Registration Dossier

Administrative data

First-aid measures

General advice:
Move out of dangerous area.
Show this safety data sheet to the doctor in attendance.
Do not leave the victim unattended.
Symptoms of poisoning may appear several hours later.
Call a physician immediately.

Protection of first-aiders:
First Aid responders should pay attention to self-protection and use the recommended protective clothing

If inhaled:
If unconscious, place in recovery position and seek medical advice.
Keep respiratory tract clear.
If symptoms persist, call a physician.
If breathed in, move person into fresh air.

In case of skin contact:
In case of contact, immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.
Wash contaminated clothing before re-use.
If on skin, rinse well with water.
If on clothes, remove clothes.
If symptoms persist, call a physician.

In case of eye contact:
Small amounts splashed into eyes can cause irreversible tissue damage and blindness.
In the case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
Continue rinsing eyes during transport to hospital.
Remove contact lenses.
Protect unharmed eye.
Keep eye wide open while rinsing.
If eye irritation persists, consult a specialist.

If swallowed:
Keep respiratory tract clear.
Do NOT induce vomiting.
Call a physician immediately.
Rinse mouth thoroughly with water.

Fire-fighting measures

Suitable extinguishing media:
Water spray
Alcohol-resistant foam
Carbon dioxide (CO2)
Dry chemical

Unsuitable extinguishing media:
High volume water jet

Specific hazards during firefighting:
Contact with incompatible materials or exposure to temperatures exceeding SADT may result in a self-accelerating decomposition reaction with release of flammable vapors which may auto-ignite.
Cool closed containers exposed to fire with water spray.

Special protective equipmentfor firefighters:
Wear self-contained breathing apparatus for firefighting if necessary.
Use personal protective equipment.

Specific extinguishing methods:
Do not use a solid water stream as it may scatter and spread fire.
Remove undamaged containers from fire area if it is safe to do so.
Use water spray to cool unopened containers.

Further information:
Collect contaminated fire extinguishing water separately. This must not be discharged into drains.
Fire residues and contaminated fire extinguishing water must be disposed of in accordance with local regulations.
Use extinguishing measures that are appropriate to local circumstances and the surrounding environment.

Accidental release measures

Personal precautions:
Use personal protective equipment.
Avoid dust formation.
Avoid breathing dust.
Remove all sources of ignition.
Follow safe handling advice and personal protective equipment recommendations.
Never return spills in original containers for re-use.
Treat recovered material as described in the section "Disposal considerations".

Environmental precautions:
Prevent product from entering drains.
Prevent further leakage or spillage if safe to do so.
If the product contaminates rivers and lakes or drains inform respective authorities.

Methods for cleaning up:
Contact with incompatible substances can cause decomposition at or below SADT.
Clear spills immediately.
Suppress (knock down) gases/vapours/mists with a water spray jet.
To clean the floor and all objects contaminated by this material, use plenty of water.
Soak up with inert absorbent material.
Isolate waste and do not reuse.
Non-sparking tools should be used.
Local or national regulations may apply to releases and disposal of this material, as well as those materials and items employed in the cleanup of releases. You will need to determine which regulations are applicable.

Handling and storage

Advice on safe handling:
Do not swallow.
Do not breathe vapours/dust.
Avoid exposure - obtain special instructions before use.
Avoid contact with skin and eyes.
Take precautionary measures against static discharges.
Never return any product to the container from which it was originally removed.
Provide sufficient air exchange and/or exhaust in work rooms.
Avoid confinement.
Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
Smoking, eating and drinking should be prohibited in the application area.
Wash thoroughly after handling.
Protect from contamination.

Advice on protection against fire and explosion:
Avoid dust formation. Provide appropriate exhaust ventilation at places where dust is formed. Keep away from combustible material.

Hygiene measures:
Keep away from food and drink. When using do not eat or drink. When using do not smoke. Wash hands before breaks and immediately after handling the product.

Requirements for storage areas and containers:
Avoid impurities (e.g. rust, dust, ash), risk of decomposition.
Electrical installations / working materials must comply with the technological safety standards. Containers which are opened must be carefully resealed and kept upright to prevent leakage. Store in original container. Store in accordance with the particular national regulations.

Advice on common storage: Keep away from strong acids, bases, heavy metal salts and other reducing substances.
Recommended storage temperature: < 30 °C
Other data: No decomposition if stored normally.

Transport information

Land transport (ADR/RID)

UN number:
UN 1511
Proper shipping name and description:
UREA HYDROGEN PEROXIDE
Class:
5.1
Classification code:
OC2
Packaging group:
III
Labels:
5.1(8)
SpecialProvisionsopen allclose all

Inland waterway transport (ADN(R))

UN number:
UN 1511
Proper shipping name and description:
UREA HYDROGEN PEROXIDE
Class:
5.1
Classification code:
OC2
Packaging group:
III
Labels:
5.1(8)
Remarksopen allclose all

Marine transport (IMDG)

UN number:
UN 1511
Proper shipping name and description:
UREA HYDROGEN PEROXIDE
Class:
5.1
Packaging group:
III
EmS code:
F-A, S-Q
Labels:
5.1 (8)
Remarksopen allclose all

Air transport ICAO/IATA

UN number:
UN 1511
Proper shipping name and description:
Urea hydrogen peroxide
Class:
5.1
Packaging group:
III
Labels:
Oxidizer, Corrosive
Remarksopen allclose all
SpecialProvisionsopen allclose all

Exposure controls / personal protection

Eye protection:
Tightly fitting safety goggles.
Please wear suitable protective goggles. Also wear face protection if there is a splash hazard.
Ensure that eyewash stations and safety showers are close to the workstation location.

Hand protection
Material: butyl-rubber
Break through time: >= 480 min
Glove thickness: 0.5 mm

Remarks:
Choose gloves to protect hands against chemicals depending on the concentration and quantity of the hazardous substance and specific to place of work. For special applications, we recommend clarifying the resistance to chemicals of the aforementioned protective gloves with the glove manufacturer. Wash hands before breaks and at the end of workday.

Skin and body protection:
Select appropriate protective clothing based on chemical resistance data and an assessment of the local exposure potential.

Respiratory protection: In the case of dust or aerosol formation use respirator with anapproved filter.

Filter type: Filter type P

Stability and reactivity

Reactivity: Stable under recommended storage conditions.

Chemical stability: Stable under recommended storage conditions.

Hazardous reactions: Dust may form explosive mixture in air.

Materials to avoid: Accelerators, strong acids and bases, heavy metals and heavy metal salts, reducing agents

Hazardous decomposition products: Irritant, caustic, flammable, noxious/toxic gases and vapours can develop in the case of fire and decomposition.

Disposal considerations

Waste treatment methods
Product:
The product should not be allowed to enter drains, water courses or the soil.
Do not contaminate ponds, waterways or ditches with chemical or used container.
Dispose of wastes in an approved waste disposal facility.

Contaminated packaging:
Empty remaining contents.
Dispose of as unused product.
Do not re-use empty containers.
Do not burn, or use a cutting torch on, the empty drum.
Dispose of in accordance with local regulations.