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Please be aware that this old REACH registration data factsheet is no longer maintained; it remains frozen as of 19th May 2023.

The new ECHA CHEM database has been released by ECHA, and it now contains all REACH registration data. There are more details on the transition of ECHA's published data to ECHA CHEM here.

Diss Factsheets

Physical & Chemical properties

Boiling point

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Administrative data

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Reference
Endpoint:
boiling point
Type of information:
experimental study
Adequacy of study:
key study
Study period:
2000
Reliability:
2 (reliable with restrictions)
Rationale for reliability incl. deficiencies:
study well documented, meets generally accepted scientific principles, acceptable for assessment
Reason / purpose for cross-reference:
reference to same study
Qualifier:
equivalent or similar to guideline
Guideline:
other: OECD 104
GLP compliance:
no
Type of method:
dynamic method
Remarks:
under nitrogen
Specific details on test material used for the study:
Name of test material (as cited in study report): Methylmorpholine
Analytical purity: 99.9 % (Aldrich)
Key result
Boiling pt.:
114.25 °C
Atm. press.:
999.9 hPa
The regression of the results leads with a
mean deviation of 0.15 % to the following equation (range of measurements 17.58 - 114.25 °C):
ln (p/bar) = 9.4919 - 3150.39 / (217.56 + t/°C)
Conclusions:
The boiling point of the test substance was determined to be 114.25 °C at 999.9 hPa in a non GLP vapour pressure determination according to OECD Guideline 104.

Description of key information

The boiling point of the test substance was determined to be 114.25 °C at 999.9 hPa in a non GLP vapour pressure determination according to OECD Guideline 104 (BASF AG, 2000).

Key value for chemical safety assessment

Boiling point at 101 325 Pa:
114 °C

Additional information

The vapour pressure was determined by measuring the boiling temperature of the substance at various specified pressures (dynamic method; also recommended for the determination of the boiling temperature in OECD TG 103, boiling point). Test was performed under nitrogen atmosphere.