Registration Dossier

Guidance on Safe Use

Guidance on Safe Use

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Administrative data

First-aid measures

- General information:
Immediately remove any clothing soiled by the product.
Symptoms of poisoning may even occur after several hours; therefore medical observation for at least 48 hours after the accident.
Take affected persons out into the fresh air.
Seek immediate medical advice.

- After inhalation:
In case of unconsciousness place patient stably in side position for transportation.
Provide oxygen treatment if affected person has difficulty breathing.
If not breathing, give artificial respiration, preferably mouth to mouth.

- After skin contact:
After contact with skin, wash immediately almost 15 minutes with plenty of water.
- After eye contact:
Rinse opened eye for almost 15 minutes under running water.

- After swallowing:
Call for a doctor immediately.
Rinse mouth out with water.
Never give anything by mouth to an unconscious person.
Induce vomiting immediately by giving two glasses of water and sticking finger down throat.

- Emergency equipment
Provide wash facilities for eyes and skin near work area.

Fire-fighting measures

- Suitable extinguishing agents:
Carbon dioxide, dry chemicals, foam, water spray (mist).
Use fire extinguishing methods suitable to surrounding conditions.

- For safety reasons unsuitable extinguishing agents: Water with full jet

- Special hazards caused by the substance, its products of combustion or resulting gases:
High temperatures may liberate toxic or corrosive gases. Do not breathe smoke or vapours.

- Protective equipment:
Wear self-contained respiratory protective device.
Wear fully protective suit.
- Additional information Cool endangered receptacles with water spray

Accidental release measures

- Person-related safety precautions:
Wear protective equipment. Keep unprotected persons away.
Avoid contact with skin.
Avoid contact with eyes.
- Measures for environmental protection:
Prevent from spreading (e.g. by damming-in or oil barriers).
Inform respective authorities in case of seepage into water course or sewage system.
Do not allow to enter sewers/ surface or ground water.

- Measures for cleaning/collecting:
Clean up small spills with neutralization agent such as lime, caustic, or soda ash.
Large spills may be taken up with pump or vacuum and finished off with neutralization agent.
May require excavation of contaminated soil. Shovel up residues and place in a labelled sealable container for subsequent safe disposal.
Put leaking container into a labelled drum or overdrum.
Residue may be washed down with water.

Handling and storage

- Handling:
- Information for safe handling:
Ensure good ventilation/exhaustion at the workplace.
When using do not eat or drink.

- Information about fire - and explosion protection:
Keep ignition sources away - Do not smoke.
Use explosion-proof apparatus / fittings and spark-proof tools.
Protect against electrostatic charges.

- Storage:
- Requirements to be met by storerooms and receptacles:
Store in a cool location.
Store in dry, cool, well-ventilated area.
Mechanical ventilation is recommended.
- Information about storage in one common storage facility: Not required.
- Further information about storage conditions:
Keep container tightly sealed.
Open receptacle only under localized extractor facilities.

Transport information

Land transport (ADR/RID)

UN number:
1099
Shippingopen allclose all
Class:
3 (FT1)
Classification code:
336
Packaging group:
I
Labels:
3 + 6.1
Remarks:
Limited quantities (LQ) 0
Transport category 1
Tunnel restriction code C/E

Inland waterway transport (ADN(R))

UN number:
1099
Shippingopen allclose all
Class:
3
Classification code:
336
Packaging group:
I
Labels:
3 + 6.1
Remarksopen allclose all

Marine transport (IMDG)

UN number:
1099
Proper shipping name and description:
ALLYL BROMIDE
Chemical name:
ALLYL BROMIDE
Class:
3
Packaging group:
I
EmS code:
F-E,S-D
Labels:
3 + 6.1
Marine pollutant
Remarks
Marpol II: Not determinated - Marpol III: Marine Pollutant

Symbol (fish and tree)

Air transport ICAO/IATA

UN number:
1099
Proper shipping name and description:
ALLYL BROMIDE
Chemical name:
ALLYL BROMIDE
Class:
3
Packaging group:
I
Labels:
3 + 6.1
Remarks
Aircraft Passenger: Not authorized - Aicraft Cargo: 30l

Additional transport information

Additional transport information
UN "Model Regulation": UN1099; ALLYL BROMIDE; 3 (6.1); I

Exposure controls / personal protection

- Additional information about design of technical facilities:
No further data; see item 7.

Ingredients with limit values that require monitoring at the workplace:
Not required.
- Additional information:
The lists valid during the making were used as basis.

- Personal protective equipment:
- General protective and hygienic measures:
The usual precautionary measures are to be adhered to when handling chemicals.
Keep away from foodstuffs, beverages and feed.
Immediately remove all soiled and contaminated clothing
Wash hands before breaks and at the end of work.
Avoid contact with the eyes and skin.

- Respiratory protection:
In case of brief exposure or low pollution use respiratory filter device. In case of intensive or longer exposure use self-contained respiratory protective device.

- Protection of hands:
Protective gloves
The glove material has to be impermeable and resistant to the product/the substance/ the preparation.
Due to missing tests no recommendation to the glove material can be given for the product/ the preparation/ the chemical mixture.
Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation
- Material of gloves
The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and varies from manufacturer to manufacturer.
- Penetration time of glove material
The exact break trough time has to be found out by the manufacturer of the protective gloves and has to be observed.
- Eye protection: Tightly sealed goggles
- Body protection: Use protective suit.

Stability and reactivity

- Thermal decomposition / conditions to be avoided:
Stable under normal conditions of use.
Keep ignition sources away - Do not smoke.

- Materials to be avoided:
Avoid contact with metals.
Reacts with oxidizing agents.
Reacts with strong alkali.
Protect from humidity and water.
- Dangerous reactions Reacts with acids.

- Dangerous decomposition products:
Carbon monoxide and carbon dioxide
Bromine
Hydrogen bromide

Disposal considerations

- Product:
- Recommendation
Must not be disposed together with household garbage. Do not allow product to reach sewage system.

- Uncleaned packaging:
- Recommendation:
Disposal must be made according to official regulations.