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Please be aware that this old REACH registration data factsheet is no longer maintained; it remains frozen as of 19th May 2023.

The new ECHA CHEM database has been released by ECHA, and it now contains all REACH registration data. There are more details on the transition of ECHA's published data to ECHA CHEM here.

Diss Factsheets

Administrative data

Endpoint:
melting point/freezing point
Type of information:
experimental study
Adequacy of study:
key study
Reliability:
1 (reliable without restriction)
Rationale for reliability incl. deficiencies:
other: GLP guideline study

Data source

Reference
Reference Type:
study report
Title:
Unnamed
Year:
2015
Report date:
2015

Materials and methods

Test guideline
Qualifier:
according to guideline
Guideline:
OECD Guideline 102 (Melting point / Melting Range)
GLP compliance:
yes (incl. QA statement)
Type of method:
thermal analysis
Remarks:
DSC

Test material

Constituent 1
Chemical structure
Reference substance name:
sra-[(2E)-2-butenedioato(2-)hydroxy aluminium]
EC Number:
810-213-8
Cas Number:
1370461-06-5
Molecular formula:
C4 H3 Al O5
IUPAC Name:
sra-[(2E)-2-butenedioato(2-)hydroxy aluminium]
Test material form:
solid: particulate/powder
Remarks:
migrated information: powder
Details on test material:
Name of test material (as cited in study report): Aluminum, [(2E)-2-butenedioato(2-)-01 ]hydroxy-
Analytical purity: Approx. 85.8 g/100g (see final report 14L00403)
Lot/batch No.:13-0001-2
Expiration date of the lot/batch: Sep 30, 2014
Storage condition of test material: RT

Results and discussion

Melting / freezing point
Atm. press.:
1 013 hPa
Decomposition:
yes
Decomp. temp.:
> 300 °C
Remarks on result:
other: No melting temperature was found between 0 °C and decomposition of the test item, starting at about 300 °C.

Any other information on results incl. tables

Results in detail

Melting temperature       

No melting temperature was found between 0 °C and decomposition of the test item, starting at about 300 °C.

The estimated accuracy is ± 1 °C.

Observed thermic processes

An endothermic peak was observed at about 150 °C (peak temperature, Test 1 and 2, 151 heating). This is interpreted as loss of volatile components, followed by another endothermic peak starting at about 300 °C (onset temperature, Test 1 and 2, 151 heating).

After Test 1 up to 400 °C, the test item was not molten, it was as powdery as before and showed a weight loss of 10.4 %. The color

was changed to light brown beige. This was interpreted as a reaction. In Test 2 up to 500 °C, the test item showed the beginning of another endothermic peak starting at about 460 °C. After Test 2 the test item was not molten, the color was changed to black and a weight loss of 41.4 % was registered. This is a clear indication of the decomposition of the test item.

All these observations are confirmed by the preliminary TG/DTATest (non-GLP).

Applicant's summary and conclusion