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Diss Factsheets

Physical & Chemical properties

Explosiveness

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Reference
Endpoint:
explosive properties of explosives
Type of information:
experimental study
Adequacy of study:
key study
Reliability:
1 (reliable without restriction)
Rationale for reliability incl. deficiencies:
guideline study
Qualifier:
according to guideline
Guideline:
EU Method A.14 (Explosive properties)
Deviations:
no
Remarks:
The study was conducted according to the guideline in effect at the time of study conduct.
GLP compliance:
yes
Parameter:
thermal sensitivity - Koenen test: diameter of the orifice plate
Number of fragments:
0
Remarks on result:
other: no fragments, tube unchanged
Parameter:
other: Mechanical sensitivity (shock)
Remarks on result:
other: Negative; sensitivity >40 Nm
Parameter:
sensitiveness to friction: friction load (N)
Remarks on result:
not sensitive to friction using a friction load of 360 N

                                   Results of Thermal Sensitivity (effect of a flame)

Diameter of orifice (mm)

Sample mass (g)

Time till reaction (s)a

Results

2

19.6

267b

No fragments, tube unchanged

2

19.4

177b

No fragments, tube unchanged

2

19.6

180b

No fragments, tube unchanged

6

19.9

158b

No fragments, tube unchanged

6

19.6

172b

No fragments, tube unchanged

6

19.5

160b

No fragments, tube unchanged

aTotal heating time 300 sec.

bWhite smoke was observed.

 

Results of Mechanical sensitivity (shock): 6 times negative, sensitivity >40 Nm.

 

Results of mechanical sensitivity (friction): 6 times negative, sensitivity >360 N. A change in colour to black was observed.

Interpretation of results:
GHS criteria not met
Conclusions:
Thermal sensitivity (effect of a flame): no fragments, tube unchanged
Mechanical sensitivity (shock): Negative, sensitivity >40 Nm
Mechanical sensitivity (friction): Negative; sensitivity >360 N
Executive summary:

The explosiveness of the test substance was tested using thermal sensitivity (effect of a flame), mechanical sensitivity (shock), and mechanical sensitivity (friction). The test substance was negative for explosiveness in all 3 tests. In the thermal sensitivity test, no fragments were observed (tube remained unchanged). The mechanical sensitivity (shock) test was negative with sensitivity >40 Nm. The mechanical sensitivity (friction test) was negative with sensitivity >360 N. A change in colour to black was observed in the friction test.

Description of key information

EU Method A.14

Key value for chemical safety assessment

Explosiveness:
non explosive

Additional information

Justification for classification or non-classification

The test substance is not considered explosive and is not classified according to EU Classification, Labelling and Packaging of Substances and Mixtures (CLP) Regulation (EC)

No. 1272/2008.