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Diss Factsheets
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EC number: 235-487-0 | CAS number: 12251-53-5
- Life Cycle description
- Uses advised against
- Endpoint summary
- Appearance / physical state / colour
- Melting point / freezing point
- Boiling point
- Density
- Particle size distribution (Granulometry)
- Vapour pressure
- Partition coefficient
- Water solubility
- Solubility in organic solvents / fat solubility
- Surface tension
- Flash point
- Auto flammability
- Flammability
- Explosiveness
- Oxidising properties
- Oxidation reduction potential
- Stability in organic solvents and identity of relevant degradation products
- Storage stability and reactivity towards container material
- Stability: thermal, sunlight, metals
- pH
- Dissociation constant
- Viscosity
- Additional physico-chemical information
- Additional physico-chemical properties of nanomaterials
- Nanomaterial agglomeration / aggregation
- Nanomaterial crystalline phase
- Nanomaterial crystallite and grain size
- Nanomaterial aspect ratio / shape
- Nanomaterial specific surface area
- Nanomaterial Zeta potential
- Nanomaterial surface chemistry
- Nanomaterial dustiness
- Nanomaterial porosity
- Nanomaterial pour density
- Nanomaterial photocatalytic activity
- Nanomaterial radical formation potential
- Nanomaterial catalytic activity
- Endpoint summary
- Stability
- Biodegradation
- Bioaccumulation
- Transport and distribution
- Environmental data
- Additional information on environmental fate and behaviour
- Ecotoxicological Summary
- Aquatic toxicity
- Endpoint summary
- Short-term toxicity to fish
- Long-term toxicity to fish
- Short-term toxicity to aquatic invertebrates
- Long-term toxicity to aquatic invertebrates
- Toxicity to aquatic algae and cyanobacteria
- Toxicity to aquatic plants other than algae
- Toxicity to microorganisms
- Endocrine disrupter testing in aquatic vertebrates – in vivo
- Toxicity to other aquatic organisms
- Sediment toxicity
- Terrestrial toxicity
- Biological effects monitoring
- Biotransformation and kinetics
- Additional ecotoxological information
- Toxicological Summary
- Toxicokinetics, metabolism and distribution
- Acute Toxicity
- Irritation / corrosion
- Sensitisation
- Repeated dose toxicity
- Genetic toxicity
- Carcinogenicity
- Toxicity to reproduction
- Specific investigations
- Exposure related observations in humans
- Toxic effects on livestock and pets
- Additional toxicological data
Guidance on Safe Use
Administrative data
First-aid measures
General information:
Instantly remove any clothing soiled by the product.
Eye contact:
Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Continue rinsing eyes during transport to hospital.
Skin contact:
Immediately wash with soap and water and rinse thoroughly. Remove contaminated clothing and shoes. Obtain medical attention immediately.
Ingestion:
Rinse mouth with water. Drink 1 or 2 glasses of water. Never give anything by mouth to an unconscious person. Do NOT induce vomiting. Obtain medical attention.
Inhalation:
Remove to fresh air. Rinse mouth and nose with water. Keep patient warm and at rest. consult doctor in case of symptoms.
Information to doctor or other trained persons giving first aid:
Danger: danger of gastric perforation.
Treatment: If swallowed, gastric irrigation
Fire-fighting measures
Suitable extinguishing media:
Use fire fighting measures that suit the environment.
CO2, powder or water jet. Fight larger fires with water spray or alcohol resistant foam.
Extinguishing media which must not be used for safety reasons:
Water with a full water jet
Specific hazards during fire fighting:
may forms corrosive vapour of alkaline solutions
Normal measures for preventive fire protection.
Special protective equipment for fire-fighters:
Wear alkaline resistant protective suit.
Additional information:
Collect contaminated fire fighting water separately. It must not enter the sewage system.
Prevent any seepage into the ground.
Accidental release measures
Personal precautions:
Avoid causing dust.
