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explosive properties of explosives
Type of information:
experimental study
Adequacy of study:
key study
Study period:
2 (reliable with restrictions)
Rationale for reliability incl. deficiencies:
guideline study without detailed documentation
according to guideline
other: 1)Method with the falling hammer 2)Procedure with the friction apparatus 39Steel sleeve method. Nozzle diameter: 2.0 mm; Weighing: 18.4 g
Version / remarks:
Prüfung auf thermische sensibilität nach dem stahlhülsenverfahren gemass sprenstoffgesetz (StAA-Nr 4/15.01)
Prüfung auf Schlagenempfindlichkeit gemass Sprenstoffgesetz (StAA-Nr 4/15.03)
Prüfung auf Reibempfindlichkeit gemass Sprenstoffgesetz (StAA-Nr 4/15.05)
not specified
GLP compliance:
Specific details on test material used for the study:
97% toluene-4-sulphonohydrazed; 3% Hydrated castor oil
Key result
sensitiveness to friction: friction load (N)
Remarks on result:
not sensitive to friction using a friction load of 360 N
Key result
thermal sensitivity - Koenen test: limiting diameter (mm)
Remarks on result:
negative (not further specified)
t1=6s; t2=25s: no explosion t1=8s; t2=24s: no explosion t1=7s; t2=22s: no explosion
Key result
sensitiveness to impact: impact energy (J)
Remarks on result:
not sensitive to impact using an impact energy of 40 J
1 test: decomposes in traces with odor development; 5 tests: no reaction. Overall: no reaction
Interpretation of results:
GHS criteria not met
The substance is not explosive.
Executive summary:

With a diameter of the hole of 2.0 mm in the nozzle plate, no explosions were found in all three experiments. In all three experiments, the pods remained unchanged

In all 6 experiments no explosions were observed at a strike energy of 40J. In one experiment, traces of traces of decomposition with odor development were found in places.

At a friction pin load of 360N, no reaction was observed in any of the 6 experiments.

The substance is not explosive.

Description of key information

The study does not need to be conducted since the Calculated Oxygen Balance is < 200.

Key value for chemical safety assessment

non explosive

Additional information

Calculated Oxygen Balance=146 = 1600/186.23*(2*7+10/2-2).

Justification for classification or non-classification

The substance does not need to be classified as explosive, because TSH is classified as a self-reactive substance Type D.