Registration Dossier

Administrative data

First-aid measures

Emergency measure - Inhalation: Move exposed person to fresh air. Symptomatic treatment. In case of indisposition seek medical advice. Emergency measure - Eyes: Rinse eyes with water. Emergency measure - Skin: Wash affected skin with water. Emergency measure - Ingestion: Symptomatic treatment. In case of indisposition, seek medical advice.

Fire-fighting measures

Recommended extinguishing agent: Carbon dioxide, dry powder foam or water may be used. Product arising from burning: COx, NOx Product determined by test: N Protective equipment: Wear full protective clothing and self-contained breathing apparatus.

Accidental release measures

Emergency measures in case of spillage: Wear proper protective equipment. Sweep up spilled substance into labelled containers and dispose of by incineration in accordance with local regulations. Do not wash into shower or waterway.

Handling and storage

Handling: Avoid contact with skin, eyes or clothing. Use adequate ventilation while handling the substance. Wash thouroughly after handling. Storage: The substance should be stored in sealed containers in well ventilated rooms at room temperature secured from falling down. Packaging of the substance and or preparation: 25 and 200 kg substance in tons which are varnished inside.

Transport information

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Marine transport (IMDG)

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Air transport ICAO/IATA

Remarks
Transport: Transportation must be in compliance with regional laws and regulations
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Exposure controls / personal protection

RESPIRATORY PROTECTION
The substance under consideration Condensation products of m-phenylenebis(methylamine) with condensation products of 4-methyl-m-phenylene diisocyanate with alcohols, C10-14 (even numbered) is never used in its pure form. It is synthesized in-situ, i.e. dissolved in a solvent, and formulated into an additive for lacquers, paints and other coatings systems. The final concentration of the substance in these additives is 20 - 25 % (w/w), hence the substance is highly diluted. It is important to note that neither the substance on its own nor the additives formulated by the registrant will be used in any spray application. Hence, no special respiratory protection is needed - especially when the physico-chemical, toxicological and ecotoxicological properties of the substance are taken into account - when using the substance on its own or in the additives formulated by the registrant.

In case of spray applications (PROC7 and PROC11) of formulated lacquers, paints and other coatings systems, appropropriate respiratory protection is highly recommended. Since Condensation products of m-phenylenebis(methylamine) with condensation products of 4-methyl-m-phenylene diisocyanate with alcohols, C10-14 (even numbered) is used in a typical concentration of 0.1 - 0.5 % (w/w) in the formulated mixture, the main hazard of the formulated lacquers, paints and coatings systems is determined by solvents and other ingredients of those mixtures and NOT by Condensation products of m-phenylenebis(methylamine) with condensation products of 4-methyl-m-phenylene diisocyanate with alcohols, C10-14 (even numbered).

As a consequence, no clear recommendation as to the optimum respiratory protection for individual spray applications - both in industrial (PROC7) as well as in non-industrial (PROC11) settings - for formulated lacquers, paints and other coatings systems can be given here. The appropriate respiratory protection is determined solely by the formulated lacquers, paints and coatings systems that are sprayed.

SKIN AND EYE PROTECTION
The situation described above holds true in exact the same way for skin and eye protection as well as for other exposure control measures, e.g. ventilation.

Stability and reactivity

Danger other than fire: Not known.

Chemical reaction with water: None

Dust explosion: Not to be expected

Dust explosion determined by test: N

Disposal considerations

Industry - Possibility of recovery/recycling: Not possible. Industry - Possibility of neutralisation: Not possible. Industry - Possibility of destruction: controlled discharge: Not recommended Industry - Possibility of destruction - incineration: Incinerate with high temperatures and flue gas scrubbing. Industry - Possibility of destruction - water purification: Not recommended Industry - Possibility of destruction - other: Not applicable Public at large - Possibility of recovery/recycling: Not applicable Public at large - Possibility of neutralisation: Not applicable Public at large - Possibility of destruction: controlled discharge: Not applicable Public at large - Possibility of destruction - incineration: Not applicable Public at large - Possibility of destruction - water purification: Not applicable Public at large - Possibility of destruction - others: Not applicable