Registration Dossier

Administrative data

First-aid measures

General advice: Remove contaminated clothing and wash before reuse.
Self-protection of the Nrst aider: Apply artiNcial respiration only if patient is not breathing but do not use mouth to
mouth resuscitation. If it is suspected that fumes are still present, the responder should wear an appropriate mask or
self-contained breathing apparatus.
If there is any suspicion of inhalation of H2S:
* Rescuers must wear breathing apparatus, belt and safety rope, and follow rescue procedures.
* Remove casualty to fresh air as quickly as possible.
* Immediately begin artiNcial respiration if breathing has ceased.
* Provision of oxygen may help.
* Obtain medical advice for further treatment.
IF INHALED: IF INHALED: If breathing is difNcult, remove to fresh air and keep at rest in a position comfortable for
breathing. Call a POISON CENTER or doctor/physician if you feel unwell.
IF ON SKIN: IF ON SKIN: Wash with plenty of soap and water. If skin irritation or rash occurs: Get medical
advice/attention. Take off contaminated clothing and wash before reuse.
IF IN EYES: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to
do. Continue rinsing. If eye irritation persists, get medical advice/attention.
IF SWALLOWED: IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. Do NOT induce vomiting. In
case of ingestion, always assume that aspiration has occurred. The casualty should be sent immediately to a hospital.
Do not wait for symptoms to develop.
Symptoms: May cause drowsiness and dizziness. Aspiration into the lungs may cause chemical pneumonitis, which
can be fatal. May produce an allergic reaction. May cause damage to organs through prolonged or repeated exposure:
(blood, liver, spleen and thymus). May cause cancer. Toxic if inhaled.
Medical treatment: Do not induce vomiting because of risk of aspiration into the lungs. If aspiration is suspected obtain
immediate medical attention.
Other hazards: If exposed to Hydrogen Sulphide (H2S), consider oxygen therapy. Consult a Poison Centre for guidance.
Due to possible delayed effect of poisoning and for safety reasons, they should be kept under medical observation.
Note to physician: Due to possible delayed effect of poisoning and for safety reasons, they should be kept under
medical observation.

Fire-fighting measures

Suitable extinguishing media: - Foam (SpeciNcally trained personnel only)
- Water fog (SpeciNcally trained personnel only)
- Dry chemical powder
- Carbon dioxide
- Other inert gases (subject to regulations)
- Sand or earth

Unsuitable extinguishing media: Do not use water jet. Direct water jet may spread the Nre. Simultaneous use of foam
and water on the same surface is to be avoided as water destroys the foam.
Special hazards arising from the substance: Incomplete combustion is likely to give rise to a complex mixture of
airborne solid and liquid particulates and gases, including carbon monoxide and unidentiNed organic and inorganic
compounds. If sulfur compounds are present in appreciable amounts, combustion products may also include H2S and
SOx (sulfur oxides) or sulfuric acid.
Advice for Nre-Nghters: Evacuate the area. Fire Nghters should wear complete protective clothing including selfcontained
breathing apparatus. Chemical protection suit. Keep containers cool by spraying with water if exposed to Nre.
Harmful to aquatic organisms. Do not allow to enter drains, sewers or watercourses.

Accidental release measures

Personal precautions: Obtain special instructions before handling spill. Ensure that all relevant regulations regarding
handling and storage facilities of aammable products are followed. (Subject to applicability) A speciNc assessment of
inhalation risks from the presence of H2S in tank headspaces, conNned spaces, product residue, tank waste and waste
water, and unintentional releases must be made to help determine controls appropriate to local circumstances.
Evacuate if necessary. Keep away from heat/sparks/open aames/hot surfaces. – No smoking. Avoid contact with the
product. Do not breathe fumes. Avoid release to the environment. Remove contaminated clothing and wash clothing
before reuse. Wash hands thoroughly after handling.
Environmental precautions: Do not allow to enter drains, sewers or watercourses. Hazardous to the aquatic
environment. Any large spillage into watercourses must be alerted to the regulatory authority responsible for
environmental protection or other regulatory body.
Methods and material for containment and cleaning up: Contain the spillage using bunding. Absorb spillage in earth or
sand. Use only non-sparking tools. Sweep up and shovel into waste drums or plastic bags. Transfer to a lidded
container for disposal or recovery.
Maritime spillages should be dealt with using a Shipboard Oil Pollution Emergency Plan (SOPEP), as required by
MARPOL Annex 1, Regulation 26.

