in accordance with good industrial hygiene and safety practices.
Keep in a dry, cool place.
Avoid residues of the product on the containers.
If the material has to be melted we recommend a water bath with a maximum temperature of 50 °C.
Heated chambers are also permissible.

Advice on protection against fire and explosion:
Normal measures for preventive fire protection.

Dust explosion class:
Not applicable.

Store in the original receptacle, keeping this tightly sealed, under cool and dry conditions. Well ventilated.

Further information:
Protect from sunlight, warmth and heat.
In order to ensure due transportation, make certain that stacks are of the correct height, containers are securely fastened so as not to fall off, and labelled according to the regulations.
Storage capability limited; dependent on Storage conditions.

Advice on common storage:
Observe prohibition against storing together!

German storage class:
Combustible / non-combustible liquids and solids not assigned to other storage classes.

Dust explosion class
Not applicable.

Transport information

Land transport (ADR/RID)

Shippingopen allclose all
Labelling according to regulations governing hazardous goods: yes
Not dangerous according to transport regulations.

Inland waterway transport (ADN(R))

Shippingopen allclose all
Not dangerous according to transport regulations.

Marine transport (IMDG)

Labelling according to regulations governing hazardous goods: yes
Not dangerous according to transport regulations.

Air transport ICAO/IATA

Labelling according to regulations governing hazardous goods: yes
Not dangerous according to transport regulations.

Additional transport information

Additional transport information
Combination traffic :
Labelling of containers / shipping units following main product run as per sea or air transport regulations.

Exposure controls / personal protection

Control parameters:
Engineering measures:
Ensure suitable suction/aeration at the work place and with operational machinery.
Provide for installation of emergency shower and eye bath.

Personal protective equipment:
Respiratory protection:
Use suitable respiratory protection where aerosols/vapours are generated.
When handling for a short time: Respirator with brown A-type filter.
In the event of prolonged exposure during handling: Respirator with ABEK-P2 combination filter.
Note time limit for wearing respiratory protective equipment.

Hand protection:
Applies to handling for brief periods or of small amounts:
Glove material: Nitrile, for example, Dermatril P 743, Kächele-Cama Latex GmbH (KCL), Germany
Material thickness: 0.20 mm
Method: DIN EN 374
Applies to handling for longer periods or of large amounts:
Glove material: Chloroprene, for example: Camapren 720, Kächele-Cama Latex GmbH (KCL), Germany
Material thickness: 0.65 mm
Method: DIN EN 374

Eye protection:
safety glasses with side-shields conforming to EN166 or when handling larger quantities: basket-shaped glasses.

Skin and body protection:
Usual lab protective clothing or when handling larger quantities: chemical protective suit, disposable protective suit.

Hygiene measures:
Remove and wash contaminated clothing before re-use.
No eating, drinking, smoking, or snuffing tobacco at work.
Wash face and/or hands before break and end of work.
Avoid contact with skin, eyes and clothing.
Apply adequate skin protection agents before handling the product.
Cleanse and apply cream to skin after work. Preventive skin protection recommended.

Protective measures:
Handle in accordance with good industrial hygiene and safety practices.
The personal protective equipment used must meet the requirements of directive 89/686/EEC and amendments (CE certification).
It should be defined in the work place in the form of a risk analysis according to directive 89/686/EEC and amendments.
If there is the possibility of skin/eye contact, the indicated hand/eye/body protection should be used.

Stability and reactivity

Chemical Stability:
The product is chemically stable.

Possibility of hazardous reactions:
Risk of a polymerisation triggered by exothermic reaction above 70 °C.

Conditions to avoid:
Avoid temperatures in excess of 60°C for longer periods.

Incompatible materials:
Radical producers such as peroxides, azo compounds.

Disposal considerations

Disposal according to local authority regulations.
Pack and label wastes like the pure substance. Do not detach label from the delivery containers prior to disposal.

Uncleaned packaging:
Do not reuse empty containers and dispose of in accordance with the regulations issued by the appropriate local authorities.

Waste Key Number:
The waste key number must be determined as per the European Waste Types List (decision on EU Waste Types List 2000/532/EC) in cooperation with the disposal firm / producing firm / official authority.