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Diss Factsheets

Physical & Chemical properties

Water solubility

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Administrative data

Link to relevant study record(s)

Reference
Endpoint:
water solubility
Type of information:
experimental study
Adequacy of study:
key study
Study period:
2012-09-17 to 2012-11-23
Reliability:
1 (reliable without restriction)
Rationale for reliability incl. deficiencies:
guideline study
Qualifier:
according to guideline
Guideline:
EU Method A.6 (Water Solubility)
Deviations:
no
GLP compliance:
yes (incl. QA statement)
Type of method:
flask method
Water solubility:
>= 4.5 - <= 4.9 mg/L
Temp.:
20 °C
pH:
>= 5.9 - <= 6
Details on results:
The overall water solubility of the test item at a temperature of 20 °C was determined to be 4.7 mg/L.

Water solubility of the test item – experiments A-D

Experiment

A

B

C

D (blank)

Amount of test item (mg)

53.1

51.3

50.9

--

Amount of distilled water (mL)

50

50

50

50

Stirring time at 30 °C (h)

24

48

72

72

pH at 23 °C

6.0

6.0

5.9

5.9

Measured carbon concentration

(total organic carbon in mg/L)

4.64

4.22

4.35

--1)

Water solubility (mg/L)

4.9

4.5

4.6

--

1)below the quantification limit

The water solubility of the test item was determined to be 4.7 mg/L.

Conclusions:
Interpretation of results: slightly soluble (0.1-100 mg/L)
Executive summary:

The study was performed as a multisite study. The solubility experiments were performed by Siemens AG whereas the analytics (total organic carbon (TOC) measurements) were performed by Currenta Analytik. The water solubility of the test item (carbonised PAN based fibre, milled) at a temperature of 20 °C was determined to be 4.7 mg/L.

Description of key information

The solubility in water was determined by the flask method according to OECD guideline 105 (water solubility)/EU method A.6 (water solubility).

Key value for chemical safety assessment

Water solubility:
4.7 mg/L
at the temperature of:
20 °C

Additional information

The test substance (milled carbonised PAN based fibre) falls within the typical range of the substance definition including the impurities (in total < 0.3 %) which in principle consist of metal and mixed metal oxides (mainly Al, Ca, Fe, Na, and Si oxides). These substances are of negligible concern regarding human health and the environment. The different manufacturing processes and precursor materials lead to slightly different compositions. Accordingly, the choice of the test material is based on the substance with the highest content of nitrogen. The obtained test result and the resulting classification are therefore regarded to also cover all other qualities of the substance non-graphitic carbon fibre within the scope of this registration.