Registration Dossier

Administrative data

First-aid measures

Inhalation : Remove to fresh air. If symptoms persist, call a physician.

Skin contact : Wash off with soap and water. If skin irritation occurs, seek medical advice/attention.

Eye contact : Flush affected eyes with plenty of water immediately and call a physician.

Ingestion : Clean mouth with water and drink afterwards plenty of water. Do NOT induce vomiting.

Fire-fighting measures

Suitable extinguishing media : Dry sodium chloride dry sand. Special powder against metal fire.

Unsuitable extinguishing media : Water. Carbon dioxide (CO2)

Specific hazards during firefighting: Contact with water leads to formation of hydrogen fluoride.

Special protective equipment for firefighters: In the event of fire, wear self-contained breathing apparatus.

Further information : Prevent fire extinguishing water from contaminating surface water or the ground water system.

Accidental release measures

Personal precautions : Avoid formation and deposition of dust. Use effective exhaust ventilation system. Avoid breathing dust. Avoid contact with skin, eyes and clothing. Use personal protective equipment.

Environmental precautions : Do not flush into surface water or sanitary sewer system.

Methods for cleaning up : Use mechanical handling equipment. Avoid dust formation. Fill into labelled, sealable containers.

Handling and storage

Handling

Advice on safe handling : Avoid dust formation. Do not breathe dust. Do not breathe vapours, aerosols. Ensure adequate ventilation and, if necessary, exhaust ventilation when handling or transferring the product.Avoid contact with the skin and the eyes. Ensure that the occupational exposure limit value/s (OEL) and/or other limit values are complied with.

Advice on protection against fire and explosion: No special precautions required.

Storage
Requirements for storage areas and containers: Comply with the directives governing water law
Further information on storage conditions: Store in tightly closed containers in a dry place.

Transport information

Land transport (UN RTDG/ADR/RID)

UN number:
Not classified as hazardous for transport - No warning label required.
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Inland waterway transport (UN RTDG/ADN(R))

UN number:
Not classified as hazardous for transport - No warning label required.
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Marine transport (UN RTDG/IMDG)

UN number:
Not classified as hazardous for transport - No warning label required.
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Air transport (UN RTDG/ICAO/IATA)

UN number:
Not classified as hazardous for transport - No warning label required.
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Exposure controls / personal protection

Exposure Limit Values

Fluorides, inorganic; CAS-No.: 16924-00-8
Basis : TRGS 900
Threshold limits: 2.5 mg/m3 Inhalable fraction
Ceiling limit : 2(II)
Note : DFG

Fluorides, inorganic; CAS-No.: 16924-00-8
Basis : 2000/39/EC
Threshold limits TWA : 2.5 mg/m3

Personal protective equipment

Respiratory protection : Respiratory protective device with particle filter EN 143 - P2 or P3

Hand protection : Butyl-rubber, Natural rubber, Nitrile rubber Take note of the information given by the producer concerning
permeability and break through times, and of special workplace conditions (mechanical strain, duration of contact). After contamination with product change the gloves immediately and remove them according to relevant national and local regulations.

Eye protection : Safety glasses

Skin and body protection : Protective suit

Hygiene measures : Handle in accordance with good industrial hygiene and safety practice. Keep working clothes separately.

Environmental exposure controls
General advice : Do not flush into surface water or sanitary sewer system.

Stability and reactivity

Conditions to avoid : Protect from moisture.

Materials to avoid : Contact with water leads to formation of hydrogen fluoride.

Hazardous decomposition products: no data available

Thermal decomposition : Note: no data available

Disposal considerations

Product : The Federal, regional and local rules and regulations governing disposal must be complied with. This product cannot be classified with disposal identification key acc. to the EU disposal directives as a classification results from the intended utilisation purpose of the consumer