Registration Dossier

Data platform availability banner - registered substances factsheets

Please be aware that this old REACH registration data factsheet is no longer maintained; it remains frozen as of 19th May 2023.

The new ECHA CHEM database has been released by ECHA, and it now contains all REACH registration data. There are more details on the transition of ECHA's published data to ECHA CHEM here.

Diss Factsheets

Physical & Chemical properties

Auto flammability

Currently viewing:

Administrative data

Link to relevant study record(s)

Reference
Endpoint:
auto-ignition temperature (liquids)
Type of information:
experimental study
Adequacy of study:
key study
Study period:
from 2020-05-28 to 2020-06-02
Reliability:
1 (reliable without restriction)
Rationale for reliability incl. deficiencies:
guideline study
Qualifier:
according to guideline
Guideline:
EU Method A.15 (Auto-Ignition Temperature (Liquids and Gases))
Version / remarks:
2008
Deviations:
no
Qualifier:
according to guideline
Guideline:
DIN 51794 (Testing of mineral oil hydrocarbons - Determination of ignition temperature)
Version / remarks:
2003
Deviations:
no
GLP compliance:
yes (incl. QA statement)
Key result
Auto-ignition temperature:
615 °C
Atm. press.:
>= 1 000.9 - <= 1 014.7 hPa

The lowest temperatures at which an ignition occurred in the main test are given in the Table.

Table:        Lowest temperatures at which an ignition occurred

Main test series

Lowest temperatures of an ignition /
°C

Highest temperatures without an ignition /
°C

Atmospheric Pressure /
hPa

1

618

616

1011.6 – 1014.7

2

619

617

1005.8

3

616

614

1000.9 – 1002.8

Based on results of the main test series, the lowest auto-ignition temperature was determined to be 616 °C.

Regulation (EC) No 440/2008 and DIN 51794: The auto-ignition temperature rounded down to the nearest multiple of 5 °C was determined as 615 °C.

For information:

DIN EN 14522: The auto-ignition temperature reduced by 1.5 % and rounded to the nearest integer temperature was determined as 607 °C.

 

Conclusions:
The auto-ignition temperature of the test item was determined as 615 °C.
Executive summary:

A study was conducted according to Regulation (EC) No 440/2008, DIN 51794 and DIN EN 14522. The auto-ignition temperature is the lowest temperature of a hot surface, at which the ignition of a flammable test item as a gas/air- or vapour/air-mixture is observed. The main test is started at the lowest auto-ignition temperature found in the preliminary test and the temperature then decreased in intervals of 2 – 3 K. The number of drops is varied until a temperature is found where no ignition is observed independent of the number of drops added. Three test series were carried out. The lowest auto-ignition temperature rounded down to the nearest multiple of 5 °C was determined as 615 °C. According to DIN EN 14522, the auto-ignition temperature reduced by 1.5 % and rounded to the nearest integer temperature was determined as 607 °C.

Description of key information

The auto-ignition temperature of the test item was determined as 615 °C (reference 4.12-1).

Key value for chemical safety assessment

Autoflammability / Self-ignition temperature at 101 325 Pa:
615 °C

Additional information

A study was conducted according to Regulation (EC) No 440/2008, DIN 51794 and DIN EN 14522. The auto-ignition temperature is the lowest temperature of a hot surface, at which the ignition of a flammable test item as a gas/air- or vapour/air-mixture is observed. The main test is started at the lowest auto-ignition temperature found in the preliminary test and the temperature then decreased in intervals of 2 – 3 K. The number of drops is varied until a temperature is found where no ignition is observed independent of the number of drops added. Three test series were carried out. The lowest auto-ignition temperature rounded down to the nearest multiple of 5 °C was determined as 615 °C. For information:DIN EN 14522: The auto-ignition temperature reduced by 1.5 % and rounded to the nearest integer temperature was determined as 607 °C.