Registration Dossier

Administrative data

First-aid measures

General:
Check the vital functions. Unconscious: maintain adequate airway and respiration. Respiratory arrest: artificial respiration or oxygen. Cardiac arrest: perform
resuscitation. Victim conscious with laboured breathing: half-seated. Victim in shock: on his back with legs slightly raised. Vomiting: prevent
asphyxia/aspiration pneumonia. Prevent cooling by covering the victim (no warming up). Keep watching the victim. Give psychological aid. Keep the victim
calm, avoid physical strain. Depending on the victim's condition: doctor/hospital.
After inhalation:
Remove the victim into fresh air. Respiratory problems: consult a doctor/medical service.
After skin contact:
Wash immediately with lots of water. Do not apply (chemical) neutralizing agents. Take victim to a doctor if irritation persists.
After eye contact:
Rinse with water. Do not apply neutralizing agents. Take victim to an ophthalmologist if irritation persists.
After ingestion:
Rinse mouth with water. Immediately after ingestion: give lots of water to drink. Consult a doctor/medical service if you feel unwell.

Most important symptoms and effects, both acute and delayed:
Acute symptoms
After inhalation:
No effects known.
After skin contact:
Not irritating.
After eye contact:
Not irritating.
After ingestion:
No effects known.
Delayed symptoms
No effects known.

Fire-fighting measures

Extinguishing media:
Suitable extinguishing media:
Water spray. Alcohol-resistant foam. ABC powder. Carbon dioxide.
Unsuitable extinguishing media:
No unsuitable extinguishing media known.
Special hazards arising from the substance or mixture:
On burning: release of toxic and corrosive gases/vapours (nitrous vapours, carbon monoxide - carbon dioxide).
Advice for firefighters:
Instructions:
Dilute toxic gases with water spray. Take account of toxic/corrosive precipitation water. Take account of environmentally hazardous firefighting water. Use
water moderately and if possible collect or contain it.
Special protective equipment for fire-fighters:
Gloves. Face-shield. Protective clothing. Dust cloud production: compressed air/oxygen apparatus. Heat/fire exposure: compressed air/oxygen apparatus.

Accidental release measures

Personal precautions, protective equipment and emergency procedures:
Prevent dust cloud formation. No naked flames.
Protective equipment for emergency responders
Gloves. Face-shield. Protective clothing. Dust cloud production: compressed air/oxygen apparatus.

Environmental precautions:
Contain released substance, pump into suitable containers. Plug the leak, cut off the supply. Dam up the solid spill. Knock down/dilute dust cloud with water
spray. Prevent soil and water pollution. Prevent spreading in sewers.
Methods and material for containment and cleaning up:
Prevent dust cloud formation. Scoop solid spill into closing containers. Carefully collect the spill/leftovers. Clean contaminated surfaces with an excess of water.
Take collected spill to manufacturer/competent authority. Wash clothing and equipment after handling.

Handling and storage

Precautions for safe handling:
Avoid raising dust. Keep away from naked flames/heat. Gas/vapour heavier than air at 20°C. Observe very strict hygiene - avoid contact. Keep container tightly
closed. Remove contaminated clothing immediately. Do not discharge the waste into the drain.
Conditions for safe storage, including any incompatibilities:
Safe storage requirements:
Store in a dry area. Store in a dark area. Keep container in a well-ventilated place. Meet the legal requirements.
Keep away from:
Heat sources, oxidizing agents, (strong) acids.
Suitable packaging material:
No data available
Non suitable packaging material:
No data available

Transport information

Land transport (ADR/RID)

UN number:
3077
Proper shipping name and description:
Environmentally hazardous substance, solid, n.o.s.
Chemical name:
1,8-naphthylenediamine
Language:
English
Class:
9
Classification code:
M7
Packaging group:
III
Labels:
9
SpecialProvisionsopen allclose all

Inland waterway transport (ADN(R))

UN number:
3077
Proper shipping name and description:
Environmentally hazardous substance, solid, n.o.s.
Chemical name:
1,8-naphthylenediamine
Language:
English
Class:
9
Classification code:
M7
Packaging group:
III
Labels:
9
Remarksopen allclose all

Marine transport (IMDG)

UN number:
3077
Proper shipping name and description:
Environmentally hazardous substance, solid, n.o.s.
Chemical name:
1,8-naphthylenediamine
Class:
9
Packaging group:
III
EmS code:
9
Labels:
9
Marine pollutant
Remarksopen allclose all

Air transport ICAO/IATA

UN number:
3077
Proper shipping name and description:
Environmentally hazardous substance, solid, n.o.s.
Chemical name:
1,8-naphthylenediamine
Class:
9
Packaging group:
III
Labels:
9
Remarksopen allclose all
SpecialProvisionsopen allclose all

Exposure controls / personal protection

Appropriate engineering controls
Avoid raising dust. Keep away from naked flames/heat. Carry operations in the open/under local exhaust/ventilation or with respiratory protection.
Individual protection measures, such as personal protective equipment
Observe very strict hygiene - avoid contact. Keep container tightly closed. Do not eat, drink or smoke during work.
a) Respiratory protection:
Dust production: dust mask with filter type P2.
b) Hand protection:
Gloves.
c) Eye protection:
Face shield. In case of dust production: protective goggles.
d) Skin protection:
Protective clothing. In case of dust production: head/neck protection. In case of dust production: dustproof clothing.

Stability and reactivity

Reactivity:
No data available.
Chemical stability:
Discolours on exposure to light.
Possibility of hazardous reactions:
No data available.
Conditions to avoid:
Avoid raising dust. Keep away from naked flames/heat.
Incompatible materials:
Oxidizing agents, (strong) acids.
Hazardous decomposition products:
On burning: release of toxic and corrosive gases/vapours (nitrous vapours, carbon monoxide - carbon dioxide).

Disposal considerations

Provisions relating to waste
The waste code must be assigned by the user, preferably in consultation with the (environmental) authorities concerned. Hazardous waste according to
Directive 2008/98/EC.
Disposal methods
Dissolve or mix with a combustible solvent. Remove to an authorized incinerator equipped with an afterburner and a flue gas scrubber with energy
recovery. Remove waste in accordance with local and/or national regulations. Hazardous waste shall not be mixed together with other waste. Different
types of hazardous waste shall not be mixed together if this may entail a risk of pollution or create problems for the further management of the waste.
Hazardous waste shall be managed responsibly. All entities that store, transport or handle hazardous waste shall take the necessary measures to prevent
risks of pollution or damage to people or animals.
Packaging/Container
Waste material code packaging (Directive 2008/98/EC).
15 01 10* (packaging containing residues of or contaminated by dangerous substances).