Handling and storage

Precautions for safe handling: Obtain special instructions before use. Ensure that proper housekeeping measures are in
place. Do not eat, drink or smoke while using this product. Do not handle until all safety precautions have been read and
understood. Avoid the formation or spread of mists of air. Do not swallow. Aspiration hazard; Can enter lungs and
cause damage. Ensure adequate ventilation. In case of inadequate ventilation wear respiratory protection. Do not
handle in a conNned space. The vapour is heavier than air. Beware of accumulation in pits and conNned spaces. Use
only non-sparking tools. Ground/bond containers, tanks and transfer/receiving equipment. Do not use compressed air
for Nlling, discharging, or handling operations. Avoid direct contact with the substance. Wear protective gloves /
protective clothing / eye protection / face protection if contact is likely. Wash hands thoroughly after handling. Do not
eat, drink or smoke when using this product.
Conditions for safe storage: Storage area layout, tank design, equipment and operating procedures must comply with
the relevant European, national or local legislation. Storage installations should be designed with adequate bunds so as
to prevent ground and water pollution in case of leaks or spills. Cleaning, inspection and maintenance of internal
structure of storage tanks must be done only by properly equipped and qualiNed personnel as deNned by national, local
or company regulations. Before entering storage tanks and commencing any operation in a conNned area check the
atmosphere for oxygen content and aammability. (Subject to applicability) If sulphur compounds are suspected to be
present in the product, check the atmosphere for H2S content. Light hydrocarbon vapours can build up in the
headspace of containers. These can cause aammability / explosion hazards. Store separately from oxidising agents.
Empty containers may contain aammable product residues. Do not weld, solder, drill, cut or incinerate empty containers,
unless they have been properly cleaned.
Incompatible materials: Some synthetic materials may be unsuitable for containers or container linings depending on
the material speciNcation and intended use. Compatibility should be checked with the manufacturer

Transport information

Land transport (UN RTDG/ADR/RID)

UN number:
1267
Shipping information
Proper shipping name and description:
Crude Hydrocarbon Condensate
Chemical name:
Hydrocarbons from mixed waste plastics, thermo-mechanical depolymerization condensate
Language:
English
Labels:
3+9 (Marine Pollutant / Environmentally Hazardous Substances)
Special provisions / remarks
Special provisions:
640C
Remarks:
Flashpoint below 55C

Inland waterway transport (UN RTDG/ADN(R))

UN number:
1267
Shippingopen allclose all
Labels:
3+9 (Marine Pollutant / Environmentally Hazardous Substances)
Remarksopen allclose all

Marine transport (UN RTDG/IMDG)

UN number:
1267
Shipping information
Proper shipping name and description:
Crude Hydrocarbon condensate
Chemical name:
Hydrocarbons from mixed waste plastics, thermo-mechanical depolymerization condensate
Remarksopen allclose all

Air transport (UN RTDG/ICAO/IATA)

UN number:
1267
Shipping information
Proper shipping name and description:
Crude Hydrocarbon condensate
Chemical name:
Hydrocarbons from mixed waste plastics, thermo-mechanical depolymerization condensate
Remarksopen allclose all
SpecialProvisionsopen allclose all

Exposure controls / personal protection

Hygiene measures: Wash hands before breaks and after work. Remove contaminated clothing and wash before reuse.
Ensure that proper housekeeping measures are in place. Do not eat, drink or smoke while using this product.
For full personal protection measures see the applicable exposure scenario.
Respiratory protection: If technical exhaust or ventilation measures are not possible or insufNcient, respiratory
protection must be worn.
Hand protection: Wear chemically resistant gloves (tested to EN374) in combination with 'basic' employee training.
Eye protection: Use eye protection according to EN 166, designed to protect against liquid splashes.
Skin and body protection: Wear safety or chemical resistant shoes or boots and Chemical protection suit.
Environmental Exposure Controls: Avoid release to the environment.

Stability and reactivity

Chemical stability: Stable under normal conditions.
Possibility of hazardous reactions: Combustion causes toxic fumes. Hydrogen Sulphide (H2S) may be given off when
the material is heated.
Conditions to avoid: Avoid contact with heat and ignition sources and oxidizers.
Incompatible materials: Strong oxidising agents.
Hazardous decomposition products: Decomposition products may include oxides of carbon. Carbon monoxide, Carbon
dioxide. Sulphur oxides may be formed.

Disposal considerations

Product disposal methods: Disposal should be in accordance with local, state or national legislation. This material and
its container must be disposed of as hazardous waste. Send after pre-treatment to a appropriate hazardous waste
incinerator facility according to legislation. Do not discharge into drains or the environment, dispose to an authorised
waste collection point.
Additional Information: MARPOL – see International Convention for the Prevention of Pollution from Ships (MARPOL
73/78) which provides technical aspects for controlling pollution from ships.