Titanium tetrakis(dimethylammonium)

Boiling point

Link to relevant study record(s)

Reference

Reference 1

Endpoint:

boiling point

Data waiving:

study technically not feasible

Justification for data waiving:

the study does not need to be conducted because chemical change occurred during the melting point study

Justification for type of information:

Titanium tetrakic(dimethylammonium) is an organometalic compound. It can only be handled air-free. It is a flammable liquid and very unstable (see also chapter 1.2 or 5.1.2 or 13). Within seconds it reacts violently in contact with moisture or water. The decomposition products are dimethylamine and titanium oxide. Dimethylamine is a highly flammable gas. Diethylamine can be formed explosive mixtures with air. The test to determine the boiling point is technically not feasible

Reference 2

Endpoint:

boiling point

Type of information:

experimental study

Adequacy of study:

weight of evidence

Study period:

1960

Reliability:

2 (reliable with restrictions)

Rationale for reliability incl. deficiencies:

study well documented, meets generally accepted scientific principles, acceptable for assessment

Qualifier:

no guideline followed

Guideline:

other: to avoid hydrolysis, all experiments were conducted under an atmosphere of dry oxygen-free nitrogen

Principles of method if other than guideline:

The results based on the synthesis of Titanium tetrakis(dimethylammonium). To avoid hydrolysis, all experiments were conducted under an atmosphere of dry oxygen-free nitrogen

GLP compliance:

no

Type of method:

distillation method

Boiling pt.:

50 °C

Atm. press.:

0.05 mm Hg

Executive summary:

An boiling point of 50°C at 0.05 mmHg was determined by distilliation. To avoid hydrolysis, all experiments were conducted under an atmosphere of dry oxygen-free nitrogen

Description of key information

Titanium tetrakis (dimethylammonium) is an organometalic compound. It can only be handled air-free. It is a flammable liquid and very unstable (see also chapter 1.2 or 5.1.2 or 13). Within seconds it reacts violently in contact with moisture or water. The decomposition products are dimethylamine and titanium oxide. Dimethylamine is a highly flammable gas and can be formed explosive mixtures with air.  The test to determine the boiling point of Titanium tetrakic(dimethylammonium) is technically not feasible.

In experimental studies with respect to the synthesis of Titanium tetrakis(dimethylammonium), a boiling point of 50°C at 0.05 mmHg was determined by distillation.