Use personal protective equipment. Avoid contact with skin, eyes and clothing. Provide adequate ventilation. Wear breathing apparatus if exposed to vapours/dusts/aerosols.
Environmental precautions:
Isolate area using sand or earthen dykes. Do not allow to enter drains/surface water/ground-water.
Do not allow to penetrate the ground/soil.
Methods for cleaning up:
Collect mechanically.
Soak up with inert absorbent material (sand, diatomite, acid binders, universal binders, sawdust). Sweep up to prevent slipping hazard. Residue: Flush with plenty of water. Collect the discharged liquid if possible in plastic container. Dispose of waste according to applicable local, state, and federal regulations.
Handling and storage
Handling:
Thorough dedusting.
Keep containers tightly sealed. Use only in area provided with appropriate exhaust ventilation. Wear breathing protection equipment when decanting larger quantities without extractor facilities.
Information about pretection against explosions and fires:
No special measures required.
Storage:
Provide alkali-resistant floor. Do not use light alloy containers. Keep container tightly closed in a dry and well-ventilated place.
Transport information
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Marine transport (UN RTDG/IMDG)
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Exposure controls / personal protection
Exposure limit values:
General dust exposure limit:
Type German TRGS 900 (2006) 3 mg/m³
Measured as alveolic part
Additional information:
The lists taht were valid during compilation were used as a basis.
Personal protective equipment:
General protective and hygienic measures:
The usual precautionary measures should be adhered to in handling the chemicals.
Keep away from foodstuffs, beverages and food.
Instantly remove any soiled and impregnated garments.
Wash hands before breaks and immediately after the end of the work.
Avoid contact with the eyes and skin.
Do not inhale dust / smoke / mist.
Breathing equipement:
Dust mask according to DIN EN 140 or 149 (FFP1 and FFP2).
Use breathing protection in case of insufficient ventilation.
Shor term filter device: ABEK-filter (filter P2) .
Hand protection:
In case of spray contact at least protection index 2 recommended, according to more than 30 min. penetration time (EN 374).
Layer thickness of gloves at least: 0.4 mm.
In case of prolonged and intensive contact protection index 6 recommended, according to more than 480 min. penetration time (EN 374):
Layer thickness of gloves at least: 0.7 mm.
Glove material: butyl-rubber, BR; Nitrile rubber, NBR; Natural rubber, NR; Neoprene gloves.
Penetration time of glove material:
The exact break through time has to be found out by the manufacturer of the protective gloves and has to be observed.
Not suitable are gloves made of the following materials: leather gloves
Eye protection:
Tightly sealed safety glasses (DIN 58211, EN 166)
Body protection:
Alkaline resistant protective clothing
Stability and reactivity
Thermal decomposition / conditions to be avoided:
No decomposition if used according to specifications.
Materials to be avoid:
May react vigorously with strong acids.
Liberates ammonia from ammonium salts.
Dangerous reactions:
Strong exothermic reaction with acids
Dangerous composition products:
Sodium hydroxide (NaOH)
Disposal considerations
Product:
Recommendation:
Must not be disposed of together with houshold garbage. Do not allow product to reach sewage system.
European waste catalogue
160303 inorganic wastes containing dangerous substances
Uncleaned packaging:
Recommendation:
Empty contaminated packaging thoroughly. They can be recycled after thorough and proper cleaning.
Packagings that cannot be cleaned are to be disposed of in the same manner as the product.
Dispose of packaging according to regulations on the disposal of packagings.
Recommened cleaning agent:
Water, if necessary with cleaning agent.
Information on Registered Substances comes from registration dossiers which have been assigned a registration number. The assignment of a registration number does however not guarantee that the information in the dossier is correct or that the dossier is compliant with Regulation (EC) No 1907/2006 (the REACH Regulation). This information has not been reviewed or verified by the Agency or any other authority. The content is subject to change without prior notice.
Reproduction or further distribution of this information may be subject to copyright protection. Use of the information without obtaining the permission from the owner(s) of the respective information might violate the rights of the owner.